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    1.
    发明专利
    未知

    公开(公告)号：DE1932892A1

    公开(公告)日：1971-01-07

    申请号：DE1932892

    申请日：1969-06-28

    Applicant: BASF AG

    Inventor： HANS HAAS DR ,  HEINRICH SPERBER DR ,  WILHELM FRIEDRICHSEN DR

    IPC: B01J23/881 ,  C07C45/38 ,  C07C45/00

    Abstract: The production of formaldehyde by oxidation of methanol in the presence of a catalyst in the form of oxides of iron and of molybdenum on a silicate carrier. The formaldehyde which can be prepared according to the process of the invention is a disinfectant, tanning material, reducing agent and valuable starting material for the production of synthetic resins, adhesives, plastics and auxiliaries for many industrial fields.

    Phthalic anhydride purif
    3.
    发明专利
    Phthalic anhydride purif 未知

    公开(公告)号：DE1935008A1

    公开(公告)日：1971-01-14

    申请号：DE1935008

    申请日：1969-07-10

    Applicant: BASF AG

    Inventor： WILHELM FRIEDRICHSEN DR ,  OTTO GOEHRE DR

    IPC: C07C51/573

    Abstract: Crude phthalic anhydride, obtained by catalytic oxidation of o-xylene or naphthalene, is subjected to a thermal treatment and a distillation. During the thermal treatment and/or the distillation it is heated to 200-350 degrees C in the liqiud or gaseous phase in the presence of a catalyst containing vanadium pentoxide.

    4.
    发明专利
    未知

    公开(公告)号：DE1442590A1

    公开(公告)日：1968-10-31

    申请号：DE1442590

    申请日：1965-05-18

    Applicant: BASF AG

    Inventor： WILHELM FRIEDRICHSEN DR ,  OTTO GOEHRE DR

    IPC: B01J23/22 ,  B01J23/24 ,  B01J23/68 ,  B01J23/84 ,  B01J23/89 ,  B01J37/02 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  C07C51/31 ,  B01J11/06

    Abstract: 1,140,264. Oxidation of hydrocarbons. BADISCHE ANILIN- & SODA-FABBIK A.G. 17 May, 1966 [18 May, 1965], No. 21781/66. Heading C2C. [Also in Division B1] Aromatic hydrocarbons may be oxidized to carboxylic acids, for example o-xylene may be oxidized to phthalic anhydride+maleic anhydride, using a catalyst consisting of an inert porous carrier coated with a 0À02 to 2 mm. thick layer of a composition containing 1% to 15% by weight of vanadium pentoxide and 85% to 99% by weight of titanium dioxide, the catalyst containing from 0À05% to 3% by weight of vanadium pentoxide. In the examples, vapour phase o-xylene and air are passed over the catalyst in a tube heated by a salt-bath, the reaction temperature being: (1), (4), and (5) 400‹ C.; (2) and (7) 390‹ C.; (3) 380‹ C.; (6) 410‹ C. Also mentioned are oxidation of propylene to acetic acid; butene-(1 butene-(2) or butadiene-(1,3) to maleic acid; benzene to maleic acid; naphthalene to phthalic acid; toluene to benzoic acid; methyl naphthalenes to naphthoic acids; durene to pyromellitic acid.

    5.
    发明专利
    未知

    公开(公告)号：DE1921467A1

    公开(公告)日：1970-11-19

    申请号：DE1921467

    申请日：1969-04-26

    Applicant: BASF AG

    Inventor： HUBERT CORR DR ,  WILHELM FRIEDRICHSEN DR ,  GUENTER POEHLER DR

    IPC: B01J23/24 ,  B01J37/02 ,  C07C5/10 ,  C07C209/48 ,  B01J11/46

    Abstract: 1307301 Catalytic hydrogenation BADISCHE ANILIN- & SODA-FABRIK AG 24 April 1970 [26 April 1969] 19809/70 Heading C2C [Also in Divisions B1 and C5] A catalytic hydrogenation process comprises hydrogenating a hydrogenatable organic material at elevated temperature and pressure, the hydrogenatable material being in substantially liquid phase, in the presence of one or more supported metals in Groups VIII, VIIb or VIb of the Mendeleef Periodic Table acting as-catalyst, said catalyst having been made by spraying a shaped support with a solution or suspension containing one or more metals and/or compounds of metals contained in Group VIII, VIIb or VIb of the Mendeleef Periodic Table, at a temperature ranging from 150‹ to 500‹ C. Preferably basifying metal compounds and bonding agents are also sprayed on and after the spraying process the catalyst and support are heated to 300‹ to 1000‹ C. to convert the metal compounds to the corresponding oxides. Examples describe the catalytic hydrogenation of diamino diphenyl alkanes and their ethers to diamino dicyclohexyl alkanes and their ethers; of anilines and nitrobenzenes to cyclohexylamines, cycloalkanones and phenols to cycloalkanols, aliphatic nitriles to aliphatic amines and aliphatic carboxylic acids to aliphatic alcohols.

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