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公开(公告)号：CA2862155A1
公开(公告)日：2013-07-04
申请号：CA2862155
申请日：2012-12-27
Applicant: BASF SE
Inventor： LIMBACH MICHAEL , LINDNER RONALD , LEJKOWSKI MICHAEL LUDWIK , KAGEYAMA TAKEHARU , BODIZS GABRIELLA EVA , SCHUNK STEPHAN , FUTTER CORNELIA , ROTHER JORG
Abstract: In a process for preparing an alkalimetalor alkaline earth metal salt of an a,ß-ethylenically unsaturated carboxylic acid, a)a transition metal-alkene complex is reacted with CO2 to give a metallalactone, b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the a,ß-ethylenically unsaturated carboxylic acid with the transition metal complex, and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the a,ß-ethylenically unsaturated carboxylic acid and regenerate the transition metal-alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is, for example, ethene. The transition metal complex comprises, for example, nickel and a bidentate P,P, P,N, P,O or P,carbene ligand, such as 1,2-bis(di-tert-butylphosphino)ethane.
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2.发明专利
公开(公告)号：IN4656CHN2014A
公开(公告)日：2015-09-18
申请号：IN4656CHN2014
申请日：2014-06-19
Applicant: BASF SE
Inventor： LIMBACH MICHAEL , LINDNER RONALD , LEJKOWSKI MICHAEL LUDWIK , KAGEYAMA TAKEHARU , BODIZS GABRIELLA EVA , SCHUNK STEPHAN , FUTTER CORNELIA , ROTHER JÖRG
Abstract: a ß2 a ßa ßtertIn a process for preparing an alkalimetalor alkaline earth metal salt of an ethylenically unsaturated carboxylic acid a)a transition metal alkene complex is reacted with COto give a metallalactone b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the ethylenically unsaturated carboxylic acid with the transition metal complex and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the ethylenically unsaturated carboxylic acid and regenerate the transition metal alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is for example ethene. The transition metal complex comprises for example nickel and a bidentate P P P N P O or P carbene ligand such as 1 2 bis(di butylphosphino)ethane.
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3.发明公开PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES 审中-公开通过催化羧化烯烃ALPHA，BETA烯属不饱和羧酸盐的生产
公开(公告)号：EP2797869A4
公开(公告)日：2015-08-05
申请号：EP12861287
申请日：2012-12-27
Applicant: BASF SE
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