PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALTS BY THE CARBOXYLATION OF ALKENES
    2.
    发明申请
    PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALTS BY THE CARBOXYLATION OF ALKENES 审中-公开
    MANUFACTURING通过羧化烯烃烯属不饱和羧酸盐的

    公开(公告)号:WO2011107559A2

    公开(公告)日:2011-09-09

    申请号:PCT/EP2011053229

    申请日:2011-03-03

    Abstract: The invention relates to a method for producing an alkali or earth alkali salt of an a,ß-ethylenically unsaturated carboxylic acid, wherein a) an alkene, carbon dioxide and a carboxylation catalyst is reacted to form an alkene/carbon dioxide/carboxylation catalyst adduct, b) using an auxiliary base, the adduct is decomposed into the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the carboxylation catalyst, c) using an alkali or earth alkali metal base, the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid is reacted to form the alkali or earth alkali salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the auxiliary base. Salts of a,ß-ethylenically unsaturated carboxylic acids, such as in particular sodium acrylate, are required in large quantities, for example, for producing water-absorbing resins.

    Abstract translation: 一种用于产生一的碱金属或碱土金属的盐,β-烯属不饱和羧酸,其中a)的烯烃,二氧化碳和羧化催化剂的烯烃/二氧化碳/羧化催化剂的加合物反应,b)加合物与辅助碱释放羧化过程 分解成一个的辅助碱的盐,β-烯属不饱和羧酸,c)该一个的辅助碱的盐,β-烯属不饱和羧酸与具有碱金属或碱土金属碱的碱金属或碱土金属盐,SS-烯属不饱和的辅助碱的解放 羧酸反应。 盐,β-烯属不饱和羧酸,如尤其是钠,在大量使用,。 作为制造所需的水基树脂。

    PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALTS BY THE CARBOXYLATION OF ALKENES

    公开(公告)号:CA2791834A1

    公开(公告)日:2011-09-09

    申请号:CA2791834

    申请日:2011-03-03

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing an alkali or earth alkali salt of an a,ß-ethylenically unsaturated carboxylic acid, wherein a) an alkene, carbon dioxide and a carboxylation catalyst is reacted to form an alkene/carbon dioxide/carboxylation catalyst adduct, b) using an auxiliary base, the adduct is decomposed into the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the carboxylation catalyst, c) using an alkali or earth alkali metal base, the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid is reacted to form the alkali or earth alkali salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the auxiliary base. Salts of a,ß-ethylenically unsaturated carboxylic acids, such as in particular sodium acrylate, are required in large quantities, for example, for producing water-absorbing resins.

    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE

    公开(公告)号:ZA201404090B

    公开(公告)日:2017-05-31

    申请号:ZA201404090

    申请日:2014-06-05

    Applicant: BASF SE

    Abstract: A catalyst for the reforming of hydrocarbon-comprising compounds with CO2, water and/or hydrogen, a process for producing the same, and a process using the same for the reforming of the hydrocarbon-comprising compounds are provided. The production of the catalyst is based on contacting, intimately mixing and thermal treating of a hydrotalcite-comprising starting material with a fusible metal salt, which more preferably comprises nickel nitrate hexahydrate, to result in the metal salt melt. After molding and shaping, the compounds are subjected to high-temperature calcination step. In addition, the process using the catalyst for the reforming of the hydrocarbon-comprising compounds is carried out in a temperature range from 500 to 1100 °C at a pressure in the range from 2 to 70 bar. The catalyst is distinguished from the prior art by physicochemical properties.

    PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID

    公开(公告)号:CA2991075A1

    公开(公告)日:2017-01-26

    申请号:CA2991075

    申请日:2016-07-01

    Applicant: BASF SE

    Abstract: The present invention relates to a process forpreparingfuran-2,5-dicarboxylic acid, comprising the following steps: preparing or providing a starting mixture comprising5-(hydroxymethyl)furfural (HMF),5,5'-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water,subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst comprising one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also comprising water and oxidation by-products. Moreover the present invention relates to the use of a catalyst comprising one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

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