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    HALOGEN-FREE, PHOSPHOROUS-CONTAINING, FLAME-PROTECTED POLYMER FOAMS
    1.
    发明申请
    HALOGEN-FREE, PHOSPHOROUS-CONTAINING, FLAME-PROTECTED POLYMER FOAMS 审中-公开
    无卤素，无磷阻燃聚合物泡沫

    公开(公告)号：WO2011095540A2

    公开(公告)日：2011-08-11

    申请号：PCT/EP2011051550

    申请日：2011-02-03

    Applicant: BASF SE ,  HAHN KLAUS ,  KRIHA OLAF ,  BELLIN INGO ,  SPIES PATRICK ,  FUCHS SABINE ,  DEGLMANN PETER ,  MASSONNE KLEMENS ,  DENECKE HARTMUT ,  FLECKENSTEIN CHRISTOPH ,  JANSSENS GEERT ,  HOFMANN MAXIMILIAN ,  DOERING MANFRED ,  MICHAEL CIESIELSKI ,  WAGNER JOCHEN

    Inventor： HAHN KLAUS ,  KRIHA OLAF ,  BELLIN INGO ,  SPIES PATRICK ,  FUCHS SABINE ,  DEGLMANN PETER ,  MASSONNE KLEMENS ,  DENECKE HARTMUT ,  FLECKENSTEIN CHRISTOPH ,  JANSSENS GEERT ,  HOFMANN MAXIMILIAN ,  DOERING MANFRED ,  MICHAEL CIESIELSKI ,  WAGNER JOCHEN

    IPC: C08J9/00

    CPC classification number: C08J9/0038 ,  C08J9/0066 ,  C08J2325/04 ,  C08K5/53

    Abstract: The invention relates to a polymer foam having a density in the range between 5 and 120 kg/m3, containing a) a polymer component, containing at least one styrene polymer, b) 0.1 to 5 parts by weight (relative to 100 parts by weight of component a)) of a flame retardant mixture, containing b1) at least one phosphorus compound of formula (I) having a phosphorus content in the range between 5 and 80% by weight, relative to the phosphorus compound, (X1)s =PR1R2R3 (I), where the symbols and indices in formula (I) have the following meanings: R1 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; R2 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl,C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13;R3 is H, SH, SR4, OH, OR5 or a group 30 -(Y1)n-[P(= X2)uR6 -(Y2)n]m-P(= X3)tR7R8; or two groups R1, R2, R3 together with the phosphorus atom to which they are bound form a ring system; X1, X2 and X3 are independently of each other identically or differently O or S; Y1, Y2 are identically or differently O or S; R4, R5, R9, R10, R11, R12,R13 are identically or differently C1-C12-alkyl, C3-C8-cycloalkyl, which is unsubstituted or substituted by one or more C1-C4-alkyl groups, C2-C12-alkenyl, C2-C12-alkinyl, C6-C10-aryl or C6-C10-aryl C1-C4-alkyl; R6, R7, R8 are independently of each other identically or differently C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; n is 1, if Y1 or Y2 is O, and 1, 2, 3, 4, 5, 6, 7 or 8, if Y1 or Y2 is S; m is a whole number between 0 and 100; s, t and u are independently of each other 0 or 1; and b2) elementary sulphur.

    Abstract translation: 阻燃剂混合物，其包含b1的一）），其包括含有至少一种苯乙烯聚合物的聚合物组分，B）（基于具有在5〜120千克/米3范围内的密度，A聚合物泡沫）0.1至5重量份每100重量份组分的） 在式（I）具有在5的范围内的磷含量到80重量％的至少一种磷化合物，基于磷化合物（X1）S = PR1R2R3（I），其中，在式（I）中的符号和指数具有以下含义 有：R1是C1-C16烷基，C1-C10羟基烷基，C2-C16烯基，C1-C16烷氧基，C2-C16-链烯氧基，C3-C10环烷基，C3-C10环烷氧基，C6-C10 芳基，C6-C10芳氧基，C6-C10芳基C1-C16烷基，C6-C10芳基C1-C16烷氧基，SR9，COR 10，COOR 11，CONR 12 R 13; R2是C1-C16烷基，C1-C10羟基烷基，C2-C16烯基，C1-C16烷氧基，C2-C16-链烯氧基，C3-C10环烷基，C3-C10环烷氧基，C6-C10芳基， C6-C10芳基C1-C16烷基，C6-C10芳基C1-C16烷氧基，SR9，COR 10，COOR 11，CONR 12 R 13; R 3是H，SH，SR 4，OH，OR 5或Gruppe30 - （Y1） N- [P（= X2）UR6 - （Y2）N] MP（= X3）tR7R8;或两个基团R1，R2，与磷原子R3一起形成它们所连接形成环系统; X 1，X 2和X 3相同或不同且彼此独立地为O或S; Y1，Y2是相同或不同的O或S; R4，R5，R9，R10，R11，R12，R13为相同或不同的C1-C12烷基，C3-C8环烷基，其未被取代或者被一个或多个C1-C4烷基取代，C2-C12链烯基， C 2 -C 12炔基，C 6 -C 10芳基或C 6 -C 10芳基-C 1 -C 4烷基; R6，R7，R8是相同的或彼此独立地C1-C16烷基，C1-C16链烯基，C1-C16烷氧基，C1-C16-链烯氧基，C3-C10环烷基，C3-C10环烷氧基，C6-C10的不同 芳基，C6-C10芳氧基，C6-C10芳基C1-C16烷基，C6-C10芳基C1-C16烷氧基，SR9，COR 10，COOR 11，CONR 12 R 13; 如果Y1或Y2是O，n是1，如果Y1或Y1是1，则为1,2,3,4,5,6,7或8。 Y2是S; m是0至100的整数; s，t和u独立地为0或1; 和b2）元素硫。

    METHOD FOR PRODUCING XPS MOULDED PIECES PROVIDED WITH INSECTICIDE
    5.
    发明申请
    METHOD FOR PRODUCING XPS MOULDED PIECES PROVIDED WITH INSECTICIDE 审中-公开
    用于生产杀虫剂EQUIPPED XPS成型片

    公开(公告)号：WO2010046379A2

    公开(公告)日：2010-04-29

    申请号：PCT/EP2009063780

    申请日：2009-10-21

    Applicant: BASF SE ,  ISHAQUE MICHAEL ,  KRIHA OLAF ,  HAHN KLAUS ,  LONGO DANIELA

    Inventor： ISHAQUE MICHAEL ,  KRIHA OLAF ,  HAHN KLAUS ,  LONGO DANIELA

    CPC classification number: A01N25/34 ,  A01N25/10 ,  A01N25/16 ,  A01N43/36 ,  A01N43/54 ,  A01N43/56 ,  A01N47/02

    Abstract: The invention relates to a method for producing extruded polystyrene foam (XPS) moulded pieces provided with insecticide, comprising the following steps: (a) heating polystyrene (PS) to form a polymer melt, (b) introducing a blowing agent into the polymer melt to give a foamable melt and (c) foaming the foamable melt to give an XPS moulded piece, wherein in at least one of the steps (a) and/or (b), at least one insecticide from the group of phenylpyrazoles, chlorfenapyr and hydramethylnon is introduced into the melt.

    Abstract translation: 一种用于杀虫配挤出聚苯乙烯泡沫（XPS）模制部件，包括：（a）加热聚苯乙烯（PS）的步骤，以形成聚合物熔体，（b）将发泡剂引入聚合物熔体以形成可发泡熔体，和制备方法（c） 发泡可发泡的熔体到XPS成型件，其中，在步骤中的至少一个（a）和/或（b）选自苯基吡唑，氟唑虫清和灭蚁腙至少一种杀虫剂被引入到聚合物熔体中。

    PARTICLE FOAMS WITH CORROSION-INHIBITING AUXILIARY MATERIAL
    6.
    发明申请
    PARTICLE FOAMS WITH CORROSION-INHIBITING AUXILIARY MATERIAL 审中-公开
    具有防腐辅助物质粒子FOAMS

    公开(公告)号：WO2014067948A3

    公开(公告)日：2015-05-28

    申请号：PCT/EP2013072614

    申请日：2013-10-29

    Applicant: BASF SE

    Inventor： SCHERZER DIETRICH ,  HAHN KLAUS ,  KRÖNER ANITA ,  RUCH JOACHIM

    IPC: C08J9/00 ,  C08J9/16

    CPC classification number: C08J9/0004 ,  C08J9/16 ,  C08J2325/00 ,  C08J2423/02 ,  C08J2453/02

    Abstract: The invention relates to a particle foam which contains 0.5 to 8 wt.-% of one or more corrosion inhibitors, selected from among amines, triazoles, carboxylic acid esters, carboxylic acid salts, nitrites, alcohols or mixtures thereof, to methods for producing said foam and to the use for packaging corrodible metal articles.

    Abstract translation: 一种粒子泡沫重量％含有0.5〜选自胺，三唑，羧酸酯，羧酸盐，亚硝酸盐，醇或它们的混合物8一种或多种腐蚀抑制剂，以及涉及其制备方法和用于腐蚀能力的金属物品的包装。

    FLAME-RESISTANT COMPOSITE FOAM
    7.
    发明申请
    FLAME-RESISTANT COMPOSITE FOAM 审中-公开
    FLAME PROTECTED COMPOSITE FOAM

    公开(公告)号：WO2011113795A3

    公开(公告)日：2011-12-01

    申请号：PCT/EP2011053808

    申请日：2011-03-14

    Applicant: BASF SE ,  PERETOLCHIN MAXIM ,  STEINKE TOBIAS HEINZ ,  PFEIFFER MATTHIAS ,  FUCHS SABINE ,  BELLIN INGO ,  HAHN KLAUS ,  SCHERR GUENTER ,  SCHMITZ KARL-HEINZ

    Inventor： PERETOLCHIN MAXIM ,  STEINKE TOBIAS HEINZ ,  PFEIFFER MATTHIAS ,  FUCHS SABINE ,  BELLIN INGO ,  HAHN KLAUS ,  SCHERR GUENTER ,  SCHMITZ KARL-HEINZ

    IPC: C08J9/00

    CPC classification number: C08J9/0038 ,  C08J9/0066 ,  C08J9/236 ,  C08J9/33 ,  C08J9/35 ,  C08J2361/20 ,  C08J2425/00

    Abstract: A composite foam containing A) foamed particles containing A1) 25 to 95% by weight styrene polymer(s), A2) optionally a blowing agent, A3) optionally one or more additives, B) an aminoplast component containing B1) 1 to 65% by weight cured, optionally modified, and optionally foamed aminoplast resin, B2) 0.1 to 20% by weight of one or more flame retardant organic phosphorous compounds having a phosphorous content of 5 to 80% by weight (based on the respective compound) and/or expanded graphite, B3) optionally one or more flame retardant synergists or the component B2), B4) optionally a blowing agent, B5) optionally one or more additives, wherein the percentages by weight - where not stated otherwise - relate to the sum of the components A1), B1) and B2), is suitable, in particular, as insulating material.

    Abstract translation: 一种复合泡沫，其包含A）含有A1发泡颗粒）25至95重量的苯乙烯聚合物（S），A2）任选的发泡剂，A3的％）任选的一种或多种添加剂，B）的氨基塑料组分，其包含B1）1〜65重量 B2）0.1重量％至20重量％的一种或多种磷含量为5-80重量％（基于具体化合物计）的阻燃有机磷化合物和/或 或膨胀石墨，B3）任选的一种或组分B2多种阻燃增效剂），B4）任选的发泡剂，B5）任选的一种或多种添加剂，其中所述重量百分比 - 除非另有说明 - 组分A1的总和），B1 ）和B2）特别适合作为绝缘材料。

    MICROWAVE-ASSISTED SETTING OF SHAPED CERAMIC/FOAM BODIES
    8.
    发明申请
    MICROWAVE-ASSISTED SETTING OF SHAPED CERAMIC/FOAM BODIES 审中-公开
    形状陶瓷/泡沫体的微波辅助设置

    公开(公告)号：WO2010076170A2

    公开(公告)日：2010-07-08

    申请号：PCT/EP2009067079

    申请日：2009-12-14

    Applicant: BASF SE ,  NEHLS BENJAMIN ,  SCHMIED BERNHARD ,  MAHN ULRIKE ,  HAHN KLAUS ,  WIELAND PETRA ,  FUCHS SABINE ,  ULANOVA TATIANA ,  FRANCIS TIMOTHY ,  BAUMGAERTNER KLAUS-MARTIN ,  MUEGGE HORST

    Inventor： NEHLS BENJAMIN ,  SCHMIED BERNHARD ,  MAHN ULRIKE ,  HAHN KLAUS ,  WIELAND PETRA ,  FUCHS SABINE ,  ULANOVA TATIANA ,  FRANCIS TIMOTHY ,  BAUMGAERTNER KLAUS-MARTIN ,  MUEGGE HORST

    IPC: C08J9/232 ,  B01J19/12 ,  B27N3/00 ,  B29C35/08 ,  B29C44/10 ,  C08J9/236

    CPC classification number: C08J9/236 ,  B29C35/0805 ,  B29C67/205 ,  B29C2035/0855 ,  C08J9/232 ,  H05B6/80 ,  H05B2206/046

    Abstract: The invention relates to a method for the production of shaped foam bodies, comprising: provision of a composition having foam particles and binder; introduction of the composition into a space which is bounded on at least one side by a pressing surface; and exertion of pressure onto the composition by means of the pressing surface. The method further irradiation of microwaves through the pressing surface into the composition, while pressure is being exerted onto the composition. The invention furthermore relates to a device for carrying out the method according to the invention, having: at least one pressing surface and a counterbearing surface lying opposite, between which a space extends which is adapted to receive a composition of foam particles and binder. The pressing surface and counterbearing surface adjoin the space directly. The device further comprises at least one stiff layer which locally or entirely is essentially transparent for microwaves and has a surface facing toward the space, which is connected to the pressing surface in such a way as to transmit force. The device also comprises a microwave radiator unit which is arranged on a side of the stiff layer remote from the space and is aligned relative to the space in order to irradiate microwaves into the space through the stiff layer. Lastly, the invention relates to a microwave radiator unit for the heat treatment of foam compositions. The microwave radiator unit comprises a multiplicity of microwave antennas which are arranged in a plane array and at least two of which are connected through a distributor device to a common microwave signal source, which feeds the at least two antennas.

    Abstract translation: 本发明涉及一种用于生产成型泡沫体的方法，其包括：提供具有泡沫颗粒和粘合剂的组合物; 将组合物引入由至少一侧通过挤压表面界定的空间中; 并借助于挤压表面对组合物施加压力。 该方法进一步将微波通过压制表面照射到组合物中，同时将压力施加到组合物上。 本发明还涉及一种用于执行根据本发明的方法的装置，该装置具有：至少一个压制表面和一个相对的承载表面，在所述承载表面之间延伸有空间，该空间适于接收泡沫颗粒和粘合剂的组合物。 按压表面和承重表面直接连接空间。 该装置进一步包括至少一个局部或完全对于微波来说基本上透明的刚性层，并且具有面向该空间的表面，该表面以这样的方式连接到按压表面以便传递力。 该装置还包括微波辐射器单元，该微波辐射器单元布置在刚性层的远离该空间的一侧上，并相对于该空间对齐，以便通过该刚性层将微波辐射到该空间中。 最后，本发明涉及用于泡沫组合物的热处理的微波辐射器单元。 微波辐射器单元包括多个微波天线，微波天线以平面阵列布置，并且其中至少两个微波天线通过分配器装置连接到公共微波信号源，该微波信号源馈送至少两个天线。

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