公开(公告)号：WO2010106035A3

公开(公告)日：2011-01-06

申请号：PCT/EP2010053326

申请日：2010-03-16

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH

IPC: C01B25/45 ,  C01B25/26 ,  H01M4/00 ,  H01M4/58 ,  H01M4/62

CPC classification number: C01B25/45 ,  H01M4/5825

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bFe1-cM2 cPd-eM3 eOx, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1 : Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to obtain a compound of general formula (I).

Abstract translation: 本发明涉及制备通式（I）Lia-bM1 bFe1-cM2 cPd-eM3 eOx的化合物的方法，其中Fe具有氧化态+2和M1，M2，M3，a，b，c， d，e和x是：M1：Na，K，Rb和/或Cs，M2：Mn，Mg，Al，Ca，Ti，Co，Ni，Cr，V，M3：Si，S，F a： 1.9，b：0-0.3，c：0-0.9，d：0.8-1.9，e：0-0.5，x：1.0-8，这取决于Li，M1，M2，P，M3的量和氧化态， 其中通式（I）的化合物是中性带电的，包括以下步骤（A），提供包含至少一种含锂化合物，至少一种含铁化合物的混合物，其中铁具有氧化态为0，并且在 至少一种含M1化合物（如果存在）和/或至少一种含M2化合物（如果存在）和/或至少一种含M3化合物（如果存在）和至少一种包含至少一个磷原子的化合物 状态+5，和（B）在步骤（A）中获得的混合物的温度下加热 100〜500℃，自动压力，得到通式（I）的化合物。

公开(公告)号：WO2010076265A2

公开(公告)日：2010-07-08

申请号：PCT/EP2009067742

申请日：2009-12-22

Applicant: BASF SE ,  BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHROEDLE SIMON

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHROEDLE SIMON

IPC: C01B25/45

CPC classification number: C01B25/45 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/0525

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bQ1-cM2 cPd-eM3 eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1 : Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one Q-comprising compound, in which Q has at least partially an oxidation state higher than +2, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to reduce Q to oxidation state +2 and to obtain a compound of general formula (I).

Abstract translation: 本发明涉及制备通式（Ⅰ）Lia-bM1bQ1-cM2cPd-eM3eOx（1）的化合物的方法，其中Q具有氧化态+2和M1，M2，M3，a，b ，c，d，e和x分别为：Q：Fe，Mn，Co，Ni，M1：Na，K，Rb和/或Cs，M2：Mg，Al，Ca，Ti，Co，Ni，Cr， Fe，Mn，其中Q和M2彼此不同，M3：Si，S，F a：0.8-1.9，b：0-0.3，c：0-0.9，d：0.8-1.9，e：0-0.5 ，x：1.0-8，其取决于Li，M1，M2，P，M3的量和氧化态，其中通式（I）的化合物是中性带电的，包括以下步骤（A），提供至少包含 一种含锂化合物，至少一种含Q的化合物，其中Q至少部分具有高于+2的氧化态，以及至少一种含M1化合物（如果存在）和/或至少一种含M2的化合物 化合物（如果存在）和/或至少一种含M3化合物（如果存在）和至少一种被还原的还原剂 一种化合物，其包含至少一种氧化态+5的磷原子，和（B）在100-500℃的温度和自发压力下加热步骤（A）中获得的混合物以将Q降低至氧化态+2 并得到通式（I）的化合物。

公开(公告)号：WO2012038270A2

公开(公告)日：2012-03-29

申请号：PCT/EP2011065597

申请日：2011-09-09

Applicant: BASF SE ,  SCHULZ-DOBRICK MARTIN ,  EWALD BASTIAN ,  LAMPERT JORDAN KEITH

Inventor： SCHULZ-DOBRICK MARTIN ,  EWALD BASTIAN ,  LAMPERT JORDAN KEITH

CPC classification number: C01G53/006 ,  C01G53/44 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525

Abstract: Process for preparing modified transition metal mixed oxides, characterized in that a precursor of a mixed oxide which contains Li and at least two transition metals as cations is treated with at least one material selected from among compounds of phosphorus, silicon, titanium, boron and aluminium having at least one phenoxy or alkoxy group or at least one halogen.

Abstract translation: 一种制备改性的过渡金属混合氧化物的，其特征在于，一个过程将含有Li和至少两种过渡金属作为阳离子的复合氧化物的前体，与从与磷，硅，钛，硼或铝的化合物中的至少一种物质的至少 苯氧基，烷氧基或至少一个卤素。

公开(公告)号：CA2787373A1

公开(公告)日：2011-08-04

申请号：CA2787373

申请日：2011-01-28

Applicant: BASF SE

Inventor： LAMPERT JORDAN KEITH ,  BRAMNIK KIRILL ,  HEILEK JOERG

IPC: H01M4/28

Abstract: A process for producing oxidic compounds of the general formula (?) LizMxOy (?) wherein M is one or more elements from groups 2 to 12 of the periodic table, more particularly selected from Co, Mn, Ni, Fe, Al, Mg, x is 1 to 2, y is 2 to 4, and z is 0.5 to 1.5, comprises heating mixtures selected from oxides, hydroxides, carbonates and nitrates of Li and of M together to temperatures in the range from 600 to 1200? in a reaction vessel performing incomplete rotary motions about one axis.

公开(公告)号：PL2586085T3

公开(公告)日：2025-04-14

申请号：PL11797720

申请日：2011-06-24

Applicant: BASF SE

Inventor： SCHRÖDLE SIMON ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHWETER MARK ,  PETROVIC IVAN

IPC: H01M4/48 ,  C01G53/00 ,  H01B1/08 ,  H01M4/50 ,  H01M4/505 ,  H01M4/525

公开(公告)号：CA2721204A1

公开(公告)日：2009-10-22

申请号：CA2721204

申请日：2009-04-16

Applicant: BASF SE

Inventor： HIBST HARTMUT ,  ROBERTS BRIAN ,  LAMPERT JORDAN KEITH ,  BRAMNIK KIRILL

IPC: C01B25/45 ,  H01M4/136 ,  H01M4/58 ,  H01M10/052

Abstract: The present invention relates to a Process for the preparation of compounds of general formula (I), Lia-bM1bFe1-cM2 cPd-eM3 eOx, wherein M1, M2, M3, a, b, c, d and e: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, Fe, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, (B) optionally drying the mixture provided in step (A), in order to obtain a solid compound and (C) calcining the solid compound obtained from step (A) or (B) at a temperature of 300 to 1000° C.

公开(公告)号：ES3010294T3

公开(公告)日：2025-04-02

申请号：ES11797720

申请日：2011-06-24

Applicant: BASF SE

Inventor： SCHRÖDLE SIMON ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHWETER MARK ,  PETROVIC IVAN

IPC: H01M4/48 ,  C01G53/00 ,  H01B1/08 ,  H01M4/50 ,  H01M4/505 ,  H01M4/525

Abstract: La invención se refiere a un método para producir óxidos metálicos mixtos de litio que contienen esencialmente litio, manganeso, cobalto y níquel como átomos metálicos y tienen una relación estequiométrica de litio con respecto a la colectividad de los metales de transición mayor que 1, que comprende a) la producción de una mezcla denominada producto intermedio (B), que comprende esencialmente hidróxidos metálicos mixtos que contienen litio e hidróxidos de óxidos metálicos mixtos que contienen litio, en la que el manganeso, el cobalto y el níquel están contenidos en la relación (1-ab):a:b y en la que el número de oxidación, promediado sobre todos los iones de manganeso, cobalto y níquel, es al menos 4-1,75a-1,75b, donde 0

公开(公告)号：CA2755522A1

公开(公告)日：2010-09-23

申请号：CA2755522

申请日：2010-03-16

Applicant: BASF SE

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH

IPC: C01B25/45 ,  C01B25/26 ,  H01M4/00 ,  H01M4/58 ,  H01M4/62

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bFe1-cM2 cPd-eM3 eOx, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1 : Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to obtain a compound of general formula (I).

公开(公告)号：CA2746965A1

公开(公告)日：2010-07-08

申请号：CA2746965

申请日：2009-12-22

Applicant: BASF SE

Inventor： BRAMNIK KIRILL ,  HIBST HARTMUT ,  LAMPERT JORDAN KEITH ,  SCHRODLE SIMON

IPC: C01B25/45 ,  C01B25/26 ,  H01M4/58

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1 bQ1-cM2 cPd-eM3 eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1 : Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one Q-comprising compound, in which Q has at least partially an oxidation state higher than +2, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to reduce Q to oxidation state +2 and to obtain a compound of general formula (I).

公开(公告)号：CA2787373C

公开(公告)日：2018-03-06

申请号：CA2787373

申请日：2011-01-28

Applicant: BASF SE

Inventor： LAMPERT JORDAN KEITH ,  BRAMNIK KIRILL ,  HEILEK JOERG

IPC: H01M4/28

Abstract: A process for producing oxidic compounds of the general formula (?) LizMxOy (?) wherein M is one or more elements from groups 2 to 12 of the periodic table, more particularly selected from Co, Mn, Ni, Fe, Al, Mg, x is 1 to 2, y is 2 to 4, and z is 0.5 to 1.5, comprises heating mixtures selected from oxides, hydroxides, carbonates and nitrates of Li and of M together to temperatures in the range from 600 to 1200? in a reaction vessel performing incomplete rotary motions about one axis.