Biodegradable polyester capsules comprising an aqueous core and a pesticide

    公开(公告)号:AU2017209835B2

    公开(公告)日:2020-10-22

    申请号:AU2017209835

    申请日:2017-01-17

    Applicant: BASF SE

    Abstract: The invention relates to microcapsules comprising a capsule shell, and a capsule core, wherein the capsule shell comprises a polyester, and wherein the capsule core comprises a water-solu- ble pesticide, and at least 10 wt% of water based on the total weight of the capsule core; to a process for manufacturing said microcapsules; to a method of application of the microcapsules for controlling undesired insect or mite attack, harmfull fungy, and/or undesired vegetation, and/or for regulating the growth of plants; to plant propagation material comprising the micro- capsules; and to the use of the microcapsules for reducing the volatility, or the leaching behav- ior of the pesticide.

    Proceso para la preparación de microcápsulas que tienen una cubierta de poliurea y un material de núcleo lipófilo

    公开(公告)号:ES2746271T3

    公开(公告)日:2020-03-05

    申请号:ES15786919

    申请日:2015-10-27

    Applicant: BASF SE

    Abstract: Un proceso para la preparación de una dispersión de microcápsulas, en el que las microcápsulas tienen un diámetro medio en volumen d 50 de entre 15 y 90 μm y un porcentaje del peso de la cubierta de entre el 3 y el 40 %, con respecto al peso total de las cápsulas, en el que la cubierta de las microcápsulas comprende al menos una poliurea y el núcleo comprende al menos un componente lipófilo, con la condición de que el núcleo no contenga una fragancia, que comprende las etapas de: a) el suministro de una premezcla (I) que comprende al menos un coloide protector diferente de la hidroxialquil celulosa en una solución acuosa, b) el suministro de una premezcla (II) que comprende al menos un poliisocianato y al menos un componente lipófilo, c) la mezcla de la premezcla (I) y la premezcla (II) hasta que se forma una emulsión (III), d) la adición de una solución acuosa (IV) que contiene al menos una amina polifuncional a la emulsión formada en la etapa c), e) la formación de una dispersión de microcápsulas mediante el calentamiento de la mezcla obtenida en la etapa d) a una temperatura de al menos 50 ºC hasta que se forman las microcápsulas, y f) la adición de hidroxialquil celulosa a la dispersión obtenida en la etapa e).

    Biodegradable polyester capsules comprising an aqueous core and a pesticide

    公开(公告)号:AU2017209835A1

    公开(公告)日:2018-08-02

    申请号:AU2017209835

    申请日:2017-01-17

    Applicant: BASF SE

    Abstract: The invention relates to microcapsules comprising a capsule shell, and a capsule core, wherein the capsule shell comprises a polyester, and wherein the capsule core comprises a water-solu- ble pesticide, and at least 10 wt% of water based on the total weight of the capsule core; to a process for manufacturing said microcapsules; to a method of application of the microcapsules for controlling undesired insect or mite attack, harmfull fungy, and/or undesired vegetation, and/or for regulating the growth of plants; to plant propagation material comprising the micro- capsules; and to the use of the microcapsules for reducing the volatility, or the leaching behav- ior of the pesticide.

    BIODEGRADABLE POLYESTER CAPSULES COMPRISING AN AQUEOUS CORE AND A PESTICIDE

    公开(公告)号:CA3010154A1

    公开(公告)日:2017-07-27

    申请号:CA3010154

    申请日:2017-01-17

    Applicant: BASF SE

    Abstract: The invention relates to microcapsules comprising a capsule shell, and a capsule core, wherein the capsule shell comprises a polyester, and wherein the capsule core comprises a water-solu- ble pesticide, and at least 10 wt% of water based on the total weight of the capsule core; to a process for manufacturing said microcapsules; to a method of application of the microcapsules for controlling undesired insect or mite attack, harmfull fungy, and/or undesired vegetation, and/or for regulating the growth of plants; to plant propagation material comprising the micro- capsules; and to the use of the microcapsules for reducing the volatility, or the leaching behav- ior of the pesticide.

    ANIONIC POLYVINYL ALCOHOL COPOLYMER AS PROTECTIVE COLLOID FOR PESTICIDAL POLYUREA MICROCAPSULES

    公开(公告)号:CA2944701A1

    公开(公告)日:2015-11-05

    申请号:CA2944701

    申请日:2015-04-27

    Applicant: BASF SE

    Abstract: The present invention relates to a process for producing microcapsules which contain a shell and a core of a liquid water-insoluble material, where (a) a premix (I) is prepared from water and a protective colloid; (b) a further premix (II) is prepared from the water-insoluble material and at least bifunctional isocyanate (A) or a mixture of two or more different isocyanates containing (A); (c) the two premixes (I) and (II) are mixed together until an emulsion is formed; (d) at least a bifunctional amine is then poured into the emulsion from step (c); and (e) the emulsion is then heated until the microcapsules are formed, and where the liquid water-insoluble material comprises a pesticide, where the protective colloid is a polyvinyl alcohol copolymer having hydrolysis degrees from 60 to 99.9 %, and where the polyvinyl alcohol copolymer contains comonomers with anionic groups. Further subject matter are microcapsules obtainalbe by said process. The present invention also relates to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the microcapsules are allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment.

    Microcápsulas
    7.
    发明专利

    公开(公告)号:ES2833431T3

    公开(公告)日:2021-06-15

    申请号:ES15804514

    申请日:2015-12-03

    Applicant: BASF SE

    Abstract: Microcapsula que comprende un nucleo de la capsula que comprende un material del nucleo y una cubierta de la capsula en la que la cubierta de la capsula comprende una capa que rodea el nucleo de un poli(alcohol vinilico) y una capa adyacente de una polioxazolina; en la que el material del nucleo se selecciona de filtros UV solubles en aceite (5 o) seleccionados de (o1) derivados de acido p-amino-benzoico, (o2) derivados de acido salicilico, (o3) derivados de benzofenona, (o4) derivados de dibenzoilmetano, (o5) difenilacrilatos, (o6) acido 3-imidazol-4-il-acrilico y sus esteres; (o7) derivados de benzofurano; (o8) filtros UV polimericos; (o9) derivados de acido cinamico; (o10) derivados del alcanfor; (o11) derivados de hidroxifenil triazina; (o12) derivados de benzotriazol; (o13) derivados de trianilino-s-triazina; (o14) o-aminobenzoatos de mentilo; (o15) homosalatos; (o16) malonatos de bencilideno; (o17) derivados de merocianina; (o18) fenilen bis difenil triazina; (o19) derivados de imidazolina; y (o20) derivados de diaril butadieno.

    Biodegradable polyester capsules comprising an aqueous core and a pesticide

    公开(公告)号:AU2017209835C1

    公开(公告)日:2021-03-18

    申请号:AU2017209835

    申请日:2017-01-17

    Applicant: BASF SE

    Abstract: The invention relates to microcapsules comprising a capsule shell, and a capsule core, wherein the capsule shell comprises a polyester, and wherein the capsule core comprises a water-solu- ble pesticide, and at least 10 wt% of water based on the total weight of the capsule core; to a process for manufacturing said microcapsules; to a method of application of the microcapsules for controlling undesired insect or mite attack, harmfull fungy, and/or undesired vegetation, and/or for regulating the growth of plants; to plant propagation material comprising the micro- capsules; and to the use of the microcapsules for reducing the volatility, or the leaching behav- ior of the pesticide.

    PROCESS FOR PREPARATION OF MICROCAPSULES

    公开(公告)号:CA3012160A1

    公开(公告)日:2017-08-17

    申请号:CA3012160

    申请日:2017-02-02

    Applicant: BASF SE

    Abstract: Process for the preparation of microcapsules comprising the steps (a) preparation of an aqueous biphasic system by mixing (i) component (a1 ) comprising a component A selected from the group of polymers consisting of polyethylene glycol vinyl acetate comb polymers, polycarboxylates, polyethers, polyaspartates, polyvinylpyrrolidone, polyamines, and polylysine; wherein component (a1 ) is a monophasic system at 23°C, and forms a monophasic system at 23°C if mixed with water in the range of from 1 :99 to 99:1 by weight, and (ii) component (a2) containing water and a water-soluble component B, wherein water-soluble component B is different from component A, and wherein (a2) is a monophasic system at 23°C, and (iii) at least one monomer (a3), and (iv) optionally at least one initiator (a4), wherein (a1 ), (a2), (a3), and (a4) can be mixed together in any order or simultaneously, followed by (b) optionally shearing of the biphasic system to form an emulsion, and (c) polymerization of monomer (a3).

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