公开(公告)号：DE19629647A1

公开(公告)日：1998-01-29

申请号：DE19629647

申请日：1996-07-23

Applicant: BASF AG

Inventor： GOTTSCHALK AXEL DR ,  MEHLER CHRISTOF DR ,  STADLER REIMUND PROF DR ,  JUNG KARSTEN ,  MORSCHHAEUSER ROMAN

IPC: C08F297/04

Abstract: Block copolymers comprise: (a) at least 3 blocks A, built up from at least 3 of varying monomer constitutional units, each block being only directly connected with blocks with which it is incompatible; and (b) end blocks E and E , different from each other, the end block E developing attractive molecular interaction with the end block E .

公开(公告)号：DE19652312A1

公开(公告)日：1998-06-18

申请号：DE19652312

申请日：1996-12-16

Applicant: BASF AG

Inventor： MEHLER CHRISTOF DR ,  GOTTSCHALK AXEL DR ,  STADLER REIMUND PROF DR ,  DENIZLIGIL SELCHUK DR

IPC: C08F293/00 ,  C08F295/00 ,  C08F297/00 ,  C08G81/02

Abstract: In a method for the production of linear block copolymers, which contain at least a sequence A-B-C of a block A of radically polymerizable monomers (a), a block B of monomers (b) and a block C of radically polymerizable monomers (c), the monomers (a), (b) and (c), which are different from each other, are made to react with (1) radical polymerization of monomers (c) with a macro radical initiator (I) of general formula Y-B-X-B-Y, in which X and Y are divisible functional groups upon formation of radicals, whereby X can be separated without fission from Y, under conditions leading to the formation of macro radical initiators (II) which contain the sequence Y-B-C, by selectively separating X and by polymerizing (c), (2) radical polymerization of monomers (a) with the macro radical initiator (II) by separating Y and forming linear block copolymers containing the sequence A-B-C. The block copolymers have the sequences A-B-C, A-B-C-B-A, C-B-A-B-C or A-B-C-B-A-B-C-B-A.

公开(公告)号：DE19643889A1

公开(公告)日：1998-05-07

申请号：DE19643889

申请日：1996-10-30

Applicant: BASF AG

Inventor： MEHLER CHRISTOF DR ,  GOTTSCHALK AXEL DR ,  STADLER REIMUND PROF DR ,  BALSAMO-HERNANDEZ VITTORIA

IPC: C08F8/04 ,  C08F297/04 ,  C08J5/00 ,  C08J5/18 ,  C08L53/02 ,  D01F6/30

Abstract: The selective hydrogenation of a block terpolymer (I) consisting of a block (A) consisting of conjugated diene monomers, a block (B) consisting of vinylic or olefinic monomers containing a functional group and a block (C) consisting of a vinyl aromatic monomer is claimed. Block (A) is selectively hydrogenated using hydrogen in the presence of a RhCl(P(C6H5)3)3 or RuCl(P(C6H5)3)3 catalyst.Also claimed are: (i) the resulting hydrogenated block copolymer (ii) moulded articles, film or fibres containing the hydrogenated block copolymer.

公开(公告)号：DE19521779A1

公开(公告)日：1997-01-09

申请号：DE19521779

申请日：1995-06-20

Applicant: BASF AG

Inventor： GOTTSCHALK AXEL DR ,  KRAPPE UDO ,  STADLER REIMUND PROF DR ,  ALTSTAEDT VOLKER DR ,  BREINER ULRIKE

IPC: C08F8/04 ,  C08F297/04 ,  C08F297/00 ,  C08L53/02

Abstract: - A-B-C block copolymers (I) comprise a block A, a block B with a Tg of +20[deg]C and a block C, which are different and mutually incompatible and have vol. fractions FA, FB and FC such that (a) FB FA or FC and 0.20 FB 0.35 and 0.75 FC FA 1.25 FC; or (b) 0.5 FC 0.75 and 0.20 FA 0.35 and 0.25 FA FB 0.70 FA; or (c) 0.60 FC 0.70 and 0.10 FA M 0.20 and 0.10 FB 0.20; or (d) 0.70 FC 0.94 and 0.05 FA 0.20 and 0.01 FB 0.10, such that 0.36 FB/FA 0.42.

公开(公告)号：DE4416854A1

公开(公告)日：1995-11-16

申请号：DE4416854

申请日：1994-05-13

Applicant: BASF AG

Inventor： GOTTSCHALK AXEL DR ,  STADLER REIMUND PROF DR ,  KRAPPE UDO

IPC: C08L53/00 ,  C08L71/12 ,  C08L25/04 ,  C08L51/00 ,  C08L55/02 ,  C08L33/06 ,  B29D7/01

Abstract: Multiphase polymer mixtures contain (a) a polymer (A); (b) an A-B block copolymer (B) made up of a block A and of an elastic block B; (c) a B-C block copolymer (C) made of an elastic block B and of a block C; and (d) at least another polymer (D) which is different from (A), (B) and (C) and incompatible with polymer (A). Blocks A, B and C differ from each other, polymer (A) is compatible with block A and incompatible with block C, polymer (D) is compatible with block C and incompatible with block A, elastic block B has a glass transition temperature below +20 DEG C and blocks A, B and C are incompatible with each other.