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公开(公告)号:DK0463479T3
公开(公告)日:1999-08-30
申请号:DK91109640
申请日:1991-06-12
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , BOEHME RALF
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:DE59109087D1
公开(公告)日:1999-02-25
申请号:DE59109087
申请日:1991-06-12
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO DR
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:AT175688T
公开(公告)日:1999-01-15
申请号:AT91109640
申请日:1991-06-12
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO DR
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:DK0433822T3
公开(公告)日:1994-04-18
申请号:DK90123652
申请日:1990-12-08
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , HINZ WERNER DR
IPC: C07C69/63 , C07C69/635 , C07C69/65 , C07C69/76 , C07C69/78 , C07C271/14 , C07C271/24 , C07C271/28 , C08G65/32 , C08G65/332 , C08G65/333 , C08G65/337 , C08J9/00 , C08K5/10 , C09K23/42
Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.
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公开(公告)号:DE59003792D1
公开(公告)日:1994-01-20
申请号:DE59003792
申请日:1990-12-08
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , HINZ WERNER DR
IPC: C07C69/63 , C07C69/635 , C07C69/65 , C07C69/76 , C07C69/78 , C07C271/14 , C07C271/24 , C07C271/28 , C08G65/32 , C08G65/332 , C08G65/333 , C08G65/337 , C08J9/00 , C08K5/10 , C09K23/42
Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.
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公开(公告)号:DE3941871A1
公开(公告)日:1991-06-20
申请号:DE3941871
申请日:1989-12-19
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , HINZ WERNER DR
IPC: C07C69/63 , C07C69/635 , C07C69/65 , C07C69/76 , C07C69/78 , C07C271/14 , C07C271/24 , C07C271/28 , C08G65/32 , C08G65/332 , C08G65/333 , C08G65/337 , C08J9/00 , C08K5/10 , C09K23/42
Abstract: The invention relates to novel esters which contain fluorocarbon and oxypropylenealkyl ether groups in bonded form, of the formulae in which: Rf is a linear or branched, partially fluorinated or perfluorinated alkyl group having 2 to 10 carbon atoms, a partially fluorinated or perfluorinated cycloalkyl group having 4 to 8 carbon atoms, a perfluorophenyl group or a perfluoroalkylphenyl group having 1 to 6 carbon atoms in the perfluoroalkyl radical, R is a linear or branched alkyl group having 1 to 4 carbon atoms and n is an integer from 2 to 70, to storage-stable, blowing agent-containing emulsions which contain at least one partially fluorinated or perfluorinated (cyclo)aliphatic hydrocarbon having 3 to 8 C atoms and/or sulphur hexafluoride, at least one optionally modified organic polyisocyanate or a higher-molecular-weight reactive hydrogen compound and at least one of the abovementioned carboxylates or carbamidates, and to the use of these emulsions for the preparation of cellular plastics by the polyisocyanate polyaddition process.
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公开(公告)号:DE3933335A1
公开(公告)日:1991-04-11
申请号:DE3933335
申请日:1989-10-06
Applicant: BASF AG
Inventor: VOLKERT OTTO DR
IPC: B32B27/00 , C08G18/00 , C08G18/42 , C08G18/48 , C08G18/76 , C08J9/12 , C08J9/14 , C08L75/04 , F25D11/00
Abstract: The invention relates to a process for preparation of rigid polyurethane foams having low thermal conductivity by reacting …… a) organic and/or modified organic polyisocyanates with … b) at least one relatively high molecular weight compound having at least two reactive hydrogen atoms and optionally … c) low molecular weight chain extenders and/or crosslinking agents in the presence of … d) cyclopentane (d1) or mixtures (d2) which contain: …… d2i) cyclopentane and/or cyclohexane and … d2ii) at least one compound which is homogeneously miscible with cyclopentane and/or cyclohexane and preferably has a boiling point below 35 DEG C, selected from the group consisting of the alkanes, cycloalkanes having not more than 4 carbon atoms, dialkyl ethers, cycloalkylene ethers and fluoroalkanes,… optionally in conjunction with water, as blowing agents (d), …… e) catalysts and optionally … f) auxiliaries and/or additives. …… The rigid polyurethane foams are used in the refrigerator industry and as insulating material in heating and composite elements.
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公开(公告)号:DE3569747D1
公开(公告)日:1989-06-01
申请号:DE3569747
申请日:1985-02-01
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , GEORG GERHARD
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