FUNGICIDAL MIXTURES
    5.
    发明申请
    FUNGICIDAL MIXTURES 审中-公开
    真菌混合物

    公开(公告)号:WO2008148859A3

    公开(公告)日:2009-09-17

    申请号:PCT/EP2008057027

    申请日:2008-06-05

    Abstract: The present invention relates to mixtures comprising, as active components, 1) a fungicidal compound of formula (I) wherein: R1 is alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryl; or heteroaryl; R2 is alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryl; heteroaryl; 5-pyrimidinyl; or 2-or 5-thiazolyl; R3 is H; alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryloxyalkyl; arylthioalkyl; aryl; heteroaryl; or alkylsilyl; R4 is H; acyl; haloacyl, alkoxycarbonyl; aryloxycarbonyl; alkylaminocarbonyl; or dialkylaminocarbonyl; or a salt thereof; and 2) a fungicidal compound II selected from azoles, strobilurins, carboxamides, heterocylic compounds, carbamates, and other active compounds in synergistically effective amounts.

    Abstract translation: 本发明涉及包含作为活性成分的1)式(I)的杀真菌化合物的混合物,其中:R 1是烷基; 烷氧基; 卤代; 芳; 芳基; 或杂芳基; R2是烷基; 烷氧基; 卤代; 芳; 芳基; 杂; 5-嘧啶基; 或2-或5-噻唑基; R3为H; 烷基; 烷氧基; 卤代; 芳; 芳氧; 芳硫基; 芳基; 杂; 或烷基甲硅烷基; R4是H; 酰基; 卤代酰基,烷氧基羰基; 芳氧羰基; 烷基氨基; 或二烷基氨基羰基; 或其盐; 和2)协同有效量的选自唑类,嗜球半胱氨酸,羧酰胺,杂环化合物,氨基甲酸酯和其它活性化合物的杀真菌化合物II。

    METHOD FOR PRODUCING DIFLUOROMETHYL-SUBSTITUTED PYRAZOLE COMPOUNDS
    10.
    发明申请
    METHOD FOR PRODUCING DIFLUOROMETHYL-SUBSTITUTED PYRAZOLE COMPOUNDS 审中-公开
    用于生产二氟吡唑

    公开(公告)号:WO2008152138A3

    公开(公告)日:2009-05-28

    申请号:PCT/EP2008057506

    申请日:2008-06-13

    CPC classification number: C07D231/12 C07D231/14

    Abstract: The invention relates to a method for producing 3-difluoromethyl-substituted pyrazole compounds of formula (I), wherein R1 represents H, halogen, nitro, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, phenyl, naphthyl, hetaryl, cyano, -C(=O)-OR1a, -C(=O)-NR1bR1c, -C(=O)-SR1d or -C(=S)-SR1 e; R2 represents H, C1-C4 alkyl, benzyl or phenyl; R3 represents H, halogen, C1-C8 alkoxy, C1-C8 haloalkoxy, C3-C8 cycloalkoxy, C2-C8 alkenyloxy, C1-C8 alkylthio, C1-C8 haloalkylthio, C3-C8 cycloalkylthio or C2-C8 alkenylthio; to compounds of formula (II.a) or (II.b), wherein R1 and R3 have one of the above definitions; R4 represents halogen, -OR4a, -SR4a , -O-SO2-R4a or a group -NR4bR4c; R5 and R6 represent C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, benzyl or phenyl or together with the nitrogen atom to which they are bound represent a 3- to 8-membered heterocycle; to Lewis acid adducts of compounds of formula (II.b); to the use of compounds of formula (II.a) or (II.b) and of the Lewis acid adducts thereof for producing compounds of formula (I) or (VI); and to a method for converting said compounds to the corresponding 3-difluoromethylpyrazole-4-yl carboxylic acids.

    Abstract translation: 本发明涉及一种用于制备式-3-二氟甲基吡唑(I)化合物其中R1是H,卤素,硝基,C1-C8烷基,C1-C8卤代烷基,C3-C8环烷基,苯基,萘基,杂芳基, 氰基,-C(= O)-OR1a,-C(= O)-NR1bR1c,-C(= O)-SR1d或-C(= S)-SR1e基; R2是H,C1-C4烷基,苄基或苯基; R 3为H,卤素,C1-C8烷氧基,C1-C8卤代烷氧基,C3-C8环烷氧基,C2-C8链烯氧基,C1-C8烷硫基,C1-C8卤代烷硫基,C3-C8-环烷硫基或C 2 -C C8-烯硫基;式(二.a)或(二.b)的化合物,其中R 1和R 3具有以上给出的含义之一; R 4是卤素,-OR4a,-SR4a,-O-SO2-R4A或一组-NR4bR4c基; R5和R6是C1-C8烷基,C1-C8卤代烷基,C3-C8环烷基,苄基或苯基或一起与氮原子到它们所键合的,代表3-至8-元杂环; 式(二.b)化合物的路易斯酸加合物;使用(二.a)或(二.b)和路易斯酸加合物,式I化合物的对式(I)或(VI)的化合物的制备方法; 并且这些化合物转变成相应的3-二氟甲基吡唑-4-基甲磺酸的方法。

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