1.
    发明专利
    未知

    公开(公告)号:DK0463479T3

    公开(公告)日:1999-08-30

    申请号:DK91109640

    申请日:1991-06-12

    Applicant: BASF AG

    Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a

    2.
    发明专利
    未知

    公开(公告)号:DE59109087D1

    公开(公告)日:1999-02-25

    申请号:DE59109087

    申请日:1991-06-12

    Applicant: BASF AG

    Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a

    3.
    发明专利
    未知

    公开(公告)号:AT175688T

    公开(公告)日:1999-01-15

    申请号:AT91109640

    申请日:1991-06-12

    Applicant: BASF AG

    Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a

    5.
    发明专利
    未知

    公开(公告)号:DK0433822T3

    公开(公告)日:1994-04-18

    申请号:DK90123652

    申请日:1990-12-08

    Applicant: BASF AG

    Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.

    6.
    发明专利
    未知

    公开(公告)号:DE59003792D1

    公开(公告)日:1994-01-20

    申请号:DE59003792

    申请日:1990-12-08

    Applicant: BASF AG

    Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.

    7.
    发明专利
    未知

    公开(公告)号:DE3941871A1

    公开(公告)日:1991-06-20

    申请号:DE3941871

    申请日:1989-12-19

    Applicant: BASF AG

    Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.

    8.
    发明专利
    未知

    公开(公告)号:DE3933335A1

    公开(公告)日:1991-04-11

    申请号:DE3933335

    申请日:1989-10-06

    Applicant: BASF AG

    Inventor: VOLKERT OTTO DR

    Abstract: The invention relates to a process for preparation of rigid polyurethane foams having low thermal conductivity by reacting …… a) organic and/or modified organic polyisocyanates with … b) at least one relatively high molecular weight compound having at least two reactive hydrogen atoms and optionally … c) low molecular weight chain extenders and/or crosslinking agents in the presence of … d) cyclopentane (d1) or mixtures (d2) which contain: …… d2i) cyclopentane and/or cyclohexane and … d2ii) at least one compound which is homogeneously miscible with cyclopentane and/or cyclohexane and preferably has a boiling point below 35 DEG C, selected from the group consisting of the alkanes, cycloalkanes having not more than 4 carbon atoms, dialkyl ethers, cycloalkylene ethers and fluoroalkanes,… optionally in conjunction with water, as blowing agents (d), …… e) catalysts and optionally … f) auxiliaries and/or additives. …… The rigid polyurethane foams are used in the refrigerator industry and as insulating material in heating and composite elements.

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