公开(公告)号：WO2010106035A3

公开(公告)日：2011-01-06

申请号：PCT/EP2010053326

申请日：2010-03-16

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH

IPC: C01B25/45 ,  C01B25/26 ,  H01M4/00 ,  H01M4/58 ,  H01M4/62

CPC classification number: C01B25/45 ,  H01M4/5825

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bFe1-cM2 cPd-eM3 eOx, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1 : Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to obtain a compound of general formula (I).

Abstract translation: 本发明涉及制备通式（I）Lia-bM1 bFe1-cM2 cPd-eM3 eOx的化合物的方法，其中Fe具有氧化态+2和M1，M2，M3，a，b，c， d，e和x是：M1：Na，K，Rb和/或Cs，M2：Mn，Mg，Al，Ca，Ti，Co，Ni，Cr，V，M3：Si，S，F a： 1.9，b：0-0.3，c：0-0.9，d：0.8-1.9，e：0-0.5，x：1.0-8，这取决于Li，M1，M2，P，M3的量和氧化态， 其中通式（I）的化合物是中性带电的，包括以下步骤（A），提供包含至少一种含锂化合物，至少一种含铁化合物的混合物，其中铁具有氧化态为0，并且在 至少一种含M1化合物（如果存在）和/或至少一种含M2化合物（如果存在）和/或至少一种含M3化合物（如果存在）和至少一种包含至少一个磷原子的化合物 状态+5，和（B）在步骤（A）中获得的混合物的温度下加热 100〜500℃，自动压力，得到通式（I）的化合物。

公开(公告)号：WO2008125647A3

公开(公告)日：2009-10-15

申请号：PCT/EP2008054465

申请日：2008-04-14

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  PROELSS JULIAN

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  PROELSS JULIAN

IPC: C01G31/00 ,  H01M4/131 ,  H01M4/485 ,  H01M10/052

CPC classification number: C01G31/00 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M10/052 ,  H01M2300/0082 ,  H01M2300/0091

Abstract: The present invention relates to a method for the production of lithium-rich metal oxides and lithium-rich metal oxides obtainable using said method. The invention further relates to the use of lithium-rich metal oxides for the production of a cathode for a battery, particularly a lithium ion battery, and a cathode for a lithium ion battery containing lithium-rich metal oxides.

Abstract translation: 本发明涉及一种用于制备富锂的金属氧化物和通过该方法富锂的金属氧化物而得到的方法。 本发明Weiterhinbetrifft使用富锂的金属氧化物的用于制备阴极的用于电池，特别是锂离子电池和锂离子电池的阴极，其含有富锂的金属氧化物。

公开(公告)号：WO2008083897A2

公开(公告)日：2008-07-17

申请号：PCT/EP2007064049

申请日：2007-12-17

Applicant: BASF SE ,  MRONGA NORBERT ,  BRAMNIK KIRILL

Inventor： MRONGA NORBERT ,  BRAMNIK KIRILL

CPC classification number: C09C1/36 ,  C01G23/002 ,  C01P2004/80 ,  C01P2006/62 ,  C01P2006/65 ,  C01P2006/66 ,  C09C1/0009 ,  C09C1/0081

Abstract: The invention relates to pigments of empirical formula (TiO 2 ) a (ZnO) b (SnO) c (SnO 2 ) d (RE x O y ) e (EAO) f (M u O v ) g where RE is a metal of the third sub-group or a rare earth metal, EA is an earth alkali metal and M is any further metal, with a = 0.8 - 3; b = 0.5 - 1.3; c = 0.5 - 1.3; d = 0 - 0.5; e = 0 - 0.3; f = 0 - 0.3; g = 0 - 0.1, where e + f = 0.01. RE is preferably selected from the elements Y, La, Ce and Pr. The pigments are used for colouring paints, printing inks, inks, plastics and rubber.

Abstract translation: 颜料的经验组成（的TiO _{2 ）一（ZnO）的 B'/ SUB>（SNO） C （SNO 2 ）ð（RE X 0 ý）取值（EAO）˚F< / SUB>（M û 0 v ）克其中RE是过渡族3或稀土金属，EA碱土金属的金属，M是一 指任何另外的金属，其中a = 0.8〜3; B = 0.5〜1.3; C = 0.5〜1.3; D = 0至0.5; E = 0至0.3; F = 0至0.3; G = 0〜0.1，其中E + F = RE是优选0,01.20由元素Y，La，Ce和Pr中的颜料作为着色使用的涂料，印刷油墨，油墨，塑料和橡胶的着色剂..}

公开(公告)号：CA2721204A1

公开(公告)日：2009-10-22

申请号：CA2721204

申请日：2009-04-16

Applicant: BASF SE

Inventor： HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN KEITH ,  BRAMNIK KIRILL

IPC: C01B25/45 ,  H01M4/136 ,  H01M4/58 ,  H01M10/052

Abstract: The present invention relates to a Process for the preparation of compounds of general formula (I), Lia-bM1bFe1-cM2 cPd-eM3 eOx, wherein M1, M2, M3, a, b, c, d and e: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, Fe, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, (B) optionally drying the mixture provided in step (A), in order to obtain a solid compound and (C) calcining the solid compound obtained from step (A) or (B) at a temperature of 300 to 1000° C.

公开(公告)号：WO2010076265A2

公开(公告)日：2010-07-08

申请号：PCT/EP2009067742

申请日：2009-12-22

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHROEDLE SIMON

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHROEDLE SIMON

IPC: C01B25/45

CPC classification number: C01B25/45 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/0525

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bQ1-cM2 cPd-eM3 eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1 : Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one Q-comprising compound, in which Q has at least partially an oxidation state higher than +2, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to reduce Q to oxidation state +2 and to obtain a compound of general formula (I).

Abstract translation: 本发明涉及制备通式（Ⅰ）Lia-bM1bQ1-cM2cPd-eM3eOx（1）的化合物的方法，其中Q具有氧化态+2和M1，M2，M3，a，b ，c，d，e和x分别为：Q：Fe，Mn，Co，Ni，M1：Na，K，Rb和/或Cs，M2：Mg，Al，Ca，Ti，Co，Ni，Cr， Fe，Mn，其中Q和M2彼此不同，M3：Si，S，F a：0.8-1.9，b：0-0.3，c：0-0.9，d：0.8-1.9，e：0-0.5 ，x：1.0-8，其取决于Li，M1，M2，P，M3的量和氧化态，其中通式（I）的化合物是中性带电的，包括以下步骤（A），提供至少包含 一种含锂化合物，至少一种含Q的化合物，其中Q至少部分具有高于+2的氧化态，以及至少一种含M1化合物（如果存在）和/或至少一种含M2的化合物 化合物（如果存在）和/或至少一种含M3化合物（如果存在）和至少一种被还原的还原剂 一种化合物，其包含至少一种氧化态+5的磷原子，和（B）在100-500℃的温度和自发压力下加热步骤（A）中获得的混合物以将Q降低至氧化态+2 并得到通式（I）的化合物。

公开(公告)号：WO2010023129A3

公开(公告)日：2010-06-03

申请号：PCT/EP2009060657

申请日：2009-08-18

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  KHASANOVA NELLIE ,  ANTIPOV EVGENY ,  IVANISCHEV ALEXANDER

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  KHASANOVA NELLIE ,  ANTIPOV EVGENY ,  IVANISCHEV ALEXANDER

IPC: C01B25/455 ,  H01M4/58

CPC classification number: H01M4/5825 ,  C01B25/455 ,  C01P2002/78 ,  H01M4/136 ,  H01M10/0525

Abstract: Alkali transition metal fluorophosphates of the general Formula (1) Li1-?M1M 2 1-yM3 yPO4F (1), wherein 0 = x = 1, 0 = y =1, M1 = Li, Na, K, Rb, Cs, M2, M3 = Fe, Co, Ni, Mn, Cr, V, Ti, which give powder X-ray diffraction (XRD) patterns wherein the seven most intense reflexes occur at Bragg angels corresponding to distances between the planes in the atomic lattice of 5.51+0.4, 5.45+0.4, 3.83+0.3, 2.75+0.3, 2.72+0.3, 2.68+0.3 and 2.41+0.2 Angstrom.

Abstract translation: 通式（1）Li1-αM1M21-yM3 yPO4F（1）的碱金属过渡金属氟代磷酸酯，其中0 = x = 1,0 = y = 1，M1 = Li，Na，K，Rb，Cs，M2 ，M3 = Fe，Co，Ni，Mn，Cr，V，Ti，其产生粉末X射线衍射（XRD）图案，其中七个最强反射发生在布拉格天使，对应于原子格子中的平面之间的距离为5.51 +0.4,5.45 + 0.4,3.83 + 0.3,2.75 + 0.3,2.72±0.3,2.68±0.3及2.41±0.2埃。

公开(公告)号：WO2009043730A3

公开(公告)日：2009-10-29

申请号：PCT/EP2008062428

申请日：2008-09-18

Applicant: BASF SE ,  HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN ,  BRAMNIK KIRILL

Inventor： HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN ,  BRAMNIK KIRILL

IPC: C01B25/45 ,  H01M4/58 ,  H01M10/36

CPC classification number: C01B25/45 ,  H01M4/5825 ,  H01M10/0525

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bV2-cM2 c(PO4)x (I) with M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5 - 4.5, b: 0 - 0.6, c: 0 - 1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a-b is > 0, by providing an essentially aqueous mixture comprising at least one lithium-comprising compound, at least one vanadium-comprising compound in which vanadium has the oxidation state +5 and/or +4, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, drying and calcining.

Abstract translation: 本发明涉及制备具有M1：Na，K，Rb和/或Cs，M2：Ti，Zr的通式（I）Lia-bM1 bV2-cM2 c（PO4）x（Ⅰ）的化合物的方法 ，Nb，Cr，Mn，Fe，Co，Ni，Al，Mg和/或Sc，a：1.5〜4.5，b：0 - 0.6，c：0 - 1.98和x： 和M1和/或M2（如果存在），其中ab> 0，通过提供基本上含水的混合物，其包含至少一种含锂化合物，至少一种含钒化合物，其中钒具有+5和/或 +4，和至少一种含M1化合物（如果存在）和/或至少一种含M2化合物（如果存在）和至少一种还原剂被氧化成至少一种包含至少一个磷原子的化合物 氧化态+5，干燥和煅烧。

公开(公告)号：WO2009043729A3

公开(公告)日：2009-10-29

申请号：PCT/EP2008062427

申请日：2008-09-18

Applicant: BASF SE ,  HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN ,  BRAMNIK KIRILL

Inventor： HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN ,  BRAMNIK KIRILL

IPC: C01B25/45 ,  H01M4/136 ,  H01M4/58

CPC classification number: C01B25/45 ,  H01M4/136 ,  H01M4/5825

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) : Lia-bM1 bV2-cM2 c(PO4)x; wherein M1, M2, a, b, c and x have the following meanings: M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5 - 4.5, b: 0 - 0.6, c: 0 - 1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a-b is > 0, to a compound according to general formula (I) as defined above, to spherical agglomerates and/or particles comprising at least one compound of general formula (I) as defined above, to the use of such a compound for the preparation of a cathode of a lithium ion battery or an electrochemical cell, and to a cathode for a lithium ion battery, comprising at least one compound as defined above.

Abstract translation: 本发明涉及制备通式（I）化合物的方法：Lia-bM1 bV2-cM2 c（PO4）x; 其中M1，M2，a，b，c和x具有以下含义：M1：Na，K，Rb和/或Cs，M2：Ti，Zr，Nb，Cr，Mn，Fe，Co，Ni，Al，Mg 和/或Sc，a：1.5-4.5，b：0-0.6，c：0-1.98和x：使Li和V以及M1和/或M2的电荷（如果存在）相等的数量，其中ab> 涉及如上所定义的根据通式（I）的化合物，包含至少一种如上所定义的通式（I）的化合物的球形附聚物和/或颗粒，涉及这种化合物用于制备阴极的用途 锂离子电池或电化学电池以及用于锂离子电池的阴极，其包含至少一种如上定义的化合物。

公开(公告)号：CA2787373A1

公开(公告)日：2011-08-04

申请号：CA2787373

申请日：2011-01-28

Applicant: BASF SE

Inventor： LAMPERT JORDAN KEITH ,  BRAMNIK KIRILL ,  HEILEK JOERG

IPC: H01M4/28

Abstract: A process for producing oxidic compounds of the general formula (?) LizMxOy (?) wherein M is one or more elements from groups 2 to 12 of the periodic table, more particularly selected from Co, Mn, Ni, Fe, Al, Mg, x is 1 to 2, y is 2 to 4, and z is 0.5 to 1.5, comprises heating mixtures selected from oxides, hydroxides, carbonates and nitrates of Li and of M together to temperatures in the range from 600 to 1200? in a reaction vessel performing incomplete rotary motions about one axis.

公开(公告)号：DE502006004507D1

公开(公告)日：2009-09-24

申请号：DE502006004507

申请日：2006-01-23

Applicant: BASF SE

Inventor： BRAMNIK KIRILL ,  KORONA ECKHARD ,  MRONGA NORBERT

IPC: C09D7/12 ,  C08K3/24 ,  C09C1/00 ,  C09D17/00

Abstract: Use of bismuth vanadate pigments, comprising aluminum content greater than or equal to 1.4 wt.%, for coloring powder lacquers. An independent claim is included for a powder lacquer, comprising the bismuth vanadate pigments as the coloring components.