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    COLOUR-STABLE SUPERABSORBENT
    1.
    发明申请
    COLOUR-STABLE SUPERABSORBENT 审中-公开
    颜色稳定SUPER吸收器

    公开(公告)号：WO2010012762A3

    公开(公告)日：2010-03-25

    申请号：PCT/EP2009059793

    申请日：2009-07-29

    Applicant: BASF SE ,  RIEGEL ULRICH ,  DANIEL THOMAS ,  HERFERT NORBERT ,  ELLIOTT MARK

    Inventor： RIEGEL ULRICH ,  DANIEL THOMAS ,  HERFERT NORBERT ,  ELLIOTT MARK

    IPC: C08J3/075 ,  A61L15/42

    CPC classification number: A61L15/60 ,  A61L15/42 ,  C08J3/075 ,  C08J2300/14 ,  C08L101/14

    Abstract: Superabsorbents containing a compound of formula (I) where M represents a hydrogen atom, an ammonium ion, a monovalent metal ion or one equivalent of a divalent metal ion of groups 1, 2, 8, 9, 10, 12 or 14 of the periodic table; R1 represents OH or NR4R5, where R4 and R5 independently represent H or C1-C6-alkyl; R2 represents H or an alkyl, alkenyl, cycloalkyl or aryl group which optionally has 1, 2 or 3 substituents selected independently from C1-C6-alkyl, OH, O-C1-C6-alkyl, halogen and CF3; and R3 represents COOM, SO3M, COR4, CONR4R5 or COOR4, where M, R4 and R5 are each as defined above, or, when R2 represents aryl which is optionally substituted as indicated above, also represents H, salts thereof or mixtures of such compounds and/or salts thereof display improved stability to discoloration in storage under elevated temperatures or elevated relative humidity.

    Abstract translation: 超吸收，含有式（I）其中M表示氢原子，铵离子，一价金属离子或一个当量组1,2，8，9，10，12或元素周期表第14的二价金属离子的化合物; R 1是OH或NR4R5，其中R4和R5独立地为H或C1-C6烷基; R2是H或烷基，烯基，环烷基或芳基，所述基团任选含有独立地选自C1-C6烷基中的1，2或3个取代基，OH，O-C 1 -C 6 - 烷基 ，卤素和CF 3; 且R 3为COOM，SO3M，COR4，CONR4R5，或COOR4，其中M，R4和R5具有或具有以上给出的含义，当R 2是芳基，如上所指出的，其是任选取代的，也代表H，它们的盐，或它们的混合物 这样的化合物和/或其盐，表现出升高的温度或高湿度下提高储存时抗变色稳定性。

    WATER-ABSORBING POLYMERIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF
    3.
    发明申请
    WATER-ABSORBING POLYMERIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
    吸水聚合物颗粒及其生产方法

    公开(公告)号：WO2009016055A3

    公开(公告)日：2009-08-20

    申请号：PCT/EP2008059496

    申请日：2008-07-21

    Applicant: BASF SE ,  RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  BRUHNS STEFAN

    Inventor： RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  BRUHNS STEFAN

    IPC: A61L15/60 ,  A61L15/42 ,  A61L15/58

    CPC classification number: A61L15/60 ,  A61L15/42 ,  A61L15/58

    Abstract: The present invention relates to a water absorbing material obtainable by a process comprising the steps of bringing particles of a non surface-crosslinked water-absorbing polymer in contact with a) at least one postcrosslinker, b)10-1000 ppm, based on the non surface-crosslinked water-absorbing polymer, of at least one Nitrogen-containing water-soluble polymer of which the Nitrogen can be protonated, and c)at least one hydrophobic polymer and heat-treating the particles thus obtained at a temperature in the range from 120°C to 300°C and a method for the production thereof.

    Abstract translation: 本发明涉及一种吸水材料，该方法包括以下步骤：使非表面交联的吸水聚合物的颗粒与a）至少一个后交联剂接触，b）10-1000ppm，基于非 - 表面交联的吸水聚合物，其至少一种含氮的水溶性聚合物，其中氮可以被质子化，以及c）至少一种疏水性聚合物，并在如下温度范围内对由此获得的颗粒进行热处理： 120℃〜300℃，及其制造方法。

    WATER-ABSORBING POLYMERIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF
    4.
    发明申请
    WATER-ABSORBING POLYMERIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
    吸水性聚合物颗粒及其生产方法

    公开(公告)号：WO2009016054A2

    公开(公告)日：2009-02-05

    申请号：PCT/EP2008059495

    申请日：2008-07-21

    Applicant: BASF SE ,  RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  BRUHNS STEFAN

    Inventor： RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  BRUHNS STEFAN

    IPC: A61L15/60

    CPC classification number: A61L15/60

    Abstract: The present invention relates to a water absorbing material obtainable by a process comprising the steps of bringing particles of a non surface-crosslinked water-absorbing polymer in contact with a) at least one post-crosslinker, b) 0.1 - 1.0 wt.% of at least one water-insoluble metal phosphate, based on the non surface-crosslinked water-absorbing polymer, and at least one further ingredient selected from c) at least one Nitrogen-containing water-soluble polymer of which the Nitrogen can be protonated, and d) at least one hydrophobic polymer and heat-treating the particles thus obtained at a temperature in the range from 120°C to 300°C and a method for the production thereof.

    Abstract translation: 本发明涉及一种吸水材料，所述吸水材料通过包括以下步骤的方法获得：使非表面交联的吸水性聚合物的颗粒与a）至少一种后交联剂接触，b）0.1-1.0重量％的 至少一种基于非表面交联的吸水聚合物的水不溶性金属磷酸盐和至少一种选自c）至少一种氮可被质子化的含氮水溶性聚合物的其他成分，和 d）至少一种疏水性聚合物，并在120℃至300℃的温度下热处理由此获得的颗粒及其制备方法。

    6.
    发明专利
    未知

    公开(公告)号：AT520643T

    公开(公告)日：2011-09-15

    申请号：AT04724254

    申请日：2004-03-30

    Applicant: BASF SE

    Inventor： RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  SCHWALM REINHOLD

    IPC: C07C69/00 ,  C08F20/00 ,  C08F20/18 ,  C08G65/26 ,  C08G65/28 ,  C08G65/32 ,  C08G65/332 ,  C09D5/02

    Abstract: Trimethylolpropane esters are new. Trimethylolpropane esters are of formula (1). (1) AO : OCH2CH2, OCH2CH(CH3), OCH(CH3)CH2, n1-n3 : 4-6; n1+n2+n3+n4 : 14-16; m1-m3 : 1-3; m1+m2+m3 : 4-6; R1-R3 : 4-6 Independent claims are included for: (1) a process for the production of esters of formula (1) by reaction of alkoxylated trimethylolpropane with (meth)acrylic acid in the presence of at least one esterification catalyst (C) and at least one polymerization inhibitor (D) as well as optionally a solvent (E) that forms an azeotrope with water; optionally removal of at least a portion of the water from the reaction mixture during or after the water from the reaction, optiionally neutralizing the reaction mixture; optionally removing the solvent if present by distillation and/or stripping with an inert gas; (2) across-linked hydrogel prepared by polymerization of an ester of formula (1) with (meth)acrylic acid with optionally additional monoethylenicaly unsaturated compounds (N) as well as optionally at least a further copolymerizable hydrophilic monomer (M) in the presence of at least one radicatl initiator (K) and optionally a graft base (L); optionally cross-linking of the resulting reaction mixture; drying of the reaction mixture and optionally grinding the reaction mixture; (3) a mixture comprising 0.1-40 wt.% of a ester of formula (1) and (meth)acrylic acid, 0.5-99.9 wt.% of a hydrophilic monomer (M), 0-10 wt.% of an esterification catalyst (C), 0-5 wt.% polymerization inhibitor (D) and 0-10 wt.% sovlent (E).

    9.
    发明专利
    未知

    公开(公告)号：AT521645T

    公开(公告)日：2011-09-15

    申请号：AT05700996

    申请日：2005-01-18

    Applicant: BASF SE

    Inventor： DANIEL THOMAS ,  RIEGEL ULRICH ,  ELLIOTT MARK

    IPC: C08F20/00 ,  C08F220/06

    Abstract: (Meth)acrylate salt polymers are prepared by free-radical polymerization of (meth)acrylate salt with or without other monomers in an aqueous medium by using a supersaturated aqueous solution of (meth)acrylate salt. The resulting highly concentrated reaction mixtures are notable for their high solids content and increased space-time yield.

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