Method of curing a coating composition comprising a radical curable compound and an organoborane-amine complex

    公开(公告)号:AU2010264760B2

    公开(公告)日:2014-10-23

    申请号:AU2010264760

    申请日:2010-06-22

    Applicant: BASF SE

    Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.

    Method of curing a coating composition comprising a radical curable compound and an organoborane-amine complex

    公开(公告)号:AU2010264760A1

    公开(公告)日:2012-02-09

    申请号:AU2010264760

    申请日:2010-06-22

    Applicant: BASF SE

    Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.

    PAINT COATING SYSTEM AND METHOD OF PRODUCING MULTILAYERED PAINT COATING

    公开(公告)号:CA2765135C

    公开(公告)日:2017-11-07

    申请号:CA2765135

    申请日:2010-06-24

    Applicant: BASF SE

    Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

    Sistema de revestimiento de pintura y procedimiento de producción de un revestimiento de pintura multicapa

    公开(公告)号:ES2562632T3

    公开(公告)日:2016-03-07

    申请号:ES10727730

    申请日:2010-06-24

    Applicant: BASF SE

    Abstract: Un sistema de revestimiento de pintura que comprende: un sustrato; una primera capa de pintura dispuesta sobre dicho sustrato y formada a partir de una primera composición que comprende un primer agente descomplejante o un primer complejo de organoborano; y una segunda capa de pintura dispuesta sobre dicha primera capa de pintura y formada a partir de una segunda composición que comprende el otro de dicho primer agente descomplejante y dicho primer complejo de organoborano; en el que al menos uno de dicha primera composición y dicha segunda composición comprende además un compuesto polimerizable por radicales seleccionado del grupo de monómeros polimerizables por radicales libres, oligómeros polimerizables por radicales libres, polímeros polimerizables por radicales libres, y sus combinaciones; y en el que dicho primer agente descomplejante descompleja dicho primer complejo de organoborano en una interfase de dicha primera y segunda capa de pintura para formar radicales libres que inician la polimerización por radicales libres de dicho compuesto polimerizable.

    Paint coating system and method of producing multilayered paint coating

    公开(公告)号:AU2010264689A1

    公开(公告)日:2012-02-02

    申请号:AU2010264689

    申请日:2010-06-24

    Applicant: BASF SE

    Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

    PAINT COATING SYSTEM AND METHOD OF PRODUCING MULTILAYERED PAINT COATING

    公开(公告)号:CA2765135A1

    公开(公告)日:2010-12-29

    申请号:CA2765135

    申请日:2010-06-24

    Applicant: BASF SE

    Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

    PAINT COATING SYSTEM AND METHOD OF PRODUCING MULTILAYERED PAINT COATING

    公开(公告)号:SG176751A1

    公开(公告)日:2012-01-30

    申请号:SG2011091105

    申请日:2010-06-24

    Applicant: BASF SE

    Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

    Procedimiento de curado de una composición de revestimiento que comprende un compuesto curable por radicales y un complejo de organoborano-amina

    公开(公告)号:ES2437105T3

    公开(公告)日:2014-01-08

    申请号:ES10727716

    申请日:2010-06-22

    Applicant: BASF SE

    Abstract: Un procedimiento de curado de una composición de revestimiento que comprende un compuesto polimerizablepor radicales y un complejo de organoborano-amina que tiene un iniciador de organoborano como un agente debloqueo de amina, y agua, comprendiendo dicho procedimiento las etapas de: A. combinar el complejo de organoborano-amina, el compuesto polimerizable por radicales y el agua para formarla composición de revestimiento; B. introducir dióxido de carbono en la composición de revestimiento o en una composición que incluye al menosuno del complejo de organoborano-amina, el compuesto polimerizable por radicales y el agua antes de formar lacomposición de revestimiento, en el que el dióxido de carbono está presente en la composición de revestimientoen una proporción molar de al menos 500:1 con el agente de bloqueo de amina del complejo de organoboranoaminapara formar de esta manera ácido carbónico in situ en una proporción molar de al menos 1:1 del ácidocarbónico y el agente de bloqueo de amina del complejo de organoborano-amina; C. descomplejar el complejo de organoborano-amina con el ácido carbónico separando de esta manera eliniciador de organoborano y el agente de bloqueo de amina; y D. polimerizar el compuesto polimerizable por radicales usando el iniciador de organoborano en presencia deoxígeno.

    METHOD OF CURING A COATING COMPOSITION COMPRISING A RADICAL CURABLE COMPOUND AND AN ORGANOBORANE-AMINE COMPLEX

    公开(公告)号:SG176838A1

    公开(公告)日:2012-02-28

    申请号:SG2011092467

    申请日:2010-06-22

    Applicant: BASF SE

    Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.

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