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公开(公告)号:DE3560712D1
公开(公告)日:1987-11-05
申请号:DE3560712
申请日:1985-06-25
Applicant: BASF AG
Inventor: STECKHAN EBERHARD PROF DR , WOLF REINHARD , PUETTER HERMANN DR
IPC: C07C17/00 , C07C21/19 , C07C22/04 , C07C29/00 , C07C29/58 , C07C45/61 , C07C45/64 , C07C45/65 , C07C49/687 , C07C49/697 , C07C49/80 , C07C51/00 , C07C57/54 , C07C67/27 , C25B3/25 , C25B3/04
Abstract: Chloro-olefins which contain a group of the formula II where Y is chlorine or hydrogen, which are prepared by a process in which a trichloromethyl compound which contains a group of the general formula I where X is hydrogen or an organic radical, is reduced with a chromium(II) salt in an aqueous medium.
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公开(公告)号:DE3560320D1
公开(公告)日:1987-08-13
申请号:DE3560320
申请日:1985-09-24
Applicant: BASF AG
Abstract: Aromatic carboxylates are prepared by electrochemical oxidation of the corresponding methyl benzenes or benzaldehyde dialkyl acetals in the presence of an alkanol and of a halogenated triarylamine derivative.
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公开(公告)号:DE3862329D1
公开(公告)日:1991-05-16
申请号:DE3862329
申请日:1988-03-05
Applicant: BASF AG
Inventor: DEGNER DIETER DR , STECKHAN EBERHARD PROF DR
Abstract: Process for the preparation of methoxyacetaldehyde dialkyl acetals by electrooxidation of 1-methoxy-2-alkoxyethane in the presence of alkanols and certain triarylamine compounds.
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公开(公告)号:DE3435388A1
公开(公告)日:1986-04-03
申请号:DE3435388
申请日:1984-09-27
Applicant: BASF AG
Abstract: Aromatic carboxylates are prepared by electrochemical oxidation of the corresponding methyl benzenes or benzaldehyde dialkyl acetals in the presence of an alkanol and of a halogenated triarylamine derivative.
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公开(公告)号:DE3423762A1
公开(公告)日:1986-01-09
申请号:DE3423762
申请日:1984-06-28
Applicant: BASF AG
Inventor: STECKHAN EBERHARD PROF DR , WOLF REINHARD , PUETTER HERMANN DR
IPC: C07C17/00 , C07C21/19 , C07C22/04 , C07C29/00 , C07C29/58 , C07C45/61 , C07C45/64 , C07C45/65 , C07C49/687 , C07C49/697 , C07C49/80 , C07C51/00 , C07C57/54 , C07C67/27 , C25B3/25 , C07C21/24 , C07C33/42 , C07C57/52 , C07C69/63 , C07C35/48 , C07C33/44 , C25B3/04
Abstract: Chloro-olefins which contain a group of the formula II where Y is chlorine or hydrogen, which are prepared by a process in which a trichloromethyl compound which contains a group of the general formula I where X is hydrogen or an organic radical, is reduced with a chromium(II) salt in an aqueous medium.
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公开(公告)号:DE4031803A1
公开(公告)日:1992-04-09
申请号:DE4031803
申请日:1990-10-08
Applicant: BASF AG
Inventor: HERMELING DIETER DR , STECKHAN EBERHARD PROF DR , MAGDI ABDEL AZZEM DR
IPC: C07D213/51 , C25B3/23
Abstract: A process for the preparation of pyridine acylals of the general formula I in which R and R independently of one another can be hydrogen, C1- to C20-alkyl, C1- to C20-alkoxy, aryl, aryloxy, halogen, amido, carboxyl, cyano, C2- to C20-alkoxycarbonyl, C2- to C12-alkylcarbonyl or together can be a (CH2)p or (CH=CH)q group which is optionally substituted by C1- to C8-alkyl, C1- to C8-alkoxy, aryl, aryloxy, halogen, amido, carboxyl, cyano or C2- to C20-alkoxycarbonyl, where p represents 1 to 10 and q represents 2 to 4, R denotes hydrogen, a C1- to C20-alkyl, C3- to C20-cycloalkyl or aryl, R denotes a C1- to C12-alkyl, m represents 1 or 2, by electrochemically reacting pyridine derivatives of the general formula II in which R , R , R and m have the abovementioned meanings and n represents 0 or 1, with a carboxylic anhydride of the formula (R CO)2O, where R has the abovementioned meanings, in the presence of a transition metal salt.
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公开(公告)号:DE3708337A1
公开(公告)日:1988-09-22
申请号:DE3708337
申请日:1987-03-14
Applicant: BASF AG
Inventor: DEGNER DIETER DR , STECKHAN EBERHARD PROF DR
IPC: C25B3/23 , C25B3/02 , C07C43/315
Abstract: Process for the preparation of methoxyacetaldehyde dialkyl acetals by electrooxidation of 1-methoxy-2-alkoxyethane in the presence of alkanols and certain triarylamine compounds.
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公开(公告)号:DE3529074A1
公开(公告)日:1987-02-19
申请号:DE3529074
申请日:1985-08-14
Applicant: BASF AG
Inventor: DEGNER DIETER DR , STECKHAN EBERHARD PROF DR
IPC: C07C41/00 , C07C43/32 , C07C67/00 , C25B3/23 , C25B3/29 , C25B3/02 , C11B9/00 , A61K7/46 , A23L3/00 , A23L3/34
Abstract: Preparation of aromatic carboxylic acid ortho-esters of the formula I I where R is C1-C4-alkyl and R1 is H, halogen, alkyl, aryl, heteroaryl, alkoxy, aryloxy, acyl, acyloxy or CN, by electro-oxidizing benzene derivatives of the formula II II where R2 is CH3 or CH(OR2), in the presence of an alcohol ROH, a halogenated triarylamine compound and a base, and novel ortho-trialkyl 4-tert-butoxybenzoates, where alkyl is of 1 to 4 carbon atoms. Ortho-trialkyl 4-tert-butoxybenzoates are scents and are also used to prepared p-hydroxybenzoic acid esters.
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