SOFT ARYLALKYLEPOXY RESIN
    1.
    发明专利

    公开(公告)号:JP2000044656A

    公开(公告)日:2000-02-15

    申请号:JP23169899

    申请日:1999-08-18

    Applicant: BASF CORP

    Abstract: PROBLEM TO BE SOLVED: To obtain a soft arylalkylepoxy resin containing the addition reaction product of a diol to epoxide compounds and capable of being reacted with an amine to give an amine resin used for electrodeposition coatings having extremely high resistance against the corrosions of metal surfaces and having high strengths. SOLUTION: This epoxide compound contains the addition reaction oligomer of (A) a monomer diol D1 having at least two aryl groups between the hydroxy groups to (B) a diepoxide E1 which is the bis(glycidyl ether) of the component A and (C) a diepoxide E2 which is a bis(unstable hydrogen functional compound alkoxy)arylene bis(glycidyl ether). The component A preferably has the chemical formula: HO-Ar1-OH (Ar1 is naphthalene, a C-C bond or the like), and the components B and C preferably have the chemical formulas: I and II (R1 is a 1-8C alkyl or a 2-8C alkoxyalkyl; X is O, S or the like; Ar2 is naphthalene, a 1-5C alkylene or the like), respectively.

    METHOD FOR MODIFIED AMINOPLAST COMPOUND, AMINOPLAST COMPOUND PRODUCED THEREBY, AND COATING MATERIAL CONTAINING THE SAME

    公开(公告)号:JPH111534A

    公开(公告)日:1999-01-06

    申请号:JP15535897

    申请日:1997-06-12

    Applicant: BASF CORP

    Abstract: PROBLEM TO BE SOLVED: To provide a method for decreasing molecular weight of an aminoplast compound, to obtain the aminoplast compound by this method, and the coating material composition containing the aminoplast compound of decreased molecular weight. SOLUTION: This aminoplast compound of decreased molecular weight is obtained by reacting (A) an aminoplast compound with a reactive substituent on the nitrogen atom in the amino group, the reactive substituent being selected from the group consisting of NH, alkylol, alkoxy, alkoxyalkyl and a mixture thereof, with (B) at least one carbamic acid ester selected from the group consisting of (substituted) primary carbamic acid ester, (substituted) secondary carbamic acid ester and a mixture thereof, at below 150 deg.C and atmospheric pressure to 20 atm in the presence of a primary or secondary alcohol, to substitute at least one equivalent to E-1/E equivalents of the amino substituent on the aminoplast by the functional group in the carbamic acid ester, thereby forming the aminoplast compound with the functional group (E is equivalent number of the reactive substituent per mol of the aminoplast compound).

    Method for modified aminoplast compounds, aminoplasts obtained thereby and coatings containing the same
    3.
    发明公开
    Method for modified aminoplast compounds, aminoplasts obtained thereby and coatings containing the same 失效
    一种用于改性氨基塑料的制备方法,由此涂布剂制备的这些氨基树脂

    公开(公告)号:EP0814104A2

    公开(公告)日:1997-12-29

    申请号:EP97108358

    申请日:1997-05-23

    Applicant: BASF CORP

    Abstract: A method for reducing the molecular weight of aminoplast compounds, the aminoplast compounds obtained thereby, and coating compositions containing said aminoplast compounds are provided. The reduced molecular weight aminoplasts are obtained by reacting (a) an aminoplast compound, having a total number (y) of reactive substituents on the amino nitrogens of the aminoplast, where y= (E x M) and E = equivalents per mole of aminoplast and M= total number of moles of aminoplast, wherein the reactive substituents are selected from the group consisting of -NH, alkylol, alkoxy, alkoxyalkyl, and mixtures thereof and (b) at least one carbamate compound selected from the group consisting of unsubstituted and substituted primary carbamate compounds, unsubstituted and substituted secondary carbamate compounds and mixtures thereof, in the presence of primary or secondary alcohols, at temperatures under 150 DEG C, and at pressures ranging between atmospheric pressure and 20 atm pressure, to form a functionalized aminoplast compound, wherein at least one and up to (y-1) of the amino substituents on the aminoplast are substituted with the carbamate functionality.

    Abstract translation: 一种用于降低氨基塑料化合物,由此获得的氨基塑料化合物,和涂料组合物的分子量的方法含有所述氨基塑料中提供的化合物。 降低的分子量的氨基塑料是通过使(a)氨基塑料化合物,具有反应性取代基的氨基塑料的氨基氮的总数(y)的获得,其中y =(E×M个)和E =每氨基塑料的摩尔当量 和M =被选自-NH,烷醇基,烷氧基,烷氧基烷基,以及它们的混合物和(b)至少一种氨基甲酸酯化合物,以及选自由unsubstituiertem选择氨基塑料的摩尔数,worin的反应性取代基的总数和 substituiertem伯氨基甲酸酯化合物,unsubstituiertem和substituiertem仲氨基甲酸酯化合物及其混合物,在伯或仲醇的存在下,在低于150℃的温度,并且在压力大气压和20大气压之间的范围内,以形成官能化的氨基塑料化合物, worin至少一个和最多(Y-1)上的氨基塑料的氨基取代基的是substituiertem与氨基甲酸酯功能。

    4.
    发明专利
    未知

    公开(公告)号:AT336553T

    公开(公告)日:2006-09-15

    申请号:AT97953219

    申请日:1997-12-10

    Applicant: BASF CORP

    Abstract: The present invention relates to a coating composition containing a combination of ultraviolet light absorbing compounds, one or more of which is bound to a polymer, and a method for reducing degradation of coating compositions due to ultraviolet light exposure.

    7.
    发明专利
    未知

    公开(公告)号:BR9506118A

    公开(公告)日:1997-12-23

    申请号:BR9506118

    申请日:1995-12-28

    Applicant: BASF CORP

    Abstract: A method of preparing a carbamate-functional acrylic polymer is described, comprising the steps of: (A) preparing a mixture comprising: (1) one or more acrylic monomers comprising hydroxy-functional groups or groups that can be converted to hydroxy functional groups, (2) optionally, one or more other addition polymerizable monomers, and (3) a carbamate compound, and (B) heating said mixture in the presence of a free radical initiator and an esterification catalyst, thereby forming a carbamate-functional acrylic polymer.

    9.
    发明专利
    未知

    公开(公告)号:AT268797T

    公开(公告)日:2004-06-15

    申请号:AT97122649

    申请日:1997-12-22

    Applicant: BASF CORP

    Abstract: A crosslinking agent comprising one or more carbamate groups or groups convertible to carbamate and two or more polyfunctional amino moieties having the formula ,wherein L is selected from the group consisting of alkyl or aryl, cycloalkyl and alkylaryl having a carbon chain length between 1 and 6 carbon atoms and N is a polyfunctional amino moiety. L may also have additional bridging groups such as eaters, ethers, ureas, or urethanes groups. Also included is a method of making the croselinker, a coating composition containing the crosslinker and a method for coating a substrate with the composition.

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