Production of isoprene
    1.
    发明授权
    Production of isoprene 失效
    生产异丙酚

    公开(公告)号:US3657376A

    公开(公告)日:1972-04-18

    申请号:US3657376D

    申请日:1970-06-03

    Applicant: BASF AG

    CPC classification number: C07C1/24 C07C2527/167 C07C11/18

    Abstract: PROCESS FOR THE MANUFACTURE OF ISOPRENE BY CANALYTIC DEHYDRATION OF 3-METHYL-3-BUTEN-1-OL IN THE PRESENCE OF CALCIUM PHOSPHATE AS CATALYST AT ELEVATED TEMPERATURES, WHEREIN DEHYDRATION IS CARRIED OUT, PREFERABLY IN THE PRESENCE OF STREAM, AT TEMPERATURES BETWEEN 200* AND 300*C. USING A 3-METHYL-3-BUTEN-1-OL HAVING A PURITY OF A LEAST 85% BY WEIGHT BASED ON THE TOTAL WEIGHT OF OXYGEN-CONTAINING ORGANIC COMPOUNDS PRESENT IN THE STARTING MATERIAL. ISOPRENE IS AN IMPORTANT MONOMER, FOR EXAMPLE IN THE PRODUCTION OF SYNTHETIC RUBBER.

    5.
    发明专利
    未知

    公开(公告)号:BR9101909A

    公开(公告)日:1991-12-17

    申请号:BR9101909

    申请日:1991-05-09

    Applicant: BASF AG

    Abstract: Products of the condensation of phenolmonosulfonic acids, dihydroxydiphenyl sulfones, urea and formaldehyde can be obtained by (A) preparing a homogeneous reaction mixture in sulfuric acid from the phenolmonosulfonic acid and dihydroxydiphenyl sulfone in the molar ratio of from 3:1 to 10:1, with the proviso that the water content of the mixture is not more than 10% of the total weight of the components, and the mixture contains from 0.3 to 1.5 moles of sulfuric acid per mole of dihydroxydiphenyl sulfone, at from 100 DEG to 180 DEG C., (B) subsequently, at from 40 DEG to 90 DEG C., carrying out a precondensation with 1 to 2 moles of formaldehyde and 0.5 to 1.5 moles of urea per mole of phenol units present in aqueous medium, (C) partially neutralizing the reaction mixture, (D) adding to the partially neutralized reaction mixture 0 to 0.5 mole of phenol per mole of phenol units present and then 0.1 to 0.8 mole of formaldehyde per mole of phenol units then present, (E) further condensing at from 40 DEG to 90 DEG C., (F) shifting the pH of the reaction mixture into the neutral range and (G) subsequently acidifying with a weak acid.

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