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公开(公告)号:DE3735577A1
公开(公告)日:1989-05-03
申请号:DE3735577
申请日:1987-10-21
Applicant: BASF AG
Inventor: AUMUELLER ALEXANDER DR , NEUMANN PETER DR , SPANG PETER DR , MATZKE GUENTER DR , TRAUTH HUBERT
IPC: C08G18/38 , C08G18/30 , C08G65/32 , C08K5/00 , C08K5/1545 , C08K5/34 , C08K5/3435 , C08K5/3475 , C08L71/02 , C08L75/00 , C08L75/04
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公开(公告)号:DE3708292A1
公开(公告)日:1988-09-29
申请号:DE3708292
申请日:1987-03-14
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR , WAGENBLAST GERHARD DR , TRAUTH HUBERT
IPC: C07D233/90 , C07D235/20 , C07D235/24 , C08G18/30 , C08G18/38 , C08K5/34 , C08K5/3442 , C08K5/3445 , C08K5/3447 , C08L75/00 , C08L75/04 , C08L101/00 , C07D405/12
Abstract: Photostabilized polymers, including polyurethanes and plastics coatings, contain as photostabilizer one or more compounds of the formula (I) or a novel imidazole-2-carboxanilide of the formula (III)
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公开(公告)号:DE58908064D1
公开(公告)日:1994-08-25
申请号:DE58908064
申请日:1989-08-19
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR , WAGENBLAST GERHARD DR , TRAUTH HUBERT
IPC: C07D235/20 , C07D235/24 , C08K5/34 , C08K5/3442 , C08K5/3447 , C08L33/04 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/02 , C08L75/00 , C08L75/04 , C09D7/12
Abstract: The invention relates to compounds of the general formula (I) in which R and R in each case stand for H, Cl, alkyl, alkoxy, optionally substituted phenyl or phenylalkyl, R and R stand for H, alkyl, oxaalkyl, alkoxy, oxaalkoxy, optionally substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy, alkylcarbonylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 1 or 2 and R - if n = 1 - stands for alkyl, hydroxyalkyl, cycloalkyl, alkenyl, oxaalkyl, phenylalkyl or for -(CH2)m-O- or or - if n = 2 - stands for alkylene, cycloalkylene, alkenylene, oxaalkylene or for or in which m denotes 2 to 4, R denotes alkyl, alkenyl, cycloalkyl, phenylalkyl, optionally substituted phenyl or naphthyl, and R denotes alkylene, alkenylene, cycloalkylene, optionally substituted phenylene, naphthylene, diphenylene, and The anilides (I) are effective photostabilisers for organic materials, in particular for polymers.
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公开(公告)号:DE3828537A1
公开(公告)日:1990-03-01
申请号:DE3828537
申请日:1988-08-23
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR , WAGENBLAST GERHARD DR , TRAUTH HUBERT
IPC: C07D235/20 , C07D235/24 , C08K5/34 , C08K5/3442 , C08K5/3447 , C08L33/04 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/02 , C08L75/00 , C08L75/04 , C09D7/12
Abstract: The invention relates to compounds of the general formula (I) in which R and R in each case stand for H, Cl, alkyl, alkoxy, optionally substituted phenyl or phenylalkyl, R and R stand for H, alkyl, oxaalkyl, alkoxy, oxaalkoxy, optionally substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy, alkylcarbonylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 1 or 2 and R - if n = 1 - stands for alkyl, hydroxyalkyl, cycloalkyl, alkenyl, oxaalkyl, phenylalkyl or for -(CH2)m-O- or or - if n = 2 - stands for alkylene, cycloalkylene, alkenylene, oxaalkylene or for or in which m denotes 2 to 4, R denotes alkyl, alkenyl, cycloalkyl, phenylalkyl, optionally substituted phenyl or naphthyl, and R denotes alkylene, alkenylene, cycloalkylene, optionally substituted phenylene, naphthylene, diphenylene, and The anilides (I) are effective photostabilisers for organic materials, in particular for polymers.
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公开(公告)号:DE3828536A1
公开(公告)日:1990-03-01
申请号:DE3828536
申请日:1988-08-23
Applicant: BASF AG
Inventor: AUMUELLER ALEXANDER DR , SPANG PETER DR , NEUMANN PETER DR , TRAUTH HUBERT
IPC: C07D401/12 , C08K5/3442 , C08K5/3447 , C09D7/12
Abstract: Benzimidazolecarboxanilides of the formula (I) (I) where R1 and R2 independently of one another are each hydrogen, chlorine, bromine, alkyl, alkoxy, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl or phenylalkyl, R3 and R4 independently of one another are each hydrogen, alkyl, alkyl which is interrupted by one or more oxygen atoms, alkoxy, alkoxy which is interrupted by one or more oxygen atoms, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl, phenylalkoxy, alkanoylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 0, 1, 2, 3, 4 or 5, X is oxygen, +TR R5 is hydrogen, alkyl, phenylalkyl, cyanomethyl, aminoethyl, hydroxyethyl, alkylcarbonyl or benzoyl, R6 is hydrogen, alkyl, phenylalkyl or phennyl and m is from 2 to 8, and the acid addition salts and hydrates of these compounds are stabilizers for organic material, in particular for plastics, such as polyethylene, polypropylene and polyamide.
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公开(公告)号:DE59000677D1
公开(公告)日:1993-02-11
申请号:DE59000677
申请日:1990-04-24
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR
IPC: C07C253/30 , C07C255/41
Abstract: 2-Cyano-3,3-diarylacrylic esters I … … (Ar and Ar are aromatic radicals and R is an aliphatic radical having 3-30 C atoms> are prepared by reaction of a 2-cyano-3,3-diarylacrylic ester II … … (R is methyl or ethyl> in the presence of a basic catalyst with an alcohol III… R-OH (III> with removal of the alcohol R -OH formed. … Esters I are valuable light stabilisers, for example for plastics.
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公开(公告)号:DE58902502D1
公开(公告)日:1992-11-26
申请号:DE58902502
申请日:1989-08-19
Applicant: BASF AG
Inventor: AUMUELLER ALEXANDER DR , SPANG PETER DR , NEUMANN PETER DR , TRAUTH HUBERT
IPC: C07D401/12 , C08K5/3442 , C08K5/3447 , C09D7/12
Abstract: Benzimidazolecarboxanilides of the formula (I) (I) where R1 and R2 independently of one another are each hydrogen, chlorine, bromine, alkyl, alkoxy, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl or phenylalkyl, R3 and R4 independently of one another are each hydrogen, alkyl, alkyl which is interrupted by one or more oxygen atoms, alkoxy, alkoxy which is interrupted by one or more oxygen atoms, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl, phenylalkoxy, alkanoylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 0, 1, 2, 3, 4 or 5, X is oxygen, +TR R5 is hydrogen, alkyl, phenylalkyl, cyanomethyl, aminoethyl, hydroxyethyl, alkylcarbonyl or benzoyl, R6 is hydrogen, alkyl, phenylalkyl or phennyl and m is from 2 to 8, and the acid addition salts and hydrates of these compounds are stabilizers for organic material, in particular for plastics, such as polyethylene, polypropylene and polyamide.
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公开(公告)号:DE3865478D1
公开(公告)日:1991-11-21
申请号:DE3865478
申请日:1988-03-05
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR , WAGENBLAST GERHARD DR , TRAUTH HUBERT
IPC: C07D233/90 , C07D235/20 , C07D235/24 , C08G18/30 , C08G18/38 , C08K5/34 , C08K5/3442 , C08K5/3445 , C08K5/3447 , C08L75/00 , C08L75/04 , C08L101/00
Abstract: Light-stabilised polymer (I) contains cpd(s). of formula (II) as stabiliser(s) where R1, R2 = Ph or heteroaryl, opt. substd. with 1-12C alkyl or alkoxy, PhO, Hal or CF3, and the other R1 or R2 = H, 1-12C alkyl, 7-9C phenalkyl or COOR5, or -CR1=C2- is a condensed benzene ring, opt. substd. with OH, Hal, 1-12C alkyl or alkoxy, COOR5, COR5, CONHR5, COOH, OCOR5, NHCOR5, SO2R5 or CN; R5 = 1-12C alkyl; or 5-8C cycloalkyl, Ph or 7-10C phenalkyl (opt. 1-4C alkyl-substd.); R3, R4 = H, or one R3 or R4 = 1-4C alkyl or 7-9C phenalkyl; n = 1 or 2. If n = 1, X = Ph, naphthyl, or 5- or 6-membered aromatic heterocycle, opt. condensed with a benzene ring; the residues are opt. substd. with 1-12C alkoxy, OCH2O, OC2H4O, CF3, OH, Hal, SR5, COR5, COOR5, OCOR5, COOH, CN, CONHR5, NHR5, N(R5)2 or NHCOR5; If n = 2, X = C6H4 or C10H6, opt. substd. with 1-12C alkyl or alkoxy or Hal, or C6H4YC6H4, Y = (CH2)m, CO, CO(CH2)pCO, OCO(CH2)pCOO, NHCO(CH2)pCONH, -O-, SO2, OCOC6H4COO or NHCOC6H4CONH; m = 1, 2 or 3; p = 0 or 1-8. Imidazole-2-carboxylic acid anhydrides of formula (III) are claimed. R = C6H4R9 or -CR=CR- = T-C6H3 (condensed); R8 = 1-12C alkyl or alkoxy or alkoxycarbonyl, PhO, 7-9C phenalkyl, CF3, N,N-di(1-6C)alkylamino, 2-12C alkanoyl- or alkanoyloxy-amino, 1-12C alkylcarbonyl, phenalkanoyloxy, PhCOO, PhCO, CN, OCH2O, or OC2H4O; R9 = 1-12C alkyl, 1-4C alkoxy, Cl or H; T = H, 1-4C alkyl or alkoxy, CF3, Ph, 7-9C phenalkyl or Cl; q = 1 or 2.
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公开(公告)号:DE4012449A1
公开(公告)日:1991-10-24
申请号:DE4012449
申请日:1990-04-19
Applicant: BASF AG
Inventor: AUMUELLER ALEXANDER DR , NEUMANN PETER DR , TRAUTH HUBERT , SPANG PETER DR
IPC: C08K5/3435 , C08K5/3447 , C08K5/3475
Abstract: Utilisation of mixt. (I) to stabilise polyamides and styrene polymers is claimed. (I) contains: (A) 10-90 wt% sterically hindered amine of formula (I): where n = 1 or 2; R = H, 1-4C alkyl, 1-4C acyl or 7-10C phenyl alkyl; y, in the case of n = 1 is: (a) 1-18C alkyl interrupted by 1-4 non-neighbuoring nitrogen or oxygen atoms and contg. additional hydroxy gps.; (b) 3-12C cycloalkyl; (c) phenyl, unsubstd. or substd. with 1-3 1-4C alkyl, F, Cl, Br, 1-4C alkoxy, methylenedioxy or di-1-4C alkylamino; (d) a gp. of formula (II); (e) 7-12C phenylalkyl or 13-16C diphenylalkyl with additional gps. (d) on the phenyl gps. Y in the case of n = 2 is: (f) 2-16C alkylene; (g) 5-18C cycloalkylene; (h) phenylene- and phenylene gp-contg. alkylene bridges with 8-15C atoms or 4-18C alkylene interrupted with 1-4 non-neighbouring oxygen or nitrogen atoms; (B) 90-10 wt% benzimidazol-2-carboxylic acid anilide of formula (III): X = H, 1-4C alkyl, 1-4C alkoxy or hydroxy. Also claimed are polyamides (II) and styrene (III) polymers stabilised against the effect of light, oxygen and heat contg. 0.05-5 wt% mixt. of sterically hindered (I) and (II). ADVANTAGE - (II) and (III) are superior to prior art esp. w.r.t., the tendency to form tears on the plastic surface and preservation of impact strength.
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公开(公告)号:DE3916494A1
公开(公告)日:1990-11-22
申请号:DE3916494
申请日:1989-05-20
Applicant: BASF AG
Inventor: SPANG PETER DR , NEUMANN PETER DR , TRAUTH HUBERT
IPC: C07D209/08 , C07D209/86 , C07D215/06 , C07D215/18 , C07D215/20 , C07D215/26 , C07D219/02 , C08K5/3417 , C08K5/3437
Abstract: Heterocyclic amidine derivatives of the general formula I (I) in which the variables R1 are the same or different and denote hydrogen, C1-C4-alkyl, C1-C4-alkoxy, hydroxyl or chlorine, R2 to R5 denote hydrogen or C1-C4-alkyl and R3 and R4 can together form a five-membered or six-membered ring, R6 denotes hydrogen or C1-C8-alkyl, R7 denotes cyano or -COOR8, -COR8, -CONHR8 or -CONR82, in which R8 is a straight-chain or branched-chain C1-C12-alkyl group which may be interrupted by oxygen atoms, a cyclopentyl or cyclohexyl group or a phenylalkyl group having from 1 to 3 carbon atoms in the alkyl moiety, A is a chemical bond or a methylene group which may additionally carry one or two C1-C4-alkyl radicals, and m and n are each 1 or 2. The said heterocyclic amidine derivatives I serve as UV stabilizers for organic materials.
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