公开(公告)号：NZ588752A

公开(公告)日：2012-03-30

申请号：NZ58875209

申请日：2009-04-27

Applicant: BASF SE

Inventor： REESINK BENNIE ,  DEGEN GEORG ,  BRUCK EKKEHARD

IPC: H01L37/04

Abstract: Disclosed is a thermomagnetic generator which converts thermal energy to electrical energy without intermediate conversion to mechanical work, and comprises a series of at least three different metal-based thermomagnetic materials whose magnetocaloric effect occurs at different temperatures, such that the conversion of thermal energy to electrical energy can exploit an enlarged temperature range. The compounds suitable for the invention are selected from: (1) (AyBy-1)2+äCwDxEz Where A is Mn or Co, B is Fe, Cr or Ni, C, D and E at least two of C, D and E are different, have a non-vanishing concentration and are selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, where at least one of C, D and E is Ge or Si, (2) La(FexAl1-x)13Hy or La(FexSi1-x)13Hy (II) La(FexAlyCoz)13 or La(FexSiyCoz)13 (III) LaMnxFe2-xGe (IV) 4) Gd5(SixGe1-x)4 (V) (5) Fe2P-based compounds, (6) manganites of the perovskite type, (7) Tb5(Si4-xGex) (VI) or XTiGe (VII) where X = Dy, Ho, Tm, (8) Mn2-xZxSb (VIII) or Mn2ZxSb1-x (IX)

公开(公告)号：NZ601798A

公开(公告)日：2014-01-31

申请号：NZ60179811

申请日：2011-03-09

Applicant: BASF SE

Inventor： ZHANG LIAN ,  ZHIQUIANG OU ,  LUANA CARON ,  BRUCK EKKEHARD

IPC: H01F1/01

Abstract: Disclosed herein are magnetocaloric materials, processes for their production and to their use in coolers, heat exchangers or generators, in particular refrigerators. The magnetocaloric material being selected from: (MnxFe1-x)2+zP1-ySiy Wherein: 0.20 ≤ x ≥ 0.40 0.40 ≤ y ≥ 0.8 -0.1 ≤ z ≥ 0.1.

公开(公告)号：AU2011225713A1

公开(公告)日：2012-08-23

申请号：AU2011225713

申请日：2011-03-09

Applicant: BASF SE

Inventor： BRUCK EKKEHARD ,  ZHIQUIANG OU ,  ZHANG LIAN ,  LUANA CARON

IPC: H01F1/01

Abstract: What are described are magnetocaloric materials of the general formula (MnFe)PSi where 0.20≤x ≤0.40 0.4≤y ≤0.8 -0.1 ≤z ≤0.1.

公开(公告)号：CA2789797A1

公开(公告)日：2011-09-15

申请号：CA2789797

申请日：2011-03-09

Applicant: BASF SE

Inventor： BRUCK EKKEHARD ,  ZHIQUIANG OU ,  ZHANG LIAN ,  LUANA CARON

IPC: H01F1/01

Abstract: What are described are magnetocaloric materials of the general formula (MnxFe1-x)2+zP1ySiy where 0.20=x =0.40 0.4=y =0.8 -0.1 =z =0.1.

公开(公告)号：AU2009242214A1

公开(公告)日：2009-11-05

申请号：AU2009242214

申请日：2009-04-27

Applicant: BASF SE

Inventor： DEGEN GEORG ,  BRUCK EKKEHARD ,  REESINK BENNIE

IPC: H01L37/04

Abstract: A thermomagnetic generator which converts thermal energy to electrical energy without intermediate conversion to mechanical work and which works at temperatures in the range from -20° C. to 200° C. comprises a thermomagnetic material selected from, for example, (1) compounds of the general formula (I) (AyBy-1)2+deltaCwDxEz(I) where A is Mn or Co, B is Fe, Cr or Ni, C, D and E at least two of C, D and E are different, have a non-vanishing concentration and are selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, where at least one of C, D and E is Ge or Si, delta is a number in the range from -0.1 to 0.1, w, x, y, z are numbers in the range from 0 to 1, where w+x+z=1.