公开(公告)号：JPH1072553A

公开(公告)日：1998-03-17

申请号：JP11682197

申请日：1997-05-07

Applicant: BASF AG

Inventor： GRUND CLEMENS DR ,  REICHELT HELMUT DR ,  SCHMIDT ANDREAS JOHANN DR ,  BECKMANN STEFAN DR

IPC: C07D213/85 ,  B41M5/34 ,  B41M5/385 ,  B41M5/39 ,  C07D211/68 ,  C07D213/69 ,  C07D277/42 ,  C07D401/00 ,  C07D401/02 ,  C07D401/06 ,  C07D409/02 ,  C07D413/00 ,  C07D413/02 ,  C07D417/06 ,  C09B23/00 ,  C09B23/01 ,  C09B23/06 ,  C09B23/16 ,  C09B55/00 ,  D06P1/00 ,  D06P1/16 ,  D06P3/30 ,  D06P3/32 ,  D06P5/13

Abstract: PROBLEM TO BE SOLVED: To obtain a new methine or azamethine dye having a specified structural formula, being useful for dip-dyeing or printing of synthetic material, and being excellent in compatibility with binders, stability in a printing ink, image stability, etc. SOLUTION: This dye is represented by the structural formula I [wherein X is N or CH; R is desirably a group derived from an (un)substituted derivative based on benzene, indole, quinoline, naphthalene, pyrrole, thiazole, benzimidazole, benzothiazole, thiophene or pyridine; R is desirably CN; R is desirably an alkyl optionally substituted by a cycloalkyl, an aryl, an alkoxyl, a halogen, NO2 or COOH and/or optionally interrupted by 1-3 O atoms]. It is exemplified by one represented by formula II. It can be produced by reacting a compound represented by formula III with a compound represented by the formula: R -CH2 - CH=CH-CHO or the formula: R -CH2 -CH=NH to form a compound represented by formula I (wherein X is CH or N).

公开(公告)号：EP0691382B1

公开(公告)日：1997-12-29

申请号：EP95109963

申请日：1995-06-27

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR

IPC: C07D277/20 ,  C07D277/42 ,  C07D417/06 ,  C09B23/00 ,  C09B23/01 ,  C09B23/06 ,  G02F1/361 ,  G02F1/35

CPC classification number: G02F1/3614 ,  C09B23/0091 ,  C09B23/06

公开(公告)号：DE19726807A1

公开(公告)日：1999-01-07

申请号：DE19726807

申请日：1997-06-24

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  REICHELT HELMUT DR ,  OPPER WALTER DR ,  FRIEDRICH KLAUS DR ,  GEHRER EUGEN DR ,  PLESNIVY THOMAS DR

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/888 ,  B01J23/889 ,  C07C315/00 ,  C07C317/14 ,  B01J27/053 ,  C07C315/04

Abstract: A process for the production of 4,4'-dihalo-diphenyl- sulphones (DHDPSO) comprises reacting chloro-, bromo- or fluoro- benzenes with 4-halophenylsulphonyl chlorides of formula (I); in which X = chlorine, bromine or fluorine. The reaction is carried out in the liquid phase at elevated temperature in presence of solid catalysts with acid centres, comprising (K1) layer silicates with negative layer charges neutralised by protons and essentially not doped with Lewis acids, (K2) zeolites in the acidic H-form, or (K3) mixed oxides with acid centres, consisting of a combination of (a) oxides of titanium, zirconium, hafnium, tin, iron or chromium(III) with (b) oxides of vanadium, chromium(VI), molybdenum, tungsten or scandium, or sulphated or phosphatised oxides of group (a), such mixed oxides having been calcined at 450-800 deg C after combination. Preferably type (K1) comprises aluminium silicate in which part of the silicon is replaced by aluminium and/or part of the Al is replaced by magnesium, especially a montmorillonite. Type (K2) comprises zeolites of structural types MFI, MEL, BOG, BEA, EMT, MOR, FAU, MTW, LTL, NES, CON or MCM 22, especially 12-ring zeolites of the BETA, Y, EMT or mordenite type, or 10-ring zeolites of the pentasil type. Type (K3) may be super-acid mixed oxides, preferably with group (a) oxides and group (b) oxides in a mol ratio of (70:30)-(98:2). The process comprises reacting chlorobenzene (PhCl) with 4-chlorophenyl-sulphonyl chloride (ClPhSOCl) in a mol ratio of 1-100, preferably using excess PhCl, at 100-250 deg C and 1-50 bar, preferably at boiling pt. under normal or autogenous pressure. The catalyst is in the form of a solid bed, and the reaction may be carried out as a continuous process in which excess PhCl is returned to the reactor.

公开(公告)号：DE19726806A1

公开(公告)日：1999-01-07

申请号：DE19726806

申请日：1997-06-24

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  REICHELT HELMUT DR ,  BECK KARL ,  FRIEDRICH KLAUS DR ,  GEHRER EUGEN DR ,  PLESNIVY THOMAS DR

IPC: B01J21/16 ,  C07C315/00 ,  C07C317/14 ,  C07C315/04

Abstract: A process for the production of 4,4'-dihalo-diphenyl- sulphones (DHDPSO) comprises reacting chloro-, bromo- or fluoro- benzenes with 4-halophenylsulphonyl chlorides of formula (I); in which X = chlorine, bromine or fluorine. The reaction is carried out in the liquid phase at elevated temperature in presence of solid catalysts with acid centres, comprising (K1) layer silicates with negative layer charges neutralised by protons and essentially not doped with Lewis acids, (K2) zeolites in the acidic H-form, or (K3) mixed oxides with acid centres, consisting of a combination of (a) oxides of titanium, zirconium, hafnium, tin, iron or chromium(III) with (b) oxides of vanadium, chromium(VI), molybdenum, tungsten or scandium, or sulphated or phosphatised oxides of group (a), such mixed oxides having been calcined at 450-800 deg C after combination. Preferably type (K1) comprises aluminium silicate in which part of the silicon is replaced by aluminium and/or part of the Al is replaced by magnesium, especially a montmorillonite. Type (K2) comprises zeolites of structural types MFI, MEL, BOG, BEA, EMT, MOR, FAU, MTW, LTL, NES, CON or MCM 22, especially 12-ring zeolites of the BETA, Y, EMT or mordenite type, or 10-ring zeolites of the pentasil type. Type (K3) may be super-acid mixed oxides, preferably with group (a) oxides and group (b) oxides in a mol ratio of (70:30)-(98:2). The process comprises reacting chlorobenzene (PhCl) with 4-chlorophenyl-sulphonyl chloride (ClPhSOCl) in a mol ratio of 1-100, preferably using excess PhCl, at 100-250 deg C and 1-50 bar, preferably at boiling pt. under normal or autogenous pressure. The catalyst is in the form of a solid bed, and the reaction may be carried out as a continuous process in which excess PhCl is returned to the reactor.

公开(公告)号：DE19639381A1

公开(公告)日：1998-03-26

申请号：DE19639381

申请日：1996-09-25

Applicant: SIEMENS AG ,  BASF AG ,  FRAUNHOFER GES FORSCHUNG

Inventor： NORDMANN JENS DR ,  BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR ,  BAUER MONIKA PROF DR ,  KRUEGER HARTMUT DR

IPC: G02F1/361 ,  G02F1/35

Abstract: In electrooptical and photonic devices with a functional layer of oriented, crosslinked nonlinear optical (NLO) polymer between 2 buffer layers, the polymer is a polyadduct (I) containing a NLO grouping, derived from (a) an NLO active copolymer (II) containing glycidyl groups reacting with cyanate groups and (b) organic di- or polycyanate(s) (III). Also claimed is a method of making the devices.

公开(公告)号：DE59404129D1

公开(公告)日：1997-10-30

申请号：DE59404129

申请日：1994-06-01

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  SCHEFCZIK ERNST DR

IPC: B01J31/02 ,  C07B61/00 ,  C07D213/89

公开(公告)号：DE4422333A1

公开(公告)日：1996-01-04

申请号：DE4422333

申请日：1994-06-27

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR

IPC: G02F1/35 ,  C07D277/42 ,  C09B23/00 ,  C09B23/01 ,  C09B23/04 ,  C09B23/06 ,  C09B69/10 ,  G02F1/355 ,  G02F1/361 ,  C09B23/02 ,  C09B55/00 ,  G02F2/00 ,  C07C255/34 ,  C07C255/42 ,  C07D333/38 ,  C07D333/24 ,  C07D285/04 ,  C07D271/02

Abstract: The invention concerns the use, in non-linear optics, of naphthalene derivatives of formula (I) in which rings A and B may be fused each other, X is nitrogen or a group of the formula CH or CH=CH-CH: Z is a heterocyclic group and, in the case when X is a CH=CH-CH group, may also be a 5- or 6-membered aromatic carbocyclic ring; and R , R and R are hydrogen, C1-C4 alkyl or C5-C7 cycloalkyl. The invention also concerns the methine dyes of the above formula.

公开(公告)号：DE4401911A1

公开(公告)日：1995-08-03

申请号：DE4401911

申请日：1994-01-24

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR ,  WAGENBLAST GERHARD DR

IPC: C07D277/50 ,  C07D333/38 ,  C08F246/00 ,  C09B69/10 ,  G02F1/361 ,  C07D401/04 ,  C07D409/04 ,  C07D521/00 ,  C09B29/08 ,  G02F1/35

Abstract: The invention relates to the use in non-linear optics of azo dyes of formula I and the use of polymers containing azo dyes which include as characteristic monomer units bivalent groups derived from an azo dye of formula (I) wherein: D represents the residue of a diazo component derived from an aniline or from a five-membered aromatic heterocyclic amine whose heterocyclic ring includes one to three heteroatoms chosen from the group nitrogen, oxygen and sulphur and which can be anellated by a benzene, thiophene, pyridine or pyrimidine ring; R and R represent, independently of each other, hydrogen, C1-C6-alkyl or C5-C7-cycloalkyl; and R and R represent, independently of each other, hydrogen or C1-C6 alkyl which can be substituted by hydroxyl, acryloyloxyl or methacryloyloxyl, at least one of the two groups R and R not being hydrogen.

公开(公告)号：DE4333291A1

公开(公告)日：1995-04-06

申请号：DE4333291

申请日：1993-09-30

Applicant: BASF AG

Inventor： WAGENBLAST GERHARD DR ,  SENS RUEDIGER DR ,  ETZBACH KARL-HEINZ DR ,  BECKMANN STEFAN DR

IPC: G02F1/35 ,  C09B29/033 ,  C09B29/08 ,  G02F1/355 ,  G02F1/361 ,  C09B29/085

Abstract: The invention concerns the use, in non-linear optics, of azo dyes in which the diazo component is derived from an aniline or a five-membered aromatic heterocyclic amine which has one to three ring hetero-atoms selected from the group comprising nitrogen, oxygen and sulphur and which may be fused with a benzene, thiophene, pyridine or pyrimidine ring, the coupling component of the dye being selected from the series comprising the pyrrolidin-1-yl benzenes, piperidin-1-yl benzenes, pyrrolidin-1-yl naphthalenes and piperidin-1-yl naphthalenes.

公开(公告)号：DE4232394A1

公开(公告)日：1994-03-31

申请号：DE4232394

申请日：1992-09-26

Applicant: BASF AG

Inventor： ETZBACH KARL-HEINZ DR ,  BECKMANN STEFAN DR ,  NUYKEN OSKAR PROF DR ,  STROHRIEGL PETER DR ,  MUELLER HARRY

IPC: C08F220/18 ,  C08F20/10 ,  C08F20/34 ,  C08F220/10 ,  C08F220/30 ,  C08F220/34 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C08F220/16 ,  C08F220/36 ,  C08F220/38 ,  C09K19/38

Abstract: The invention relates to copolymers having nonlinear optical properties and containing recurring units of the formula (I) in which D is an electron donor, A is an electron acceptor, R , R , R and R can be identical to or different from one another and are H, alkyl or cycloalkyl, or R and R are CN, NO2 or CHO, or R can form a fused ring with R or R can form a fused ring with R , X are CH groups and/or N atoms, m is an integer from 2 to 11, and R is a hydrogen atom or a methyl group, and recurring units of at least one of the formulae (II), (III) and (IV) They are suitable for the production of optical components in communications technology.