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    Method for producing ester of polyalcohol
    3.
    发明专利
    Method for producing ester of polyalcohol 有权
    生产聚醇的方法

    公开(公告)号：JP2013082941A

    公开(公告)日：2013-05-09

    申请号：JP2013013621

    申请日：2013-01-28

    Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

    Inventor： JAWOREK THOMAS ,  DANIEL THOMAS ,  WOLF LOTHAR ,  KOENIGER RAINER DR ,  SCHWALM REINHOLD ,  HARTMANN GABRIELE ,  WICKEL STEFAN

    IPC: C08F220/06 ,  C08G63/78 ,  A61L15/60 ,  C07C67/08 ,  C08F2/00 ,  C08G65/332

    CPC classification number: C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C07C69/54

    Abstract: PROBLEM TO BE SOLVED: To simplify a production method for a material usable as a radical crosslinking agent for a high-absorbent material.SOLUTION: A method for producing a crosslinked hydrogel is provided, in which a polyalcohol A is reacted with an ethylenically unsaturated carboxylic acid B in the presence of an esterification catalyst C, a polymerization inhibitor D, and optionally a solvent E which forms an azeotrope with water under the formation of an ester F. Optionally, at least a part of water produced is removed from a reaction mixture, optionally the reaction mixture is neutralized, and the solvent E is removed by distillation, and/or stripped using a gas which is inert under reaction conditions. The reaction mixture from one of the steps, optionally an additional monoethylenically unsaturated compound N, and optionally a copolymerizable hydrophilic monomer M are polymerized in the presence of a radical initiator K and optionally a graft base L. Optionally, the reaction mixture obtained is subjected to post crosslinking, drying, pulverization, and/or screening.

    Abstract translation: 要解决的问题：为了简化用作高吸收性材料的自由基交联剂的材料的制造方法。 解决方案：提供一种制备交联水凝胶的方法，其中多元醇A与乙烯不饱和羧酸B在酯化催化剂C，阻聚剂D和任选的形成的溶剂E的存在下反应 在酯F的形成下与水形成共沸物。任选地，将至少一部分产生的水从反应混合物中除去，任选地将反应混合物中和，并通过蒸馏除去溶剂E和/或使用 在反应条件下为惰性气体。 来自一个步骤的反应混合物，任选的另外的单烯属不饱和化合物N和任选的可共聚的亲水单体M在自由基引发剂K和任选的接枝基质L的存在下聚合。任选地，将获得的反应混合物 后交联，干燥，粉碎和/或筛选。 版权所有（C）2013，JPO＆INPIT

    METHOD FOR THE PRODUCTION OF (METH)ACRYLATES OF C10 ALCOHOL MIXTURES
    7.
    发明申请
    METHOD FOR THE PRODUCTION OF (METH)ACRYLATES OF C10 ALCOHOL MIXTURES 审中-公开
    生产C10-醇混合物的（甲基）丙烯酸酯的方法

    公开(公告)号：WO2009106550A9

    公开(公告)日：2009-11-12

    申请号：PCT/EP2009052241

    申请日：2009-02-26

    Applicant: BASF SE ,  MEISENBURG UWE ,  HOEFER FRANK ,  SCHWALM REINHOLD ,  GRUBER NICK ,  KARRER LOTHAR

    Inventor： MEISENBURG UWE ,  HOEFER FRANK ,  SCHWALM REINHOLD ,  GRUBER NICK ,  KARRER LOTHAR

    IPC: C07C67/08 ,  C07C67/54 ,  C07C69/54 ,  C09D133/06 ,  C09J133/06

    CPC classification number: C07C67/08 ,  C07C67/54 ,  C07C69/54

    Abstract: Disclosed is a method for producing (meth)acrylates of C10 alcohol mixtures by reacting (meth)acrylic acid with an isomer mixture of C10 alcohols comprising 2-propylheptanol as the main isomer and at least one of the C10 alcohols 2-propyl-4- methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4- methylhexanol, 2-isopropyl-5-methylhexanol, and/or 2-propyl-4,4-dimethylpentanol in the presence of at least one acid catalyst and at least one polymerization inhibitor and in the presence of a solvent forming an azeotrope along with water, removing the azeotrope by distillation and condensing the same such that the condensate is decomposed into an aqueous and an organic phase. According to said method, a) the esterification process is carried out in a reactor comprising a circulating evaporator, b) in the presence of a solvent, and c) the raw product is purified in a subsequent pure distillation process.

    Abstract translation: 一种用于C10醇混合物的（甲基）丙烯酸酯，其制备方法由（甲基）2-丙基-4-丙烯酸与从2-丙基庚醇作为Hauptisomeres和C10醇甲基己中的至少一个，2 C10醇的异构体混合物进行反应 丙基-5-甲基己，2- isopropylheptanol，2-异丙基-4-甲基己，2-异丙基-5-甲基己和/或2-丙基-4,4- dimethylpentanol，在至少一种酸催化剂和至少一种阻聚剂的存在下和在存在 其与水形成共沸物，蒸馏出共沸混合物和冷凝的溶剂，冷凝液分离成水相和有机相，其包括进行a）所述酯化在反应器与循环蒸发器，和b）在溶剂中和c的存在下 ）通过随后的纯化蒸馏来清洁粗产物。

    8.
    发明专利
    未知

    公开(公告)号：AT520643T

    公开(公告)日：2011-09-15

    申请号：AT04724254

    申请日：2004-03-30

    Applicant: BASF SE

    Inventor： RIEGEL ULRICH ,  DANIEL THOMAS ,  HERMELING DIETER ,  ELLIOTT MARK ,  SCHWALM REINHOLD

    IPC: C07C69/00 ,  C08F20/00 ,  C08F20/18 ,  C08G65/26 ,  C08G65/28 ,  C08G65/32 ,  C08G65/332 ,  C09D5/02

    Abstract: Trimethylolpropane esters are new. Trimethylolpropane esters are of formula (1). (1) AO : OCH2CH2, OCH2CH(CH3), OCH(CH3)CH2, n1-n3 : 4-6; n1+n2+n3+n4 : 14-16; m1-m3 : 1-3; m1+m2+m3 : 4-6; R1-R3 : 4-6 Independent claims are included for: (1) a process for the production of esters of formula (1) by reaction of alkoxylated trimethylolpropane with (meth)acrylic acid in the presence of at least one esterification catalyst (C) and at least one polymerization inhibitor (D) as well as optionally a solvent (E) that forms an azeotrope with water; optionally removal of at least a portion of the water from the reaction mixture during or after the water from the reaction, optiionally neutralizing the reaction mixture; optionally removing the solvent if present by distillation and/or stripping with an inert gas; (2) across-linked hydrogel prepared by polymerization of an ester of formula (1) with (meth)acrylic acid with optionally additional monoethylenicaly unsaturated compounds (N) as well as optionally at least a further copolymerizable hydrophilic monomer (M) in the presence of at least one radicatl initiator (K) and optionally a graft base (L); optionally cross-linking of the resulting reaction mixture; drying of the reaction mixture and optionally grinding the reaction mixture; (3) a mixture comprising 0.1-40 wt.% of a ester of formula (1) and (meth)acrylic acid, 0.5-99.9 wt.% of a hydrophilic monomer (M), 0-10 wt.% of an esterification catalyst (C), 0-5 wt.% polymerization inhibitor (D) and 0-10 wt.% sovlent (E).

    METODO PARA LA PRODUCCION DE (MET) ACRILATOS DE MEZCLAS DE ALCOHOL DE C10.
    10.
    发明专利
    METODO PARA LA PRODUCCION DE (MET) ACRILATOS DE MEZCLAS DE ALCOHOL DE C10. 未知

    公开(公告)号：MX2010009011A

    公开(公告)日：2010-09-09

    申请号：MX2010009011

    申请日：2009-02-26

    Applicant: BASF SE

    Inventor： KARRER LOTHAR ,  SCHWALM REINHOLD ,  MEISENBURG UWE ,  HOEFER FRANK ,  GRUBER NICK

    IPC: C07C67/08 ,  C07C67/54 ,  C07C69/54 ,  C09D133/06 ,  C09J133/06

    Abstract: Se describe un método para producir (met)acrilato de mezclas de alcoholes de C10 mediante la reacción del ácido (met)acrílico con una mezcla de isómeros de alcoholes de C10 que contiene 2-propilheptanol como el isómero principal y al menos uno de los alcoholes de C10 2-propil-4-metilhexanol, 2-propil-5-metilhexanol, 2-isopropilheptanol, 2-isopropil-4-metilhexanol, 2- isopropil-5-metilhexanol y/o 2-propil-4,4-dimetilpentanol en presencia de al menos un catalizador ácido y al menos un inhibidor de la polimerización y en presencia de un solvente que forma un azeótropo junto con agua, la separación del azeótropo por destilación y la condensación del mismo de modo que el condensado se descomponga en una fase acuosa y una orgánica. De acuerdo con el método, a) el proceso de esterificación se lleva a cabo en un reactor que comprende un evaporador de circulación, b) en presencia de un solvente, y c) el producto crudo se purifica en un proceso de destilación para purificación subsiguiente.

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