公开(公告)号：EP3071311A4

公开(公告)日：2017-06-28

申请号：EP14864951

申请日：2014-11-17

Applicant: BASF SE

Inventor： KERN HOLGER ,  HAMERS CHRISTOPH ,  MÖLLER KLAUS ,  ALBRECHT UWE

IPC: B01D19/04 ,  D21H21/12

CPC classification number: D21H21/12 ,  B01D19/0404 ,  C11D3/0026 ,  D21C3/28 ,  D21H17/04 ,  D21H17/06 ,  D21H17/14

Abstract: An antifoaming agent, based on an oil-in-water emulsion in which the oil phase accounts for from 5-50% by weight of the emulsion, where the oil phase includes: (a) at least one selected from the group consisting of (a1) an alcohol of not less than 12 carbon atoms and (a2) a C1-C36-carboxylic acid, a distillation residue; (d) a component including (d1) a polyglyceryl ester and (d2) a C18-C30 alkyl behenate, wherein the component (d) accounts for 1-80% by weight of the oil phase of the emulsion.

Abstract translation: 本发明为造纸工业提供基于水包油乳液的消泡剂，其中油相占乳液重量的5-50％，如果乳液油相含有（a）一种 不少于12个碳原子的醇，不少于22个碳原子的醇的脂肪酯和C1-C36-羧酸，可以通过羰基合成在制备具有相对大量碳原子的醇中获得的蒸馏残余物 或齐格勒方法，并且还可以是烷氧基化的，所述化合物的混合物和（b）任选地C12-C22-羧酸与一元至三元C1-C18-醇的脂肪酯，和（c）任选地 沸点高于200℃的烃或碳原子数为12至22的脂肪酸与1-80重量％的组分（d）组合，所述组分（d）包含（d1）聚甘油酯，其可通过不少于 20％酯化polygl 单甘油0至10重量％，双甘油15至40重量％，三甘油30至55重量％，四甘油10至25重量％，0至15重量％ 的五甘油，0-10重量％的六甘油和0-5重量％的与一种或多种12至36个碳原子的脂肪酸具有更高缩合度的聚甘油; 和（d2）山ate酸C18-C30烷基酯。 消泡剂可用于防止纸浆蒸煮中的泡沫，纸料的打浆，造纸和造纸用颜料的分散。 此外，消泡剂可用于防止纸料中的泡沫。

公开(公告)号：BR112016010920B1

公开(公告)日：2022-02-22

申请号：BR112016010920

申请日：2014-11-17

Applicant: BASF SE

Inventor： HAMERS CHRISTOPH ,  KERN HOLGER ,  MÖLLER KLAUS ,  ALBRECHT UWE

IPC: B01D19/04 ,  D21H21/12

Abstract: agente antiespumante para a indústria de papel, e, processos para evitar espuma a presente invenção que provê agentes antiespumantes para a indústria de papel, à base de emulsões de óleo em água, em que a fase óleo representa de 5 a 50% em peso da emulsão se a fase óleo das emulsões contém (a) um álcool de não menos do que 12 átomos de carbono, ésteres graxos de álcoois de não menos do que 22 átomos de carbono e ácidos carboxílicos c1-c36, resíduos de destilação que são obteníveis na preparação de álcoois tendo um número relativamente grande de átomos de carbono pela síntese de oxo ou pelo método de ziegler e que podem, além disso, ser alcoxilados, uma mistura dos compostos especificados e (b) opcionalmente um éster graxo de um ácido carboxílico c12-c22 com um álcool c1-c18 mono-hídrico ou tri-hídrico e, (c) opcionalmente um hidrocarboneto tendo um ponto de ebulição acima de 200°c ou um ácido graxo de 12 a 22 átomos de carbono, em combinação com de 1 a 80% em peso do componente (d) compreendendo (d1) ésteres poliglicerílicos que são obteníveis por não menos do que 20% de esterificação de uma mistura de poliglicerol de 0 a 10% em peso de monoglicerol, de 15 a 40% em peso de diglicerol, de 30 a 55% em peso de triglicerol, de 10 a 25% em peso de tetraglicerol, de 0 a 15% em peso de pentaglicerol, de 0 a 10% em peso de hexaglicerol e de 0 a 5% em peso de poligliceróis tendo graus superiores de condensação com um ou mais ácidos graxos de 12 a 36 átomos de carbono; e (d2) beenato de alquila c18-c30. os agentes antiespumantes podem ser usados para evitar espuma no cozimento da polpa, na batedura da carga de papel, na fabricação de papel e na dispersão de pigmentos para fabricação de papel. além disso, os agentes antiespumantes podem ser usados para evitar espuma nas cargas de papel.

公开(公告)号：CA2927406C

公开(公告)日：2019-06-25

申请号：CA2927406

申请日：2014-11-17

Applicant: BASF SE

Inventor： KERN HOLGER ,  HAMERS CHRISTOPH ,  MOLLER KLAUS ,  ALBRECHT UWE

IPC: D21H21/12

Abstract: The present invention which provides antifoaming agents for the paper industry, based on oil-in- water emulsions, in which the oil phase accounts for from 5 to 50% by weight of the emulsion if the oil phase of the emulsions contains (a) an alcohol of not less than 12 carbon atoms, fatty esters of alcohols of not less than 22 carbon atoms and C1-C36-carboxylic acids, distillation residues which are obtainable in the preparation of alcohols having a relatively large number of carbon atoms by the oxo synthesis or by the Ziegler method and which may furthermore be alkoxylated, a mixture of the stated compounds and (b) optionally a fatty ester of a C12-C22-carboxylic acid with a monohydric to trihydric C1-C18-alcohol and, (c) optionally a hydrocarbon having a boiling point above 200°C or a fatty acid of 12 to 22 carbon atoms, in combination with from 1 to 80% by weight of component (d) comprising (d1) polyglyceryl esters which are obtainable by not less than 20% esterification of a polyglycerol mixture of from 0 to 10% by weight of monoglycerol, from 15 to 40% by weight of diglycerol, from 30 to 55% by weight of triglycerol, from 10 to 25% by weight of tetraglycerol, from 0 to 15% by weight of pentaglycerol, from 0 to 10% by weight of hexaglycerol and from 0 to 5% by weight of polyglycerols having higher degrees of condensation with one or more fatty acids of 12 to 36 carbon atoms; and (d2) C18-C30 alkyl behenate. The antifoaming agents can be used for preventing foam in pulp cooking, in the beating of pa- per stock, in papermaking and in the dispersing of pigments for papermaking. Further, the anti- foaming agents can be used for preventing foam in paper stocks.

公开(公告)号：CA2927406A1

公开(公告)日：2015-05-28

申请号：CA2927406

申请日：2014-11-17

Applicant: BASF SE

Inventor： KERN HOLGER ,  HAMERS CHRISTOPH ,  MOLLER KLAUS ,  ALBRECHT UWE

IPC: B01D19/04 ,  D21H21/12

Abstract: The present invention which provides antifoaming agents for the paper industry, based on oil-in- water emulsions, in which the oil phase accounts for from 5 to 50% by weight of the emulsion if the oil phase of the emulsions contains (a) an alcohol of not less than 12 carbon atoms, fatty esters of alcohols of not less than 22 carbon atoms and C1-C36-carboxylic acids, distillation residues which are obtainable in the preparation of alcohols having a relatively large number of carbon atoms by the oxo synthesis or by the Ziegler method and which may furthermore be alkoxylated, a mixture of the stated compounds and (b) optionally a fatty ester of a C12-C22-carboxylic acid with a monohydric to trihydric C1-C18-alcohol and, (c) optionally a hydrocarbon having a boiling point above 200°C or a fatty acid of 12 to 22 carbon atoms, in combination with from 1 to 80% by weight of component (d) comprising (d1) polyglyceryl esters which are obtainable by not less than 20% esterification of a polyglycerol mixture of from 0 to 10% by weight of monoglycerol, from 15 to 40% by weight of diglycerol, from 30 to 55% by weight of triglycerol, from 10 to 25% by weight of tetraglycerol, from 0 to 15% by weight of pentaglycerol, from 0 to 10% by weight of hexaglycerol and from 0 to 5% by weight of polyglycerols having higher degrees of condensation with one or more fatty acids of 12 to 36 carbon atoms; and (d2) C18-C30 alkyl behenate. The antifoaming agents can be used for preventing foam in pulp cooking, in the beating of pa- per stock, in papermaking and in the dispersing of pigments for papermaking. Further, the anti- foaming agents can be used for preventing foam in paper stocks.