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公开(公告)号:DE2717697A1
公开(公告)日:1978-11-02
申请号:DE2717697
申请日:1977-04-21
Applicant: BASF AG
Inventor: STEIDLE WALTER DIPL CHEM DR , POHLEMANN HEINZ DIPL CHEM DR , ZAHN WOLFGANG DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR
Abstract: A polymer contg. units of the formula (I) is new. The monomer, 1-hydroxy-1-(p-vinylphenyl)-acetone, is prepd. by action of Saccharomyces cerevisae on p-formylstyrene in an aq. medium, opt. contg. a C source and nutrient salts: The polymer form complexes with metal salts and can be used as precursors for pigments. They undergo condensation reactions, e.g. with diamines and hydrazines. They are also used for surface treatment and as antistatics.
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公开(公告)号:DE2728408A1
公开(公告)日:1979-01-18
申请号:DE2728408
申请日:1977-06-24
Applicant: BASF AG
Inventor: POHLEMANN HEINZ DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR , STEIDLE WALTER DIPL CHEM DR , ZAHN WOLFGANG DIPL CHEM DR
Abstract: New optically active polymers contain the structural element of formula (I):- They are prepd. by polymerising 1-hydroxy-(4-vinylphenyl)-acetic acid (also known as p-vinyl-mandelic acid or 1-hydroxy-(4-vinylphenyl)-ethanoic acid), opt. with other unsatd. monomers. The polymers have a mol. wt. of 2000-6,000. The polymers form complexes with metal salts useful as dyestuff pre-products; they can be condensed with diamines and hydrazines. They find use as antistatics.
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公开(公告)号:DE2717703A1
公开(公告)日:1978-10-26
申请号:DE2717703
申请日:1977-04-21
Applicant: BASF AG
Inventor: STEIDLE WALTER DIPL CHEM DR , POHLEMANN HEINZ DIPL CHEM DR , ZAHN WOLFGANG DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR
IPC: C08F8/32 , C08F8/04 , C08F112/14
Abstract: Optically active polymers contain structural units of formula (I) in which R is a (cyclo)alkyl or pinane gp. (I) are made pref. pref. by reacting polymers contg. structural units of formula (II) with H2 and prim. amines. The rotation value of the polymer is dependent on the content of gps. (I). A polymer consisting exclusively of gps. (I) has a rotation alpha 20d = 3.5, C = 2 in n-dibutylether.
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