公开(公告)号：DE502008001478D1

公开(公告)日：2010-11-18

申请号：DE502008001478

申请日：2008-02-18

Applicant: BASF SE

Inventor： WEBER MARTIN ,  HOENL HANS ,  ITTEMANN PETER ,  HAENSEL WERNER

IPC: C08L25/12 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L77/00

公开(公告)号：AT483754T

公开(公告)日：2010-10-15

申请号：AT08709060

申请日：2008-02-18

Applicant: BASF SE

Inventor： WEBER MARTIN ,  HOENL HANS ,  ITTEMANN PETER ,  HAENSEL WERNER

IPC: C08L25/12 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L77/00

Abstract: A thermoplastic molding composition, comprising the following amounts of components A, B, C, and D: a) from 3 to 91.9% by weight of one or more styrene copolymers A, b) from 3 to 91% by weight of one or more polyamides B, c) from 5 to 50% by weight of one or more graft polymers C, d) from 0.1 to 25% by weight of one or more terpolymers D, whose oligomer content is smaller than 3% by weight, and also, if appropriate, comprising, as further components, a further rubber E, an at least monofunctional anhydride F, fibrous or particulate fillers G, and also further additives H, has markedly reduced anisotropy of impact resistance.

公开(公告)号：DE502006002400D1

公开(公告)日：2009-01-29

申请号：DE502006002400

申请日：2006-09-25

Applicant: BASF SE

Inventor： WEBER MARTIN ,  GOTTSCHALK AXEL ,  ITTEMANN PETER ,  HOENL HANS

IPC: C08L33/12 ,  C08L25/12 ,  C08L51/00

Abstract: A thermoplastic molding composition comprising a specified mixture containing (a) a methyl methacrylate (co)polymer, (b) a vinyl aromatic-vinyl cyanide copolymer, (c) a graft copolymer and optionally (d) conventional additives is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the (a)/(b) matrix is 0.003-0.008 as measured by a specified method. A thermoplastic molding composition comprising a specified mixture containing (c) a graft copolymer is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the matrix based on the other polymers is 0.003-0.008 as measured by a specified method. The specified mixture comprises by weight (A) a methyl methacrylate polymer (30-69%) obtained by polymerization of (i) methyl methacrylate (90-100%) and (ii) a 1-8C alkyl acrylate (0-10%); (B) a copolymer (30-69%) obtained by copolymerization of (iii) a vinyl aromatic monomer (75-88%) and (iv) a vinyl cyanide (12-25%); (C) a graft copolymer (1-40%) comprising a core polymer (60-90%) obtained from (v) a 1,3-diene (65-89.9%), (vi) a vinyl aromatic monomer (10-34.9%) and (vii) an agglomeration polymer together with a first shell (5-20%) obtained by polymerization of (viii) a vinyl aromatic monomer (30-39%), (ix) a 1-8C alkyl methacrylate (61-70%) and (x) a crosslinking monomer (0-3%) and a second shell (5-20%) obtained by polymerization of (xi) a 1-8C alkyl methacrylate (70-98%) and (xii) a 1-8C alkyl acrylate (2-30%), the weight ratio first : second shell being 2 : 1-1 : 2; and optionally (D) conventional additives (up to 20%). An independent claim is also included for production of the mixtures by melt mixing of the components.

公开(公告)号：MX2009008817A

公开(公告)日：2009-10-07

申请号：MX2009008817

申请日：2008-02-18

Applicant: BASF SE

Inventor： WEBER MARTIN ,  ITTEMANN PETER ,  HAENSEL WERNER ,  HOENL HANS

IPC: C08L25/12 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L77/00

Abstract: La invención se refiere a un compuesto termoplástico para moldeado, que contiene los componentes A, B, C y D en las siguientes cantidades: a) 3 a 91.9% en peso de uno o más copolímeros de estireno A, b) de 3 a 91.9% en peso de una o más poliamidas B, c) 5 a 50% en peso de uno o más polímeros injertados C, d) 0.1 a 25% en peso de un terpolímero D que tenga un porcentaje de oligómeros de menos de 3% en peso, y como una opción, como componentes adicionales otro caucho, y anhídrido F al menos monofuncional, fibra o cargas en forma de partícula G y aditivos adicionales H, en donde el compuesto para moldeado presenta anisotropía considerablemente reducida respecto a la resistencia al choque.

公开(公告)号：AT417894T

公开(公告)日：2009-01-15

申请号：AT06793774

申请日：2006-09-25

Applicant: BASF SE

Inventor： WEBER MARTIN ,  GOTTSCHALK AXEL ,  ITTEMANN PETER ,  HOENL HANS

IPC: C08L33/12 ,  C08L25/12 ,  C08L51/00

Abstract: A thermoplastic molding composition comprising a specified mixture containing (a) a methyl methacrylate (co)polymer, (b) a vinyl aromatic-vinyl cyanide copolymer, (c) a graft copolymer and optionally (d) conventional additives is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the (a)/(b) matrix is 0.003-0.008 as measured by a specified method. A thermoplastic molding composition comprising a specified mixture containing (c) a graft copolymer is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the matrix based on the other polymers is 0.003-0.008 as measured by a specified method. The specified mixture comprises by weight (A) a methyl methacrylate polymer (30-69%) obtained by polymerization of (i) methyl methacrylate (90-100%) and (ii) a 1-8C alkyl acrylate (0-10%); (B) a copolymer (30-69%) obtained by copolymerization of (iii) a vinyl aromatic monomer (75-88%) and (iv) a vinyl cyanide (12-25%); (C) a graft copolymer (1-40%) comprising a core polymer (60-90%) obtained from (v) a 1,3-diene (65-89.9%), (vi) a vinyl aromatic monomer (10-34.9%) and (vii) an agglomeration polymer together with a first shell (5-20%) obtained by polymerization of (viii) a vinyl aromatic monomer (30-39%), (ix) a 1-8C alkyl methacrylate (61-70%) and (x) a crosslinking monomer (0-3%) and a second shell (5-20%) obtained by polymerization of (xi) a 1-8C alkyl methacrylate (70-98%) and (xii) a 1-8C alkyl acrylate (2-30%), the weight ratio first : second shell being 2 : 1-1 : 2; and optionally (D) conventional additives (up to 20%). An independent claim is also included for production of the mixtures by melt mixing of the components.