公开(公告)号：DE10355066A1

公开(公告)日：2005-06-23

申请号：DE10355066

申请日：2003-11-25

Applicant: BASF AG ,  ALBERT LUDWIGS UNI

Inventor： JAEKEL CHRISTOPH ,  VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  BREIT BERNHARD ,  SEICHE WOLFGANG ,  WEIS MARTINE ,  WALOCH CHRISTOPH

IPC: C07B53/00 ,  C07F9/58 ,  C07F9/6571 ,  C07B41/00

Abstract: The present invention relates to a process for asymmetric synthesis in the presence of a chiral catalyst comprising at least one complex of a metal of transition group VIII with ligands capable of dimerization via noncovalent bonds, such catalysts and their use.

公开(公告)号：DE102004014474A1

公开(公告)日：2004-10-21

申请号：DE102004014474

申请日：2004-03-24

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS ,  VOLLAND MARTIN ,  PACIELLO ROCCO ,  SCHAEFER ANSGAR ,  BREIT BERNHARD ,  SEICHE WOLFGANG

IPC: C07F9/58

Abstract: Method for preparing at least one phosphinopyridone (I) and/or its tautomer by preparing a solution of a phosphine and alkali metal in liquid ammonia; reaction with a pyridine compound (II) containing a protected hydroxy and a nucleophilically displaceable group to form a pyridine compound (III) with protected hydroxy and phosphine group, then deprotection to (I).