PROCESS FOR THE PREPARATION OF 1,2-BENZISOTHIAZOLONES

    公开(公告)号:DE3569375D1

    公开(公告)日:1989-05-18

    申请号:DE3569375

    申请日:1985-12-20

    Applicant: BASF AG

    Abstract: 1,2-Benzisothiazolones and their alkali metal salts are prepared by reacting 2,2'-dithiodibenzamides in the presence of oxygen or oxygen donors in an aqueous alkaline medium to which a water-soluble organic solvent may be added and, if desired, freeing the benzisothiazolones from the alkali metal salts with acid.

    PROCESS FOR THE PREPARATION OF SACCHARIN

    公开(公告)号:DE3162904D1

    公开(公告)日:1984-05-03

    申请号:DE3162904

    申请日:1981-10-19

    Applicant: BASF AG

    Abstract: A process for the preparation of saccharin by reacting an aqueous hydrochloric acid solution of o-methoxycarbonylbenzenediazonium chloride with sulfur dioxide, wherein (a) the aqueous diazonium salt solution is reacted with sulfur dioxide at from 0 DEG to 100 DEG C. in the presence of a water-immiscible or only partially water-miscible inert organic solvent, (b) in order to decompose the diazonium salt, the reaction mixture is treated simultaneously or subsequently with a diazonium salt decomposition catalyst, (c) the aqueous organic reaction mixture, or the organic phase obtained after removing the aqueous phase, is treated with an oxidizing agent at from 0 DEG to 100 DEG C.

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