公开(公告)号：AT144270T

公开(公告)日：1996-11-15

申请号：AT92106987

申请日：1992-04-24

Applicant: BASF AG

Inventor： HORN PETER DR ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR ,  SATTLER ULF ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: C08G18/08 ,  C08G18/00 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/10 ,  C08J9/34 ,  C08K3/36 ,  C08L75/00 ,  C08L75/04

Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t

公开(公告)号：DE59108711D1

公开(公告)日：1997-06-26

申请号：DE59108711

申请日：1991-10-15

Applicant: BASF AG

Inventor： HORN PETER DR ,  HOELDERICH WOLFGANG DR ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: B29C45/00 ,  B29C44/00 ,  B29K75/00 ,  B29L31/56 ,  C08G18/00 ,  C08G18/08 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/34 ,  C08K7/26 ,  C08L75/00

Abstract: The invention relates to a process for the production of soft-elastic mouldings which contain urethane groups and are free from chlorofluorocarbons (CFCs), and have a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) crystalline, microporous molecular sieves having a cavity diameter and cavity entrance aperture of less than 1.3 nm, comprising metal oxides or metal phosphates and optionally further additives, and g) assistants, in a closed mould with compaction, expediently by reaction injection moulding (RIM).

公开(公告)号：DK0513573T3

公开(公告)日：1996-11-18

申请号：DK92106987

申请日：1992-04-24

Applicant: BASF AG

Inventor： HORN PETER DR ,  TINTELNOT DIETER ,  SATTLER ULF ,  TADDEY RUDOLF ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR

IPC: C08G18/08 ,  C08G18/00 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/10 ,  C08J9/34 ,  C08K3/36 ,  C08L75/00 ,  C08L75/04

Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t

公开(公告)号：AT153357T

公开(公告)日：1997-06-15

申请号：AT91117554

申请日：1991-10-15

Applicant: BASF AG

Inventor： HORN PETER DR ,  HOELDERICH WOLFGANG DR ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: B29C45/00 ,  B29C44/00 ,  B29K75/00 ,  B29L31/56 ,  C08G18/00 ,  C08G18/08 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/34 ,  C08K7/26 ,  C08L75/00

Abstract: The invention relates to a process for the production of soft-elastic mouldings which contain urethane groups and are free from chlorofluorocarbons (CFCs), and have a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) crystalline, microporous molecular sieves having a cavity diameter and cavity entrance aperture of less than 1.3 nm, comprising metal oxides or metal phosphates and optionally further additives, and g) assistants, in a closed mould with compaction, expediently by reaction injection moulding (RIM).

公开(公告)号：ES2093136T3

公开(公告)日：1996-12-16

申请号：ES92106987

申请日：1992-04-24

Applicant: BASF AG

Inventor： HORN PETER DR ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR ,  SATTLER ULF ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: C08G18/08 ,  C08G18/00 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/10 ,  C08J9/34 ,  C08K3/36 ,  C08L75/00 ,  C08L75/04

Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t

公开(公告)号：CA2054170C

公开(公告)日：1996-12-03

申请号：CA2054170

申请日：1991-10-24

Applicant: BASF AG

Inventor： HORN PETER ,  HOELDERICH WOLFGANG ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: B29C45/00 ,  B29C44/00 ,  B29K75/00 ,  B29L31/56 ,  C08G18/00 ,  C08G18/08 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/34 ,  C08K7/26 ,  C08L75/00 ,  B29C67/20

Abstract: Chlorofluorocarbon-free urethane-containing, soft-elastic moldings having a cellular core, a compacted peripheral zone and an essentially pore-free smooth surface are produced by reacting a) an organic and/or modified organic polyisocyanate with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent, e) a catalyst, f) a crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising metal oxides or metal phosphates, and, if desired, further additives and g) assistants, in a closed mold with compaction, expediently by RIN.

公开(公告)号：DK0545175T3

公开(公告)日：1996-11-18

申请号：DK92119790

申请日：1992-11-20

Applicant: BASF AG

Inventor： SCHUSTER LUDWIG DR ,  HORN PETER DR ,  TADDEY RUDOLF ,  TINTELNOT DIETER ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR

IPC: B65D6/14 ,  C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C08G18/66 ,  C08J9/00 ,  B65D1/12 ,  C08J9/02 ,  C08J9/34 ,  C08K3/04 ,  C08K3/36 ,  C08K7/24 ,  C08L75/00

Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.

公开(公告)号：ES2090463T3

公开(公告)日：1996-10-16

申请号：ES92119790

申请日：1992-11-20

Applicant: BASF AG

Inventor： HORN PETER DR ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR ,  TADDEY RUDOLF ,  TINTELNOT DIETER ,  SCHUSTER LUDWIG DR

IPC: B65D6/14 ,  C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C08G18/66 ,  C08J9/00 ,  B65D1/12 ,  C08J9/02 ,  C08J9/34 ,  C08K3/04 ,  C08K3/36 ,  C08K7/24 ,  C08L75/00

Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.

公开(公告)号：DE4139520A1

公开(公告)日：1993-06-03

申请号：DE4139520

申请日：1991-11-30

Applicant: BASF AG

Inventor： HORN PETER DR ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG DR ,  TADDEY RUDOLF ,  TINTELNOT DIETER ,  SCHUSTER LUDWIG DR

IPC: B65D6/14 ,  C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C08G18/66 ,  C08J9/00 ,  C08J9/02 ,  C08J9/34 ,  C08K3/04 ,  C08K3/36 ,  B65D1/12 ,  C08K7/24 ,  C08L75/00

Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.

公开(公告)号：DE59207363D1

公开(公告)日：1996-11-21

申请号：DE59207363

申请日：1992-04-24

Applicant: BASF AG

Inventor： HORN PETER DR ,  MUELLER ULRICH DR ,  HOELDERICH WOLFGANG PROF DR ,  SATTLER ULF ,  TADDEY RUDOLF ,  TINTELNOT DIETER

IPC: C08G18/08 ,  C08G18/00 ,  C08G101/00 ,  C08J9/00 ,  C08J9/02 ,  C08J9/10 ,  C08J9/34 ,  C08K3/36 ,  C08L75/00 ,  C08L75/04

Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t