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公开(公告)号:AU2010264760B2
公开(公告)日:2014-10-23
申请号:AU2010264760
申请日:2010-06-22
Applicant: BASF SE
Inventor: GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号:AU2010264760A1
公开(公告)日:2012-02-09
申请号:AU2010264760
申请日:2010-06-22
Applicant: BASF SE
Inventor: GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号:CA2765135C
公开(公告)日:2017-11-07
申请号:CA2765135
申请日:2010-06-24
Applicant: BASF SE
Inventor: OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号:ES2562632T3
公开(公告)日:2016-03-07
申请号:ES10727730
申请日:2010-06-24
Applicant: BASF SE
Inventor: OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: Un sistema de revestimiento de pintura que comprende: un sustrato; una primera capa de pintura dispuesta sobre dicho sustrato y formada a partir de una primera composición que comprende un primer agente descomplejante o un primer complejo de organoborano; y una segunda capa de pintura dispuesta sobre dicha primera capa de pintura y formada a partir de una segunda composición que comprende el otro de dicho primer agente descomplejante y dicho primer complejo de organoborano; en el que al menos uno de dicha primera composición y dicha segunda composición comprende además un compuesto polimerizable por radicales seleccionado del grupo de monómeros polimerizables por radicales libres, oligómeros polimerizables por radicales libres, polímeros polimerizables por radicales libres, y sus combinaciones; y en el que dicho primer agente descomplejante descompleja dicho primer complejo de organoborano en una interfase de dicha primera y segunda capa de pintura para formar radicales libres que inician la polimerización por radicales libres de dicho compuesto polimerizable.
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公开(公告)号:AU2010264689A1
公开(公告)日:2012-02-02
申请号:AU2010264689
申请日:2010-06-24
Applicant: BASF SE
Inventor: OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号:CA2765135A1
公开(公告)日:2010-12-29
申请号:CA2765135
申请日:2010-06-24
Applicant: BASF SE
Inventor: OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号:PT2445975E
公开(公告)日:2013-11-18
申请号:PT10727716
申请日:2010-06-22
Applicant: BASF SE
Inventor: OHRBOM WALTER H , GUTOWSKI KEITH E , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
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公开(公告)号:SG176751A1
公开(公告)日:2012-01-30
申请号:SG2011091105
申请日:2010-06-24
Applicant: BASF SE
Inventor: OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号:ES2437105T3
公开(公告)日:2014-01-08
申请号:ES10727716
申请日:2010-06-22
Applicant: BASF SE
Inventor: GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: Un procedimiento de curado de una composición de revestimiento que comprende un compuesto polimerizablepor radicales y un complejo de organoborano-amina que tiene un iniciador de organoborano como un agente debloqueo de amina, y agua, comprendiendo dicho procedimiento las etapas de: A. combinar el complejo de organoborano-amina, el compuesto polimerizable por radicales y el agua para formarla composición de revestimiento; B. introducir dióxido de carbono en la composición de revestimiento o en una composición que incluye al menosuno del complejo de organoborano-amina, el compuesto polimerizable por radicales y el agua antes de formar lacomposición de revestimiento, en el que el dióxido de carbono está presente en la composición de revestimientoen una proporción molar de al menos 500:1 con el agente de bloqueo de amina del complejo de organoboranoaminapara formar de esta manera ácido carbónico in situ en una proporción molar de al menos 1:1 del ácidocarbónico y el agente de bloqueo de amina del complejo de organoborano-amina; C. descomplejar el complejo de organoborano-amina con el ácido carbónico separando de esta manera eliniciador de organoborano y el agente de bloqueo de amina; y D. polimerizar el compuesto polimerizable por radicales usando el iniciador de organoborano en presencia deoxígeno.
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公开(公告)号:SG176838A1
公开(公告)日:2012-02-28
申请号:SG2011092467
申请日:2010-06-22
Applicant: BASF SE
Inventor: GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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