公开(公告)号：DE102006027698A1

公开(公告)日：2007-12-20

申请号：DE102006027698

申请日：2006-06-14

Applicant: BASF AG

Inventor： STAFFEL WOLFGANG ,  KESSINGER ROLAND ,  HENKELMANN JOCHEM

IPC: C07C69/01 ,  B01J31/20 ,  C07B41/12 ,  C07C67/04 ,  C07C69/34 ,  C07C69/44 ,  C08F8/00 ,  C08J3/24 ,  C08K5/05

Abstract: Preparation of vinyl carboxylate compound (I) comprises reaction of a carboxylic acid compound (II) with an alkyne compound in the presence of a catalyst such as carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron and rhenium metal, at =300[deg]C. Preparation of vinyl carboxylate compound of formula (I) comprises reaction of a carboxylic acid compound (II) of formula (R 1>-(C(O)-OH) n) with an alkyne compound (III) of formula (H-C?=C-R 2>) in the presence of a catalyst such as carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron and rhenium metal, at =300[deg]C. R 1>H or -COO-CH=CH-R 2> (when n is 1), 1-20C alkyl, 2-20C alkenyl or 3-7C cycloalkyl (when n is 1-4 and optionally substituted with 1-3 of phenyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), aryl (when n is 1-6 and optionally substituted with 1-3 of 1-4C alkyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C-alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), 7-9C bicycloalkyl, 7-9C bicycloalkenyl and/or two carbon-carbon double bonds (when n is 1 or 2 and the bicycloalkyl is substituted with 1-6 of halo or 1-4C alkyl), or 5- or 6 membered heterocyclyl ring containing one or two heteroatom such as N, O and S (when n is 1-3 and the ring is substituted with 1 or 2 of halo or 1-4C alkyl); R 2>H, 1-8C alkyl, phenyl-1-4C alkyl, phenyl (optionally substituted with 1 or 2 of 1-4C alkyl) or 3-7C cycloalkyl; R 3>1-4C alkyl; and R 4>, R 5>H or 1-4C alkyl. In formula (II): R 1>1-20C alkyl, 2-20C alkenyl or 3-7C cycloalkyl (when n is 1-4 and optionally substituted with 1-3 of phenyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), aryl (when n is 1-6 and optionally substituted with 1-3 of 1-4C alkyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C-alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), H or COOH. Independent claims are included for: (1) a vinyl carboxylate compound (I); and (2) a butane-1,2,3,4-tetracarboxylic acid tetravinyl ester. [Image].

公开(公告)号：DE102006028000A1

公开(公告)日：2007-12-20

申请号：DE102006028000

申请日：2006-06-14

Applicant: BASF AG

Inventor： STAFFEL WOLFGANG ,  KESSINGER ROLAND ,  HENKELMANN JOCHEM ,  KAESHAMMER STEFAN

IPC: C07C231/12 ,  C07C233/00

Abstract: The present invention relates to a process for preparing N-(1-alkenyl)carboxamides of the formula I, which comprises reacting a carboxamide of the formula II with an alkyne of the formula III in the presence of a catalyst selected from among carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron.

公开(公告)号：DE102006046112A1

公开(公告)日：2008-04-03

申请号：DE102006046112

申请日：2006-09-28

Applicant: BASF AG

Inventor： STAFFEL WOLFGANG ,  KESSINGER ROLAND ,  HENKELMANN JOCHEM

IPC: C07C67/04 ,  C07B41/12 ,  C07C69/01 ,  C08F8/00 ,  C08J3/24 ,  C09D7/12 ,  C09J11/06

Abstract: Preparation of vinyl carboxylate compound (I) comprises reaction of a carboxylic acid compound (II) with an alkyne compound in the presence of a catalyst such as carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron and rhenium metal, at =300[deg]C. Preparation of vinyl carboxylate compound of formula (I) comprises reaction of a carboxylic acid compound (II) of formula (R 1>-(C(O)-OH) n) with an alkyne compound (III) of formula (H-C?=C-R 2>) in the presence of a catalyst such as carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron and rhenium metal, at =300[deg]C. R 1>H or -COO-CH=CH-R 2> (when n is 1), 1-20C alkyl, 2-20C alkenyl or 3-7C cycloalkyl (when n is 1-4 and optionally substituted with 1-3 of phenyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), aryl (when n is 1-6 and optionally substituted with 1-3 of 1-4C alkyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C-alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), 7-9C bicycloalkyl, 7-9C bicycloalkenyl and/or two carbon-carbon double bonds (when n is 1 or 2 and the bicycloalkyl is substituted with 1-6 of halo or 1-4C alkyl), or 5- or 6 membered heterocyclyl ring containing one or two heteroatom such as N, O and S (when n is 1-3 and the ring is substituted with 1 or 2 of halo or 1-4C alkyl); R 2>H, 1-8C alkyl, phenyl-1-4C alkyl, phenyl (optionally substituted with 1 or 2 of 1-4C alkyl) or 3-7C cycloalkyl; R 3>1-4C alkyl; and R 4>, R 5>H or 1-4C alkyl. In formula (II): R 1>1-20C alkyl, 2-20C alkenyl or 3-7C cycloalkyl (when n is 1-4 and optionally substituted with 1-3 of phenyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), aryl (when n is 1-6 and optionally substituted with 1-3 of 1-4C alkyl, halo, OH, 1-4C alkoxy, amino, mono-1-4C-alkylamino, di-1-4C alkylamino, -OCOR 3>, -COOR 3>, -CONR 4>R 5>, -NR 4>COR 5>, -OCONR 4>R 5> or -NR 4>COOR 5>), H or COOH. Independent claims are included for: (1) a vinyl carboxylate compound (I); and (2) a butane-1,2,3,4-tetracarboxylic acid tetravinyl ester. [Image].