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公开(公告)号:US20240279059A1
公开(公告)日:2024-08-22
申请号:US18569631
申请日:2022-06-14
Applicant: BASF SE
Inventor: Armin LANGE DE OLIVEIRA , Sandra MAGNUS , Andreas KUSCHEL , Christiane KURETSCHKA , Marcelo Daniel KAUFMAN RECHULSKI
CPC classification number: C01B3/40 , B01J23/83 , C01B2203/0233 , C01B2203/0238 , C01B2203/1052 , C01B2203/1241
Abstract: A continuous process for reforming one or more hydrocarbons to a synthesis gas comprising hydrogen and carbon monoxide, the start-up phase of said process comprising (i) providing a reactor comprising a reaction zone which comprises a catalyst comprising a mixed oxide comprising cobalt and oxygen; (ii) continuously passing an inert gas stream through the reaction zone according to (i), said inert gas stream comprising one or more inert gases; (iii) continuously passing a reactant gas stream into the reaction zone obtained from (ii), wherein from 95 to 100 volume-% of the reactant gas stream passed into the reaction zone consist of the one or more hydrocarbons, carbon dioxide, and water; subjecting said reactant gas stream to reforming conditions in said reaction zone; and removing a product stream from said reaction zone, said product stream comprising hydrogen and carbon monoxide.
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公开(公告)号:US20210114006A1
公开(公告)日:2021-04-22
申请号:US17254484
申请日:2019-06-19
Applicant: BASF SE
Inventor: Christiane KURETSCHKA , Robert MCGUIRE , Ivana JEVTOVIKJ , Sven REINING , Stefan LIPP , Andrei-Nicolae PARVULESCU , Astrid Elisa NIEDERLE , Michael GESKE
IPC: B01J29/70 , B01J23/26 , B01J37/02 , B01J37/00 , B01J37/03 , B01J37/06 , B01J37/08 , C07C1/04 , C07C29/153 , C07C41/01
Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having an AEI-type framework structure, wherein the zeolitic material has a framework structure comprising Si, a trivalent element X, and oxygen, wherein the zeolitic material further comprises one or more alkali metals AM and/or one or more alkaline earth metals AEM; and b) a mixed metal oxide comprising chromium, zinc, and aluminum; and to a process for its production, as well as to the molding and the mixed metal oxide as such, respectively, as obtainable or obtained according to the inventive production process, as well as to the composition as obtainable or obtained according to the inventive production process. In addition to these, the present invention further relates to the use of the inventive composition as a catalyst or as a catalyst component, as well as to a process for preparing C2 to C4 olefins from a synthesis gas comprising hydrogen and carbon monoxide.
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公开(公告)号:US20240278225A1
公开(公告)日:2024-08-22
申请号:US18568559
申请日:2022-05-11
Applicant: LINDE GMBH , BASF SE
Inventor: Nicole SCHÖDEL , Stephanie NEUENDORF , Axel BEHRENS , Wibke KORN , Sonja SCHULTE , Stefan HOFFMANN , Marcelo Daniel KAUFMAN RECHULSKI , Virginie LANVER , Stefan DIETRICH , Nils BOTTKE , Christiane KURETSCHKA , Hamideh AHI , Manuel Frederik GENTZEN , Michael KRAMER
CPC classification number: B01J37/10 , B01J21/04 , B01J23/78 , B01J23/83 , B01J37/18 , C01B3/40 , C01B2203/0238 , C01B2203/1052 , C01B2203/1082
Abstract: The invention relates to a method for activating a catalyst for catalytic reforming that is particularly carried out with carbon dioxide being reacted, and according to which an activation gas that contains steam and hydrogen is passed over the catalyst to be activated at an activation temperature during an activation period. The activation gas comprises 10 to 30 mol-% steam, 40 to 60 mol-% hydrogen and 20 to 40 mol-% one or more inert gases.
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公开(公告)号:US20230095488A1
公开(公告)日:2023-03-30
申请号:US17795892
申请日:2021-01-29
Applicant: BASF SE
Inventor: Marcelo Daniel KAUFMAN RECHULSKI , Christiane KURETSCHKA , Sandra MAGNUS , Sabine BORCHERS , Juergen AMANN
Abstract: The present invention relates to a process for preparing a molding comprising a mixed oxide comprising O, Mg, and Ni, the process comprising: —(i) mixing water, a Mg source, a Ni source, and an acid, to obtain a mixture; —(ii) subjecting the mixture obtained from (i) to a shaping process; —(iii) calcining the molding obtained from (ii) in a gas atmosphere having a temperature in the range of from 700 to 1400° C.; wherein the molar ratio of the acid used in (i) to Ni, calculated as elemental Ni, of the Ni source used in (i), acid:Ni, is equal to or higher than 0.001:1. Further, the present invention relates to a molding comprising a mixed oxide comprising O, Mg, and Ni, wherein the mixed oxide comprises a specific crystalline phase NixMgyO, wherein the sum of x and y is 1, and wherein y is greater than 0.52. The molding is used for reforming methane to a synthesis gas comprising hydrogen and carbon monoxide.
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公开(公告)号:US20220134312A1
公开(公告)日:2022-05-05
申请号:US17427332
申请日:2020-01-30
Applicant: BASF SE
Inventor: Ekkehard SCHWAB , Marcelo Daniel KAUFMAN RECHULSKI , Stefan DIETRICH , Sandra MAGNUS , Sabine BORCHERS , Stephan A. SCHUNK , Christiane KURETSCHKA , Marie Katrin SCHROETER , Xue LIU , Thorsten JOHANN
Abstract: A molding comprising a mixed oxide, wherein the mixed oxide comprises oxygen, lanthanum, aluminum, and cobalt, wherein in the mixed oxide, the weight ratio of cobalt relative to aluminum, calculated as elements, is at least 0.17:1. A preparation method by a dry route. Use of the molding as a catalyst for the reforming of hydrocarbons into a synthesis gas.
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公开(公告)号:US20200368734A1
公开(公告)日:2020-11-26
申请号:US16635236
申请日:2018-08-08
Applicant: BASF SE
Inventor: Robert MCGUIRE , Achim WECHSUNG , Christiane KURETSCHKA , Ivana JEVTOVIKJ , Andreas KUSCHEL , Stephan A. SCHUNK
Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.
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