Abstract:
PROBLEM TO BE SOLVED: To provide a novel ethylene terpolymer wax, a manufacturing method thereof, and a floor-protecting composition using the above ethylene terpolymer wax. SOLUTION: The ethylene terpolymer wax comprises 40-95 mass% repeating units derived from ethylene, 0.1-40 mass% repeating units which has at least one ethylenic carbon-carbon double bond and is derived from at least one kind of a 4-10C dicarboxylic anhydride, and 0.1-40 mass% repeating units derived from at least one kind of an ester expressed by formula I [wherein, R 1 is selected from hydrogen, 1-10C alkyl, 3-12C cycloalkyl and 6-14C aryl; and R 2 is selected from 1-10C alkyl, 3-12C cycloalkyl and 6-14C aryl], and has a molecular weight Mw of 20,000 g/mol or less. COPYRIGHT: (C)2004,JPO
Abstract:
PROBLEM TO BE SOLVED: To produce an emulsifiable wax which has a very low total number of spots and a sufficient viscosity, is not tacky, and ca be produced under conditions exhibiting high effects in terms of cost. SOLUTION: There are provided an emulsifiable ethylene polymer comprising a copolymer of 90-95 wt.% ethylene, 4-10 wt.% at least one 3-12C alkenecarboxylic acid, and 0-1.2 wt.% at least one tertiary ester of the corresponding 3-12C alkenecarboxylic acid and having a kinematic melt viscosity (at 120 deg.C) of 800-3,000 mm2/s; a process for producing the novel emulsifiable ethylene polymer; an emulsion comprising the novel ethylene polymer; a process for producing the emulsion from the novel ethylene polymer; and a floor cleaner, a car cleaner, a leather cleaner, a stone cleaner, or a coating film for a surface made from wood, metal, paper, glass, or a plastics, comprising an aqueous emulsion of the novel emulsifiable wax.
Abstract:
PROBLEM TO BE SOLVED: To obtain an ethylene copolymer wax capable of being dispersed in water and preferably applicable to a composition for floor maintenance use. SOLUTION: The ethylene terpolymer wax contains as a block-forming monomer 35-95mass% of ethylene, 0.1-40mass% of an ester represented by formula I and 0.1-25mass% of a carboxylic acid represented by formula II (wherein, in formula I, R 1 denotes hydrogen a 1-10C alkyl, 3-12C cycloalkyl or 6-14C aryl; R 2 denotes hydrogen or a 1-10C alkyl; R 3 denotes a 1-10C alkyl, 3-12C cycloalkyl or 6-14C aryl; and n denotes an integer of 2-100; in formula II, R 4 denotes hydrogen a 1-10C alkyl, 3-12C cycloalkyl or 6-14C aryl). COPYRIGHT: (C)2004,JPO
Abstract translation:要解决的问题:获得能够分散在水中并优选适用于地板维护用组合物的乙烯共聚物蜡。 解决方案:乙烯三元共聚物蜡包含作为嵌段形成单体的35-95质量%的乙烯,0.1-40质量%的由式I表示的酯和0.1-25质量%的由式II表示的羧酸(其中, 在式I中,R“SP”表示氢,1-10C烷基,3-12C环烷基或6-14C芳基; R“SP”表示氢或1-10C烷基; R 表示1-10C烷基,3-12C环烷基或6-14C芳基; n表示2-100的整数;在式II中,R“4”表示氢 1-10C烷基,3-12C环烷基或6-14C芳基)。 版权所有(C)2004,JPO
Abstract:
PROBLEM TO BE SOLVED: To obtain a polyamine of an acylated polymer in which a part of nitrogen atoms of the polyamine have long chain acyl groups and the other parts have short chain acyl groups, useful for an aqueous preparation, preferably a viscosity increasing agent for cosmetic composition or the like. SOLUTION: The polyamine of the acylated polymer in which a part of the nitrogen atoms of the polyamine have the acyl groups expressed by formula I (R1 is a 7-27C alkyl, a 7-27C alkenyl or a 7-27C hydroxyalkyl) and a part of the nitrogen atoms have groups expressed by formula II (R2 is a 1-6C alkyl or a 1-6C hydroxyalkyl). The polymer polyamine preferably have 0.3-40% of the nitrogen atoms of the polymer are acylated by the acyl groups expressed by formula I and 5-100% of the nitrogen atoms are preferably acylated. This polymer polyamine can be obtained by reacting a carboxylic acid expressed by formula R1-COOH or a carboxylic acid expressed by formula R2-COOH. This polymer polyamine is expected in use for a viscosity increasing agent.
Abstract:
Empleo de dispersiones acuosas que contienen al menos una cera de copolímero de etileno neutralizada al menos parcialmente, seleccionada a partir de aquellas ceras de copolímero de etileno que contienen como comonómeros incorporados por polimerización (A) un 26, 1 a un 39 % en peso de al menos un ácido carboxílico con insaturación etilénica, y (B) un 61 a un 73, 9 % en peso de etileno, y aquellas ceras de copolímero de etileno que contienen incorporado por polimerización (A'') un 20, 5 a un 38, 9 % en peso de al menos un ácido carboxílico con insaturación etilénica, (B'') un 79, 4 a un 60 % en peso de etileno y (C'') un 0, 1 a un 15 % en peso de al menos un carboxilato con insaturación etilénica, como agente auxiliar para la elaboración de aguas residuales.
Abstract:
An acylated polyamine polymers (I) are new. New acylated polyamine polymers (I) comprise acyl groups of formulas -CO-R (i) or -CO-R (ii) on some of the nitrogen atoms of the polyamine (I). R = 7-27C alkyl, 7-27C alkenyl or 7-27C hydroxyalkyl; and R = H, 1-6C alkyl or 1-6C hydroxyalkyl. Independent claims are also included for: (1) the preparation of (I) by reacting a polyamine with at least one carboxylic acid of formula R -COOH and at least one carboxylic acid of formula R -COOH or their esters, anhydrides or halogenated derivatives; (2) the preparation of (I) by cationic ring opening polymerization of: (a) at least one 4,5-dihydro-oxazole and/or 5,6-dihydro-4H-1,3-oxazine, both substituted with R on position 2; and (b) at least one 4,5-dihydro-oxazole and/or 5,6-dihydro-4H-1,3-oxazine, both substituted with R on position 2; and (c) optionally at least one other comonomer; (3) an aqueous composition comprising at least one acylated polyamine (I); (4) a method for increasing the viscosity of a composition containing surfactants by adding (I).
Abstract:
A zwitterionic polyamine comprising a linear or branched hydrophobic polyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a spacer between two tertiary nitrogen atoms wherein the spacer is, for example selected from C8-C16-alkylene, C5-C15-cyloalkylene, wherein in formula (IV) R = C1- to C22-alkyl or C7-C22-aralkyl and n = 3 to 6, at least one tertiary amine end group of the polyamine backbone contains two groups having formula (V) or (VI), wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group such as -SO3M, with the proviso that in formula (VI) one X may also be hydrogen and M is hydrogen, alkali metal or ammonium, or contains one group of formula (V) or (VI) and one group selected from radicals consisting of formula (VII), C1- to C22-alkyl and C7-C22-aralkyl, the meaning of A and n is the same as in formula (V) or (VI), said zwitterionic polyetherpolyamine having a molecular weight up to 9000 and optionally containing up to 100 % of the nitrogen atoms quaternized, and a process for the production of zwitterionic polyamines by alkoxylating said polyamines, introducing anionic groups into the alkoxylated polyamines and optionally quaternizing them before or after the introduction of anionic groups. The zwitterionic polyamines are used in detergents.
Abstract:
A zwitterionic polyamine comprising a linear or branched hydrophobic polyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a spacer between two tertiary nitrogen atoms wherein the spacer is, for example selected from C8-C16-alkylene, C5-C15-cyloalkylene, wherein in formula (IV) R = C1- to C22-alkyl or C7-C22-aralkyl and n = 3 to 6, at least one tertiary amine end group of the polyamine backbone contains two groups having formula (V) or (VI), wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group such as -SO3M, with the proviso that in formula (VI) one X may also be hydrogen and M is hydrogen, alkali metal or ammonium, or contains one group of formula (V) or (VI) and one group selected from radicals consisting of formula (VII), C1- to C22-alkyl and C7-C22-aralkyl, the meaning of A and n is the same as in formula (V) or (VI), said zwitterionic polyetherpolyamine having a molecular weight up to 9000 and optionally containing up to 100 % of the nitrogen atoms quaternized, and a process for the production of zwitterionic polyamines by alkoxylating said polyamines, introducing anionic groups into the alkoxylated polyamines and optionally quaternizing them before or after the introduction of anionic groups. The zwitterionic polyamines are used in detergents.