公开(公告)号：DE1194410B

公开(公告)日：1965-06-10

申请号：DEB0070118

申请日：1962-12-22

Applicant: BASF AG

Inventor： MUELLER DR HERBERT ,  SCHARF DR EMIL ,  WITTENBERG DR DIETMAR

IPC: B01J31/20 ,  C07C2/40 ,  C07C2/46 ,  C07C11/21 ,  C07C13/19 ,  C07F15/04

公开(公告)号：DE1240852B

公开(公告)日：1967-05-24

申请号：DEB0075905

申请日：1964-03-14

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR ,  MUELLER DR HERBERT

IPC: C07C5/31

公开(公告)号：DE1204669B

公开(公告)日：1965-11-11

申请号：DEB0072528

申请日：1963-07-04

Applicant: BASF AG

Inventor： MUELLER DR HERBERT ,  WITTENBERG DR DIETMAR ,  SCHARF DR EMIL

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  C07C2/02 ,  C07C2/46

公开(公告)号：DE1179932B

公开(公告)日：1964-10-22

申请号：DEB0068300

申请日：1962-08-03

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR

IPC: C07C17/275 ,  C08K5/02

公开(公告)号：DE1124947B

公开(公告)日：1962-03-08

申请号：DEB0060432

申请日：1960-12-10

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR

IPC: B01J31/12 ,  C07F7/22 ,  D06L1/14 ,  D06L3/08 ,  D06L4/26 ,  F16D55/00 ,  F16D55/226 ,  F16D65/14 ,  F16D65/58

Abstract: Aryltin compounds are prepared by reacting a tin compound of formula SnXmYn where X is a mononuclear or dinuclear aryl radical which may be substituted by one or two C1-C4 alkyl radicals, Y is halogen, m is 0, 1, 2 or 3, n is 1, 2, 3 or 4, and m + n is 4, with at least one aryl aluminium compound of formula AlX3, AlX2Y or AlXY2 where X and Y have the meanings given above, at a temperature of between -50 DEG and 200 DEG C. Preferred tin compounds are tin tetrachloride and tin tetrabromide. If desired, tin complexes with ethers, tertiary amines or alkali metal halides may be used: specified are sodium and potassium hexachlorostannates (iv); potassium hexabromostannate (iv); SnBr4(C2H5)2O; SnCl4.CH3OC6H5; SnCl4. (C8H5)2O; SnCl4.2(C5H5)N; SnCl4.2N(C4H9)3; SnCl4.2(C2H5)3N; and SnBr4(CH3)3N. If desired, the aryl aluminium compound may be prepared in situ by heating aluminium dust, powder or grit which has been activated by small amounts of a halogen, hydrogen halide, a metal halide or an organometallic compound, with an aryl halide such as chlorobenzene, bromobenzene, 4-bromotoluene, 3-chloro-4-methyltoluene, 2-chlorotoluene, 4-chlorocumene, a -chloronaphthalene or 4-chlorodiphenyl. This process may be carried out in an inert solvent such as benzene, toluene, xylenes, cyclohexane or n-heptane. In the reaction with the tin compound aluminium halide is produced and this may be removed by complexing with an aromatic or aliphatic ether or thioether, a tertiary amine or an alkali metal or alkaline earth metal halide, thus allowing the desired aryl tin to be recovered by distillation or, in some cases, fractional crystallisation.

公开(公告)号：DE1109674B

公开(公告)日：1961-06-29

申请号：DEB0055991

申请日：1959-12-22

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR ,  MUELLER DR HERBERT

IPC: C07C2/46

公开(公告)号：DE1268614B

公开(公告)日：1968-05-22

申请号：DE1268614

申请日：1963-03-07

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR ,  MUELLER DR HERBERT

公开(公告)号：DE1233144B

公开(公告)日：1967-01-26

申请号：DEB0075265

申请日：1964-02-01

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR ,  STEDEN DR FRANZ

IPC: C08G59/42

公开(公告)号：DE1231900B

公开(公告)日：1967-01-05

申请号：DEB0081981

申请日：1965-05-18

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR ,  MUELLER DR HERBERT

IPC: C08F36/04 ,  C08F136/06

公开(公告)号：DE1216286B

公开(公告)日：1966-05-12

申请号：DEB0063864

申请日：1961-09-01

Applicant: BASF AG

Inventor： WITTENBERG DR DIETMAR

IPC: C07C2/40