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公开(公告)号：AU2010264690A1
公开(公告)日：2012-02-02
申请号：AU2010264690
申请日：2010-06-24
Applicant: BASF SE
Inventor： CRANFILL DAVID , GUTOWSKI KEITH E
Abstract: A method of forming a cured coating composition on an automobile component is provided. The method utilizes a coating compound including a radical polymerizable compound and an organoborane initiator and includes the step of applying the coating composition to the automobile component. The organoborane initiator is complexed with a bi-functional noncyclic blocking agent that has a carbon backbone and two organoborane complexing moieties. The two moieties are different from each other and are selected from the group of an amine moiety, a thiol moiety, and a phosphine moiety. In addition, the two moieties are separated from each other by two to four carbon atoms to increase the nucleophilicity of the blocking agent towards the organoborane initiator. The organoborane initiator is decomplexed from the blocking agent thereby forming a radical that is used to polymerize the radical polymerizable compound and cure the coating composition on the automobile component.
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公开(公告)号：AU2010264689A1
公开(公告)日：2012-02-02
申请号：AU2010264689
申请日：2010-06-24
Applicant: BASF SE
Inventor： OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号：CA2765137A1
公开(公告)日：2010-12-29
申请号：CA2765137
申请日：2010-06-24
Applicant: BASF SE
Inventor： CRANFILL DAVID , GUTOWSKI KEITH E
Abstract: A method of forming a cured coating composition on an automobile component is provided. The method utilizes a coating compound including a radical polymerizable compound and an organoborane initiator and includes the step of applying the coating composition to the automobile component. The organoborane initiator is complexed with a bi-functional noncyclic blocking agent that has a carbon backbone and two organoborane complexing moieties. The two moieties are different from each other and are selected from the group of an amine moiety, a thiol moiety, and a phosphine moiety. In addition, the two moieties are separated from each other by two to four carbon atoms to increase the nucleophilicity of the blocking agent towards the organoborane initiator. The organoborane initiator is decomplexed from the blocking agent thereby forming a radical that is used to polymerize the radical polymerizable compound and cure the coating composition on the automobile component.
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公开(公告)号：CA2765135A1
公开(公告)日：2010-12-29
申请号：CA2765135
申请日：2010-06-24
Applicant: BASF SE
Inventor： OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号：CA2765133C
公开(公告)日：2018-10-23
申请号：CA2765133
申请日：2010-06-24
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , CRANFILL DAVID
Abstract: A method of dissociating an organoborane-amine complex in a coating composition is provided. The method includes the step of introducing the organoborane-amine complex, the radical polymerizable compound, and optionally an amine, onto a substrate to form the coating composition. The method also includes the step of introducing carbon dioxide into the coating composition in a molar ratio of at least 1 : 1 of the carbon dioxide to free amine groups present in the coating composition. More specifically, a carbamic zwitterion is formed in-situ from reaction of the carbon dioxide and the free amine groups. The formation of the carbamic zwitterion leads to dissociation of the organoborane-amine complex and formation of a radical. The radical is then used to polymerize the radical polymerizable compound.
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Patent Agency Ranking
公开(公告)号：CA2765135C
公开(公告)日：2017-11-07
申请号：CA2765135
申请日：2010-06-24
Applicant: BASF SE
Inventor： OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
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公开(公告)号：ES2562632T3
公开(公告)日：2016-03-07
申请号：ES10727730
申请日：2010-06-24
Applicant: BASF SE
Inventor： OHRBOM WALTER H , MENOVCIK GREGORY G , MORMILE PATRICK J , CAMPBELL DONALD H , CRANFILL DAVID
Abstract: Un sistema de revestimiento de pintura que comprende: un sustrato; una primera capa de pintura dispuesta sobre dicho sustrato y formada a partir de una primera composición que comprende un primer agente descomplejante o un primer complejo de organoborano; y una segunda capa de pintura dispuesta sobre dicha primera capa de pintura y formada a partir de una segunda composición que comprende el otro de dicho primer agente descomplejante y dicho primer complejo de organoborano; en el que al menos uno de dicha primera composición y dicha segunda composición comprende además un compuesto polimerizable por radicales seleccionado del grupo de monómeros polimerizables por radicales libres, oligómeros polimerizables por radicales libres, polímeros polimerizables por radicales libres, y sus combinaciones; y en el que dicho primer agente descomplejante descompleja dicho primer complejo de organoborano en una interfase de dicha primera y segunda capa de pintura para formar radicales libres que inician la polimerización por radicales libres de dicho compuesto polimerizable.
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公开(公告)号：ES2560523T3
公开(公告)日：2016-02-19
申请号：ES10726103
申请日：2010-06-24
Applicant: BASF SE
Inventor： CRANFILL DAVID , GUTOWSKI KEITH E
Abstract: Un procedimiento para polimerizar un compuesto polimerizable por radicales empleando un iniciador de organoborano, comprendiendo dicho procedimiento las etapas de: A. introducir el compuesto polimerizable por radicales y el iniciador de organoborano sobre un sustrato para formar una mezcla, en el que el iniciador de organoborano está complejado con un agente bloqueante no cíclico bifuncional que tiene un esqueleto de carbono y dos restos complejantes de organoborano diferentes entre sí y seleccionados del grupo de un resto amina, un resto tiol y un resto fosfina, y en el que los dos restos diferentes están separados entre sí por dos a cuatro átomos de carbono para aumentar la nucleofilicidad del agente bloqueante hacia el iniciador de organoborano; B. descomplejar el iniciador de organoborano del agente bloqueante, formando con ello un radical; y C. polimerizar el compuesto polimerizable por radicales utilizando el radical, opcionalmente en ausencia de calentamiento externo, u opcionalmente a una temperatura de 20 ºC a 30 ºC.
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公开(公告)号：AU2010264685A1
公开(公告)日：2012-02-02
申请号：AU2010264685
申请日：2010-06-24
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , CRANFILL DAVID
Abstract: A method of dissociating an organoborane-amine complex in a coating composition is provided. The method includes the step of introducing the organoborane-amine complex, the radical polymerizable compound, and optionally an amine, onto a substrate to form the coating composition. The method also includes the step of introducing carbon dioxide into the coating composition in a molar ratio of at least 1 : 1 of the carbon dioxide to free amine groups present in the coating composition. More specifically, a carbamic zwitterion is formed in-situ from reaction of the carbon dioxide and the free amine groups. The formation of the carbamic zwitterion leads to dissociation of the organoborane-amine complex and formation of a radical. The radical is then used to polymerize the radical polymerizable compound.
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公开(公告)号：ES2562104T3
公开(公告)日：2016-03-02
申请号：ES10726101
申请日：2010-06-24
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , CRANFILL DAVID
Abstract: Un procedimiento de formación de una composición de revestimiento, comprendiendo dicho procedimiento las etapas de: A. introducir un complejo organoborano-amina, un compuesto polimerizable por radicales y opcionalmente una amina sobre un sustrato para formar una composición de revestimiento; B. introducir dióxido de carbono en la composición de revestimiento en una relación molar de al menos 1:1 del dióxido de carbono a los grupos amina libres presentes en la composición de revestimiento; C. hacer reaccionar el dióxido de carbono y los grupos amina libres para formar in-situ un zwitterión carbámico y para disociar el complejo organoborano-amina formando de esta manera un radical; y D. polimerizar el compuesto polimerizable por radicales usando el radical, opcionalmente en ausencia de calentamiento externo, u opcionalmente a una temperatura de 20ºC a 30ºC.
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