Aqueous surfactant mixture for solubilizing harmful organic substances in solid matrix such as contaminated soils comprises selected anionic surfactant and selected nonionic surfactant

    公开(公告)号:DE19954069A1

    公开(公告)日:2000-05-11

    申请号:DE19954069

    申请日:1999-11-10

    Applicant: BASF AG

    Abstract: An aqueous surfactant mixture comprises at least one anionic surfactant and at least one nonionic surfactant for solubilizing harmful organic substances in a solid matrix such as contaminated soil. An aqueous surfactant formulations comprises (a) at least one anionic surfactant selected from alkylaryl sulfonates of formula (I); R = 6-24 C linear or branched alkyl R = Na, K, Ca or NR 3 R (same or different) = H or 1-8 C alkyl m = 1, 2 or 3 and sulfosuccinates of formula (II); R = as above R and R independently = H or linear or branched 2-22 C alkyl with the proviso that R and R are not both H simultaneously; and (b) at least one nonionic surfactant selected from alkoxylated alcohols of formula (III); R = 6-32 C linear or branched alkyl or alkenyl residue R (same or different) = linear or branched 1-6 C alkyl n = 1-80 R = H, linear or branched 1-6 C alkyl or -CO-R R = linear or branched 1-6 C alkyl; carboxylic acid amidoalkoxylates of formula (IV); R = linear or branched 5-30 C alky or alkenyl residue R = H or linear or branched 1-6 C alkyl R (same or different) = linear or branched 1-6 C alkyl n = 1-50 R = H or linear or branched 1-6 C alkyl. Alkylglycosides in which at least one linear or branched 4-30 C alcohol is linked to a mono-, di-, oligo- or polysaccharide by way of an ether link; and Polyalkyleneoxide block copolymers with at least one terminal polyethyleneoxide block and at least one block of propylene oxide and/or butylene oxide and having an average molecular weight of 500-20000, for the ex-situ-, in-situ- and especially the hydraulic in-situ removal of organic substances in a solid matrix.

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