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    Nitrile containing styryl dyes
    2.
    发明授权
    Nitrile containing styryl dyes 失效
    NITRILE含有STYRYL DYES

    公开(公告)号：US3652636A

    公开(公告)日：1972-03-28

    申请号：US3652636D

    申请日：1968-08-13

    Applicant: BASF AG

    Inventor： SCHEUERMANN HORST ,  SEEFELDER MATTHIAS

    IPC: C07C255/34 ,  C09B23/14 ,  C07C121/72

    CPC classification number: C07C255/00 ,  C09B23/143

    Abstract: A CLASS OF P-N-N-DISUBSTITUTED STYRYL COMPOUNDS WHICH ARE METHINE OR STYRYL DYES PARTICULARLY USEFUL FOR DYEING TEXTILE MATERIAL OF CELLULOSE ESTERS AND SYNTHETIC POLYAMIDES OR POLYESTERS FAST GREEN-YELLOW SHADES. PARTICULARLY USEFUL STYRYL DYES ARE THOSE OF THE FORMULA

    1-((NC-)2-C=CH-),2-A,4-(PHENYL-CH2-CH2-N(-CH2-CH2-COO-E)

    -),BENZENE

    WHEREIN A IS HYDROGEN OR METHYL AND E IS METHYL, ETHYL, N-BUTYL OR ISOBUTYL.

    Production of formylmethylene-phthalimidines
    6.
    发明授权
    Production of formylmethylene-phthalimidines 失效
    甲基苯乙胺的生产

    公开(公告)号：US3660428A

    公开(公告)日：1972-05-02

    申请号：US3660428D

    申请日：1969-07-09

    Applicant: BASF AG

    Inventor： SEEFELDER MATTHIAS ,  MUELLER HANS-RICHARD

    IPC: C07D209/46 ,  C07D27/50

    CPC classification number: C07D209/46

    Abstract: PRODUCTION OF FORMYLMETHYLENEPHTHALIMIDINES BY REACTION OF ACETOPHENONE-O-CARBOXYLIC AMIDES WITH THE REACTION PRODUCT OF A FORMAMIDE AND AN ACID HALIDE FOLLOWED BY HYDROLYSIS OF THE REACTION PRODUCT. THE FORMYLMETHYLENEPHTHALIMIDINES ARE STARTING MATERIALS FOR THE PRODUCTION OF DYES, ASSISTANTS, PRINTING AUXILIARIES AND PESTICIDES.

    Production of 4-Formylmethylene-Oxazolidinones-(2)
    10.
    发明专利
    Production of 4-Formylmethylene-Oxazolidinones-(2) 未知

    公开(公告)号：GB1163777A

    公开(公告)日：1969-09-10

    申请号：GB5263566

    申请日：1966-11-24

    Applicant: BASF AG

    Inventor： SEEFELDER MATTHIAS

    IPC: C07D263/38 ,  C07D263/52

    Abstract: 1,163,777. Formylmethylene-oxazolidinones. BADISCHE ANILIN- & SODA-FABRIK A.G. 24 Nov., 1966 [25 Nov., 1965], No. 52635/66. Heading C2C. [Also in Division C4] Compounds of the formula wherein R, R 1 and R 2 each denotes an aliphatic, cycloaliphatic, araliphatic or aromatic radical with up to twelve carbon atoms, R 1 and R 2 may also denote joint members of a 5- to 12- membered cycloaliphatic ring and R 1 may also be H and preparation thereof by reacting a compound of the formula wherein R, B 1 and R 2 have the above significance with a compound of the formula wherein R 3 and R 4 each denotes C 1 -C 4 alkyl radical or a C 6 -C 10 aryl radical or R 3 and R 4 together with the nitrogen atom which they substitute and, if desired, with another hetero atom may form a heterocyclic ring having preferably 5 or 6 members at a temperature of 0‹ to 120‹ C. in an inert solvent such as a hydrocarbon, chlorohydrocarbon or ether with boiling point between 40‹ and 200‹ C. and subsequently hydrolysing the product in a conventional manner by treating it with specified alkaline agents. The formamido chlorides of the third general formula above are prepared by treating an appropriate N-formylamino compound with a specified inorganic acid chloride, in particular, those derived from dimethylformamide, N- formylpiperidine and N-methylformanilide are used in the examples. The preparation of 3- phenyl-, 3-cyclohexyl- and 3-n-butyl-substituted 5 ,5-dimethyl - 4-formylmethylene-oxazol - idin-2-one; 3-cyclohexyl- and 3-n-butyl-substituted 5,5 - pentamethylene - 4 - formylmethylene - oxazolidin - 2 - one; and 3 - benzyl and 3-(3 1 -methoxypropyl)-substituted 5- methyl - 5-ethyl - -4-formylmethylene - oxazolidin- 2-one is described.

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