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公开(公告)号:DE3767194D1
公开(公告)日:1991-02-14
申请号:DE3767194
申请日:1987-03-04
Applicant: BASF AG
Inventor: HORN PETER DR , CHAKRABARTI SARBANANDA , BOEHME RALF , SCHMIDT HANS ULRICH , STREU JOACHIM DR
IPC: B29C33/60 , C08G18/28 , C08G18/34 , C08G18/65 , C08J9/00 , C08K5/09 , C08K5/098 , C08K5/17 , C08K5/20 , C08K13/00
Abstract: A process for the production of mouldings having a cellular core and a compacted peripheral zone and improved demoulding properties by the polyisocyanate polyaddition process, by reacting a) organic polyisocyanates b) relatively high-molecular-weight compounds containing at least 2 reactive hydrogen atoms, and, if desired, c) low-molecular-weight polyhydric alcohols, polyoxyalkylene-polyols and/or secondary aromatic diamines in the presence of d) an internal mould release agent, comprising A) from 0.1 to 12% by weight, based on the total weight of components (b) and (c), of a mixture of i) from 5 to 80 parts by weight of at least one organic amine, and ii) from 20 to 95 parts by weight of at least one metal salt of stearic acid, and B) from 0.01 to 32% by weight, based on the total weight of components (b) and (c), of at least one organic mono- and/or dicarboxylic acid or anhydrides thereof, e) catalysts, f) blowing agents, and, if desired, g) assistants and/or additives, in a closed mould with compaction, expediently using the low-pressure or preferably reaction injection moulding technique.
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公开(公告)号:AT59805T
公开(公告)日:1991-01-15
申请号:AT87103022
申请日:1987-03-04
Applicant: BASF AG
Inventor: HORN PETER DR , CHAKRABARTI SARBANANDA , BOEHME RALF , SCHMIDT HANS ULRICH , STREU JOACHIM DR
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公开(公告)号:DK0463479T3
公开(公告)日:1999-08-30
申请号:DK91109640
申请日:1991-06-12
Applicant: BASF AG
Inventor: VOLKERT OTTO DR , BOEHME RALF
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:DE59109087D1
公开(公告)日:1999-02-25
申请号:DE59109087
申请日:1991-06-12
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO DR
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:AT175688T
公开(公告)日:1999-01-15
申请号:AT91109640
申请日:1991-06-12
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO DR
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:DE3607447A1
公开(公告)日:1987-09-10
申请号:DE3607447
申请日:1986-03-07
Applicant: BASF AG
Inventor: HORN PETER DR , CHAKRABARTI SARBANANDA , BOEHME RALF , SCHMIDT HANS ULRICH , STREU JOACHIM DR
IPC: B29C33/60 , C08G18/28 , C08G18/34 , C08G18/65 , C08J9/00 , C08K5/09 , C08K5/098 , C08K5/17 , C08K5/20 , C08K13/00 , C08G18/14 , C08J9/34 , C08L75/04
Abstract: A process for the production of mouldings having a cellular core and a compacted peripheral zone and improved demoulding properties by the polyisocyanate polyaddition process, by reacting a) organic polyisocyanates b) relatively high-molecular-weight compounds containing at least 2 reactive hydrogen atoms, and, if desired, c) low-molecular-weight polyhydric alcohols, polyoxyalkylene-polyols and/or secondary aromatic diamines in the presence of d) an internal mould release agent, comprising A) from 0.1 to 12% by weight, based on the total weight of components (b) and (c), of a mixture of i) from 5 to 80 parts by weight of at least one organic amine, and ii) from 20 to 95 parts by weight of at least one metal salt of stearic acid, and B) from 0.01 to 32% by weight, based on the total weight of components (b) and (c), of at least one organic mono- and/or dicarboxylic acid or anhydrides thereof, e) catalysts, f) blowing agents, and, if desired, g) assistants and/or additives, in a closed mould with compaction, expediently using the low-pressure or preferably reaction injection moulding technique.
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公开(公告)号:DE4434604A1
公开(公告)日:1996-04-04
申请号:DE4434604
申请日:1994-09-28
Applicant: BASF AG
Inventor: HORN PETER DR , DENZINGER WALTER , FUCHS HARALD DR , BOEHME RALF
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公开(公告)号:DE4434604B4
公开(公告)日:2005-03-03
申请号:DE4434604
申请日:1994-09-28
Applicant: BASF AG
Inventor: HORN PETER , DENZINGER WALTER , FUCHS HARALD , BOEHME RALF
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公开(公告)号:ES2126557T3
公开(公告)日:1999-04-01
申请号:ES91109640
申请日:1991-06-12
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO DR
Abstract: A process for the preparation of cellular plastics, preferably rigid structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) catalysts and optionally f) assistants and/or additives. a
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公开(公告)号:CA2045192C
公开(公告)日:1996-09-10
申请号:CA2045192
申请日:1991-06-21
Applicant: BASF AG
Inventor: BOEHME RALF , VOLKERT OTTO
IPC: C08G18/00 , C08G18/30 , C08G18/65 , C08G18/66 , C08G101/00 , C08J9/02 , C08J9/14 , C08G18/08 , C08G18/10 , C08G18/48
Abstract: A process for the preparation of cellular plastics, preferably hard structural polyurethane foams, by the polyisocyanate polyaddition process involves reacting a) an organic and/or modified organic polyisocyanate with b) at least one high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired, c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of d) a blowing agent from the group comprising tertiary alcohols (di), preferably tertiary butanol, or a mixture of at least one tertiary alcohol (di) and water (dii), e) a catalyst and, if desired, f) assistants and/or additives.
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