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1.发明申请ELECTROCHEMICAL ALKOXYLATING OXIDATIVE CARBON-CARBON BOND CLEAVAGE IN 1,2-DIPHENYLETHANE AND DERIVATIVES THEREOF ON A DIAMOND ELECTRODE 审中-公开电化学氧化的烷氧基化炭键裂解AM 1,2-二苯基乙烷及其衍生物AT的金刚石电极
公开(公告)号：WO2005066390A3
公开(公告)日：2005-09-22
申请号：PCT/EP2005000085
申请日：2005-01-07
Applicant: BASF AG , GRIESBACH ULRICH , PUETTER HERMANN , ZOLLINGER DANIEL
Inventor： GRIESBACH ULRICH , PUETTER HERMANN , ZOLLINGER DANIEL
IPC: C25B3/02
CPC classification number: C25B3/02
Abstract: The invention relates to a method for the electrolytic oxidative alkoxylating cleavage of 1,2-diarylethane derivatives by electrolytically oxidizing the respective 1,2-diarylethane derivative in a solvent containing the alcohol required for alkoxylation, electrolytic oxidation being performed on a diamond electrode. The inventive method makes it possible to especially produce diaryl derivatives when a 1,2-diarylethane derivative in which the two aryl radicals are directly bonded to each other is used as a substrate.
Abstract translation: 本发明涉及一种用于通过在含有必需的烷氧基化醇，其中所述电解氧化在金刚石电极进行溶剂中的相应的1,2- Diarylethanderivats的电解氧化烷氧基化1,2- Diarylethanderivaten的电解氧化裂解 ， 特别是本发明的方法允许联芳基衍生物的制备中，当1,2- Diarylethanderivat被用作衬底，其中，所述两个芳基直接连接到彼此。
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公开(公告)号：DE102004001586A1
公开(公告)日：2005-08-11
申请号：DE102004001586
申请日：2004-01-09
Applicant: BASF AG
Inventor： GRIESBACH ULRICH , PUETTER HERMANN , ZOLLINGER DANIEL
Abstract: The invention relates to a method for the electrolytic oxidative alkoxylating cleavage of 1,2-diarylethane derivatives by electrolytically oxidizing the respective 1,2-diarylethane derivative in a solvent containing the alcohol required for alkoxylation, electrolytic oxidation being performed on a diamond electrode. The inventive method makes it possible to especially produce diaryl derivatives when a 1,2-diarylethane derivative in which the two aryl radicals are directly bonded to each other is used as a substrate.
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