公开(公告)号：DE4416476A1

公开(公告)日：1995-11-16

申请号：DE4416476

申请日：1994-05-10

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  EFFENBERGER FRANZ PROF DR ,  WUERTHNER FRANK ANDREAS DR ,  STEYBE FELIX DIPL CHEM

IPC: C07D333/24 ,  B01J31/24 ,  C07D333/34 ,  C07D333/36 ,  C07D333/38 ,  C07D333/44 ,  C07D409/12 ,  C07F7/22 ,  C08F20/34 ,  C08F28/06 ,  C08F299/02 ,  C07D333/42 ,  C07D409/14

Abstract: The invention pertains to thiophenes of the formula (I), where n is 2 to 6; L and L are hydrogen, optionally substituted C1-C10 alkyl, C3-C7 cycloalkyl or phenyl, or L and L together with the connecting nitrogen atom represent a heterocyclic radical; X and Y are hydrogen, optionally substituted C1-C10 alkyl, C3-C7 cycloalkyl or phenyl; and Z is cyano, hydroxysulfonyl, C1-C10 alkoxycarbonyl, optionally substituted C1-C4 alkylsulfonyl, optionally substituted phenylsulfonyl or a radical of the formula (a), where R is hydrogen or cyano and R and R are cyano, nitro, C1-C10 alkoxycarbonyl, optionally substituted C1-C4 alkylsulfonyl or optionally substituted phenylsulfonyl. The invention also relates to the use of said thiophenes in nonlinear optics, a method for the preparation of bithiophenes, and stannylthiophenes as their intermediates.