Abstract:
PROBLEM TO BE SOLVED: To obtain an amine producible extremely simply, having a preferable pore diameter distribution, by using a middle porous oxide having a high surface area as a catalyst. SOLUTION: In reacting (A) an amine of formula I (R to R are each H, a 120C alkyl, a 2-20C alkenyl, a 2-20C alkynyl, a 3-20C cycloalkyl, etc.) with (B) an olefin of formula II, preferably isobutene, diisobutene, etc., and (C) ammonia or a primary or a secondary amine of formula III in the presence of a heterogeneous catalyst at 200350 deg.C under 100-300 bar, a middle porous oxide having a high surface area is used as the catalyst. Preferably, a catalyst formed from one or more oxides of SiO2 , Al2 O3 , B2 O3 , Ga2 O3 , and TiO3 , is used as the catalyst.
Abstract:
PROBLEM TO BE SOLVED: To obtain a new mesoporous silica having respectively specific surface area and volume of the mesopores and useful as a molded article, a catalyst or a catalyst carrier by converting a silica precursor in a water-containing reaction medium containing a polymer dispersion liquid. SOLUTION: The mesopore of this mesoporous silica has a specific surface area of >=500m /g and a volume of >=1.0mL/g. The maximum size of the pare diameter distribution of the mesopore is preferably >=3nm. The obtained silica is preferably baked. The polymer dispersion liquid is preferably a cationic aqueous polymer dispersion liquid stabilized with a cationic emulsifier and/or a cationic comonomer (emulsifying agent or α,β-ethylenic unsaturated monomer having quaternary amine or ammonium structure). These emulsified polymers can be produced preferably by using a free-radical polymerization initiator having a cationic group.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for increasing hydroamination activity of a calcined zeolite catalyst which is not deactivated by hydroamination, and to provide a method for producing an alkylamine by reacting an olefin with ammonia, a primary amine or a secondary amine under a hydroamination condition on the calcined zeolite catalyst having the increased activity. SOLUTION: This method for producing the alkylamine comprises reacting the olefin with the ammonia, the primary amine or the secondary amine under the hydroamination condition on the calcined zeolite catalyst, wherein the calcined zeolite catalyst is thermally activated within a period after start of the reaction at a temperature of 100 to 550°C in a flow of gas comprising air, nitrogen, the other inert gas or a mixture thereof. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To obtain the subject catalyst, capable of producing a polymer having a high molecular weight by using a middle-sized pore molecular sieve as a carrier. SOLUTION: This catalyst has a middle-sized molecular sieve as a carrier. Further, the molecular sieve contains oxides of elements of Si, Be, B, Al, Ga, In, etc., and/or Ce, has an aluminosilicate structure, especially a silicate structure and 1.5-25nm middle-sized pores, and contains 0.1-10wt.% chromium content. In order to obtain the catalyst, it is preferable that the middle-sized pore molecular sieve in a solvent is brought into contact with a chromium compound (e.g.; chromium oxide), then the solvent is removed and the catalyst is calcined at 400-1200 deg.C.
Abstract:
PROBLEM TO BE SOLVED: To obtain particles with addition of oxide in mesoporous by which particles with addition of oxide having a desired macroscopic shape can be directly formed by causing the reaction of an oxide precursor in a reaction medium comprising a specified fluid in the presence of a surfactant. SOLUTION: The particles with addition of oxide in mesoporous are produced by the reaction of an oxide precursor in a reaction medium comprising at least two kinds of fluids unmiscible with each other in the presence of a surfactant. It is preferable that the particles with addition of oxide in mesoporous produced by this method have a hexagonal unit lattice and P6 symmetry or P63/mmc symmetry (measured by X-ray diffraction).
Abstract:
In einem Verfahren zur Herstellung mesoporöser Oxidformkörper werden Oxidvorläufer in einem Reaktionsmedium aus mindestens zwei nicht mischbaren Fluiden in Gegenwart von Tensiden umgesetzt.
Abstract:
THE PRESENT INVENTION RELATES TO A NOVEL CLASS OF SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS. SAID METAL-ORGANIC FRAMEWORKS COMPRISE AT LEAST ONE METAL ION AND AT LEAST ONE AT LEAST BIDENTATE ORGANIC COMPOUND AND CONTAIN AT LEAST ONE TYPE OF MICRO- AND MESOPORES OR MICRO- OR MESOPORES. SAID SHAPED BODIES COMPRISE AT LEAST ONE METAL-ORGANIC FRAMEWORK MATERIAL AND MAY OPTIONALLY CONTAIN FURTHER SUBSTANCES, IN PARTICULAR AT LEAST ONE SUPPORTING MATERIAL.
Abstract:
A solid (I) containing aluminIum oxide (Al2O3) is claimed, which is obtained by a process comprising contacting Al2O3 precursor(s) (II) with template compound(s) in a liquid medium, in which the template is a dendrimeric molecular nano-system (III) or mixture of 2 or more of these. Also claimed are: (i) the method of producing (I) in this way; and (ii) the use of (III) as template in the production of (I). Preferably The nano-system contains a nitrogen (N), phosphorus (P) or carbon (C) atom or a mixture of 2 or more of these as branch point. (I) also contains element(s) selected from sodium, potassium, calcium, magnesium, beryllium, boron, gallium, indium, silicon, germanium, tin, lead, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, cobalt, nickel, ruthenium, copper, zinc, cadmium, mercury and cerium.
Abstract:
A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and in the absence of an anthrahydroquinone/anthroquinone redox system, in which the oxidation catalyst is formed by solidifying shaping processes.
Abstract:
Prepn. of amine oxides of formula O=N(R )(R )(R ) (I) comprises reacting the amine of formula N(R )(R )(R ) (II) with a hydrogen/oxygen mixt. at -5 to +90 degrees C and 1-100 bar in the presence of an oxidn. catalyst comprising a gp. VIII element on titanium silicate and/or vanadium silicate having a zeolite structure. R -R = 1-30C alkyl, 3-12C cycloalkyl, 1-30C hydroxyalkyl, 1-30C aminoalkyl, 2-30C alkoxyalkyl, aryl, 7-20C arylalkyl, 7-20C alkylaryl (opt. substd. by 1-8C alkyl), 1-8C alkoxy, 3-12C cycloalkyl (opt. substd. by 1-5 halo), ((CH2)2O)nR , ((CH(Me)CH2)O)mR ; or R +R = 3-12C unbroken alkylene bi-chain (opt. substd. by O, N or S); R , R = 1-12C alkyl, 3-12C cycloalkyl, OH, COR , CH2-COOR , 3-12C cycloalkyl, aryl, 7-20C arylalkyl or 7-20C alkylaryl; R ,R = 1-12C alkyl or 3-12C cycloalkyl; m, n = 1-40.