公开(公告)号：WO2010063672A3

公开(公告)日：2010-08-05

申请号：PCT/EP2009066042

申请日：2009-11-30

Applicant: BASF SE ,  TUERK HOLGER ,  DIELEMANN CEDRIC ,  BOHRMANN HANS-GUENTER ,  KOLTZENBURG SEBASTIAN

Inventor： TUERK HOLGER ,  DIELEMANN CEDRIC ,  BOHRMANN HANS-GUENTER ,  KOLTZENBURG SEBASTIAN

IPC: C08F2/04 ,  A01N25/04 ,  C08F220/58

CPC classification number: A01N25/10 ,  A01N43/653 ,  A01N47/24 ,  C08F2/04 ,  C08F2/06 ,  C08F220/06 ,  C08F220/18 ,  C08F220/56 ,  C08F220/58 ,  A01N2300/00

Abstract: The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I); wherein n is 0 to 10; X represents O or NR5; R1 represents hydrogen or methyl; R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7; R5 represents hydrogen or methyl; R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140°C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions.

Abstract translation: 一种用于无规自由基共聚物的制备方法的特征在于：a）式（I），其中n为0至10中的至少一个烯属不饱和磺酸; X是O或NR5; R1是氢或甲基; R2，R3独立地是氢或C1-C6烷基和R5是氢，烷基，芳基，烷基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二）芳基氨基，Alkylarylaminoalkyl或alkylarylaminoaryl ，其中该芳基基团可以被取代一次或多次，平均它们的盐或酸和盐，和b）至少两种结构不同的式（II），其中Y是O或NR 7的烯属不饱和单体的混合物; R5是氢或甲基; R 6是烷基，羟烷基，（二）烷基氨基烷基或（二）烷基氨基芳基，并且R 7是氢，烷​​基，芳基，烷基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二）芳基氨基，Alkylarylaminoalkyl 平均值或alkylarylaminoaryl，其中该芳基基团可以被取代一次或多次，和c）任选的一种或多种烯属不饱和单体，其在结构上是从组分（a）和（b）是不同的，d）至少一种引发剂无论是在（I） 溶剂混合物包含水和具有140℃以下的沸点的水溶性有机溶剂，溶解或（ii）在通过加热和聚合在溶液中，其中所形成的共聚物也溶解溶解一种或多种纯的醇。 通过该方法获得的共聚物适合作为农业化学活性成分组合物中的制剂助剂。

公开(公告)号：CA2745249A1

公开(公告)日：2010-06-10

申请号：CA2745249

申请日：2009-11-30

Applicant: BASF SE

Inventor： TUERK HOLGER ,  DIELEMANN CEDRIC ,  BOHRMANN HANS-GUENTER ,  KOLTZENBURG SEBASTIAN

IPC: C08F2/04 ,  A01N25/04 ,  C08F220/58

Abstract: The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I); wherein n is 0 to 10; X represents O or NR5; R1 represents hydrogen or methyl; R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7; R5 represents hydrogen or methyl; R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140°C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions.

公开(公告)号：MX2011005723A

公开(公告)日：2011-07-29

申请号：MX2011005723

申请日：2009-11-30

Applicant: BASF SE

Inventor： KOLTZENBURG SEBASTIAN ,  DIELEMAN CEDRIC ,  TUERK HOLGER ,  BOHRMANN HANS-GUENTER

IPC: C08F2/04 ,  A01N25/04 ,  C08F220/58

Abstract: Esta invención se relaciona a un método para producir copolímeros radicales aleatorios, caracterizados por las siguientes etapas: a) disolver mediante calentamiento a) al menos un ácido sulfónico olefínicamente insaturado de la fórmula (I); donde n es de 0 a 10; X representa O o NR5 R1 representa hidrógeno o metilo; R2, R3 independientemente representan hidrógeno o alquilo de 1 a 6 átomos de carbono y R5 representa hidrógeno, alquilo, arilo, alquilarilo, arilaquilo, alcoxialquilo, ariloxialquilo, alcoxiarilo, hidroxialquilo, (di)alquilaminoalquilo, (di)alquilaminoarilo, (di)arilaminoalquilo, alquilarilaminoalquilo o alquilarilaminoarilo, donde los grupos arilo pueden ser mono-o polisustituidos, las sales de los mismos o mezclas de ácidos y sales y b) al menos dos monómeros olefínicamente insaturados, estructuralmente distintos de la fórmula (II), en donde Y representa O o NR7 ; R5 represente hidrógeno o metilo; R6 representa alquilo, hidroxialquilo, (di)alquilaminoalquilo o (di)alquilaminoarilo y R7 representa hidrógeno, alquilo, arilo, alquilarilo, arilaquilo, alcoxialquilo, ariloxialquilo, alcoxiarilo, hidroxialquilo, (di) alquilaminoalquilo, (di) alquilaminoarilo, (di) arilaminoalquilo, alquilarilaminoalquilo, o alquilarilaminoarilo y c) opcionalmente uno o más monómeros olefínicamente insaturados que pueden ser estructuralmente distintos a partir de los componentes (a) y (b), y al menos un iniciador ya sea (i) en una mezcla de solvente que contiene agua y un solvente que tiene un punto de ebullición debajo de 140°C y es soluble en agua o (ii) en uno o más alcoholes puros y polimerizar la mezcla en solución, el copolímero formado también permanece disuelto. Los copolímeross optenibles de acuerdo al método anterior son adecuados como adyuvantes de formulación en composiciones de ingrediente activo agroquímico.

公开(公告)号：CA2745249C

公开(公告)日：2017-01-10

申请号：CA2745249

申请日：2009-11-30

Applicant: BASF SE

Inventor： TUERK HOLGER ,  DIELEMAN CEDRIC ,  BOHRMANN HANS-GUENTER ,  KOLTZENBURG SEBASTIAN

IPC: C08F2/04 ,  A01N25/04 ,  C08F220/58

Abstract: The invention provides a process for the preparation of random radical copolymers which comprises a) at least one olefinically unsaturated sulfonic acid of the formula (I), (see formula I) salts thereof or mixtures of acid and salts, b) at least two structurally different olefinically unsaturated monomers of the formula (II), (see formula II) c) if appropriate, one or more olefinically unsaturated monomers which differ structurally from components (a) and (b), and d) at least one initiator. Components a), b), c) and d) are dissolved either (i) in a solvent mixture comprising water and a water-soluble organic solvent with a boiling point of less than 140°C or (ii) in one or more pure alcohols by heating, and then polymerized in solution, the resulting copolymer remaining in solution. The copolymers which are obtainable by the process are suitable as formulation adjuvants in agrochemical active substance compositions.

公开(公告)号：AT548398T

公开(公告)日：2012-03-15

申请号：AT03750622

申请日：2003-09-25

Applicant: BASF SE

Inventor： KRUEGER CHRISTIAN ,  HEES ULRIKE ,  VAN GELDER RICHARD ,  FUESSER PETER ,  SCHULZ LOTHAR ,  BOHRMANN HANS-GUENTER ,  PUTTNER DIETER ,  EBERT SOPHIA

IPC: C08G18/08 ,  C08G18/66 ,  C08G18/76 ,  C08L75/06 ,  C09D11/00

Abstract: Disclosed are recording fluids, preferably inks for the ink jet process, containing random polyurethane copolymers and one or more melamine derivatives as crosslinkers.