MOLECULAR SIEVE CATALYST COMPOSITIONS, CATALYTIC COMPOSITES, SYSTEMS, AND METHODS

    公开(公告)号:CA2952437A1

    公开(公告)日:2015-12-23

    申请号:CA2952437

    申请日:2015-06-17

    Applicant: BASF CORP

    Abstract: Described is a selective catalytic reduction catalyst comprising a zeolitic framework material of silicon and aluminum atoms, wherein a fraction of the silicon atoms are isomorphously substituted with a tetravalent metal. The catalyst can include a promoter metal such that the catalyst effectively promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 to 650 °C. In another aspect, described is a selective catalytic reduction composite comprising an SCR catalyst material and an ammonia storage material comprising a transition metal having an oxidation state of IV. The SCR catalyst material promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 °C to 600 °C, and the SCR catalyst material is effective to store ammonia at temperatures of 400 °C and above. A method for selectively reducing nitrogen oxides, and a method for simultaneously selectively reducing nitrogen oxide and storing ammonia are also described. Additionally, an exhaust gas treatment system is also described.

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