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公开(公告)号:DE2404774A1
公开(公告)日:1975-08-21
申请号:DE2404774
申请日:1974-02-01
Applicant: BASF AG
IPC: C08G18/00 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/10 , C07C265/00 , C08G18/02 , C08G18/72 , C07C119/042
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公开(公告)号:DE2404775A1
公开(公告)日:1975-08-21
申请号:DE2404775
申请日:1974-02-01
Applicant: BASF AG
Inventor: FUCHS WERNER DIPL CHEM DR , DUDECK CHRISTIAN DIPL CHEM DR , PLATZ ROLF DIPL CHEM DR , VOGT WOLKER DIPL CHEM DR
IPC: C07C263/10 , C07C119/042
Abstract: Polyisocyanates are prepd. by (a) condensing aniline and aq. HCHO in the presence of HCl and distilling the reaction mixt. without neutralisation to separate (and opt. recycle) water and/or unreacted aniline, (b) converting the polyamine-polyamine hydrochloride mixt. entirely to hydrochloride by suspending it in liq. HCl and adding liq. COCl2 to convert the hydrochloride to isocyanate. Pref. the mole ratio aniline:HCl is 15-160:1. Prods. are esp. used for prodn. of wood glues. The process is simple, non-polluting and free from waste.
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