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公开(公告)号：ES2347414T3
公开(公告)日：2010-10-29
申请号：ES01931697
申请日：2001-05-17
Applicant: BASF SE
Inventor： GUNTHERBERG NORBERT , CZAUDERNA BERNHARD , ITTEMANN PETER
Abstract: Composiciones termoplásticas moldeables, que contienen, respecto de los componentes A) hasta F), A) 5 hasta 70% en peso de al menos un copolímero injertado A) hecho de, respecto de A, a1) 10 hasta 90% en peso de al menos un injerto elastomérico con una temperatura de transición vítrea por debajo de 0ºC, y b2) 10 hasta 90% en peso de al menos un injerto hecho de, respecto de a2), a21) 50 hasta 100% en peso de al menos un compuesto de estireno, a22) 0 hasta 50% en peso de acrilonitrilo o metacrilonitrilo o sus mezclas a23) 0 hasta 50% en peso de al menos otro monómero insaturado monoetilénicamente, B) 29 hasta 90% en peso de un copolímero rígido hecho de, respecto de B), b1) 50 hasta 100% en peso de al menos un compuesto de estireno, b2) 0 hasta 50% en peso de acrilonitrilo o metacrilonitrilo o sus mezclas, b3) 0 hasta 50% en peso de al menos otro monómero insaturado monoetilénicamente, C) 0,01 hasta 5% en peso de al menos un copolímero de tres bloques X-Y-X con un bloque medio Y de unidades de óxido de propileno y bloques X ubicados en los extremos de unidades de óxido de etileno, D) 0,01 hasta 5% en peso de al menos un producto de reacción butilado de p-cresol con diciclopentadieno de la fórmula (I) **(Ver fórmula)** con n
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公开(公告)号：AT417894T
公开(公告)日：2009-01-15
申请号：AT06793774
申请日：2006-09-25
Applicant: BASF SE
Inventor： WEBER MARTIN , GOTTSCHALK AXEL , ITTEMANN PETER , HOENL HANS
Abstract: A thermoplastic molding composition comprising a specified mixture containing (a) a methyl methacrylate (co)polymer, (b) a vinyl aromatic-vinyl cyanide copolymer, (c) a graft copolymer and optionally (d) conventional additives is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the (a)/(b) matrix is 0.003-0.008 as measured by a specified method. A thermoplastic molding composition comprising a specified mixture containing (c) a graft copolymer is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the matrix based on the other polymers is 0.003-0.008 as measured by a specified method. The specified mixture comprises by weight (A) a methyl methacrylate polymer (30-69%) obtained by polymerization of (i) methyl methacrylate (90-100%) and (ii) a 1-8C alkyl acrylate (0-10%); (B) a copolymer (30-69%) obtained by copolymerization of (iii) a vinyl aromatic monomer (75-88%) and (iv) a vinyl cyanide (12-25%); (C) a graft copolymer (1-40%) comprising a core polymer (60-90%) obtained from (v) a 1,3-diene (65-89.9%), (vi) a vinyl aromatic monomer (10-34.9%) and (vii) an agglomeration polymer together with a first shell (5-20%) obtained by polymerization of (viii) a vinyl aromatic monomer (30-39%), (ix) a 1-8C alkyl methacrylate (61-70%) and (x) a crosslinking monomer (0-3%) and a second shell (5-20%) obtained by polymerization of (xi) a 1-8C alkyl methacrylate (70-98%) and (xii) a 1-8C alkyl acrylate (2-30%), the weight ratio first : second shell being 2 : 1-1 : 2; and optionally (D) conventional additives (up to 20%). An independent claim is also included for production of the mixtures by melt mixing of the components.
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公开(公告)号：AT417892T
公开(公告)日：2009-01-15
申请号：AT06777312
申请日：2006-06-13
Applicant: BASF SE
Inventor： WEBER MARTIN , MUEHLBACH KLAUS , ITTEMANN PETER , GRUTKE STEFAN , INCHAURRONDO NICOLAS
Abstract: Molding compositions comprising: a composition (I) present in an amount of 10 to 100% by weight, based on the molding composition, wherein the composition (I) comprises: (A) 40 to 95% by weight, based on the composition (I), of a copolymer comprising: α-methylstyrene in an amount of 55 to 90% by weight, acrylonitrile in an amount of 10 to 50% by weight, and one or more other monomers in an amount of 0 to 5% by weight, wherein the percentages by weight of the α-methylstyrene, the acrylonitrile and the one or more other monomers are based on the weight of component (A); (B) 2.5 to 75% by weight, based on the composition (I), of a polymer comprising: a vinylaromatic monomer in an amount of 60 to 90% by weight, acrylonitrile in an amount of 8.01 to 39.8% by weight, and maleic anhydride in an amount of 0.2 to 1.99% by weight, wherein the percentages by weight of the vinylaromatic monomer, the acrylonitrile and the maleic anhydride are based on the weight of component (B); and (C) 2.5 to 60% by weight, based on the composition (I), of glass fibers.
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公开(公告)号：DE19910916B4
公开(公告)日：2008-06-12
申请号：DE19910916
申请日：1999-03-11
Applicant: BASF SE
Inventor： BARGHOORN PETER , FISCHER MICHAEL , GOERRISSEN HEINER , ITTEMANN PETER
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公开(公告)号：DE50115517D1
公开(公告)日：2010-07-29
申请号：DE50115517
申请日：2001-05-17
Applicant: BASF SE
Inventor： GUENTHERBERG NORBERT , CZAUDERNA BERNHARD , ITTEMANN PETER
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Patent Agency Ranking
公开(公告)号：AT471353T
公开(公告)日：2010-07-15
申请号：AT01931697
申请日：2001-05-17
Applicant: BASF SE
Inventor： GUENTHERBERG NORBERT , CZAUDERNA BERNHARD , ITTEMANN PETER
Abstract: Thermoplastic molding compositions comprising, based on the components A) to F), A) from 5 to 70% by weight of at least one graft copolymer A) made from an elastomeric graft base with a glass transition temperature below 0° C., and a graft made from a styrene compound, and acryonitrile or methacrylonitrile or a mixture of these and, where appropriate, further monoethylenically unsaturated monomers, B) from 29 to 90% by weight of a hard copolymer made from at least one styrene compound, acrylonitrile or methacrylonitrile or a mixture of these and, where appropriate, further monoethylenically unsaturated monomers, C) from 0 to 5% by weight of at least one three-block copolymer X-Y-X having a central block Y made from propylene oxide units and having terminal blocks X made from ethylene oxide units, D) from 0.01 to 5% by weight of at least one butylated reaction product of p-cresol with dicyclopentadiene, E) from 0.01 to 5% by weight of at least one thiocarboxylic ester, F) from 0.01 to 5% by weight of at least one alkali metal salt or alkaline earth metal salt of a C6-C20 carboxylic acid, and G) from 0 to 30% by weight, based on components A) to G), of other conventional additives,where the weathered db* value of the molding compositions is below +5.0 after 100 hours of exposure to light and weathering to ISO 4892/2, method A, black-panel temperature 65° C., using the CIE-Lab color system, to DIN 6174 and DIN 5033.
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公开(公告)号：ES2317585T3
公开(公告)日：2009-04-16
申请号：ES06793774
申请日：2006-09-25
Applicant: BASF SE
Inventor： WEBER MARTIN , GOTTSCHALK AXEL , ITTEMANN PETER , HONL HANS
Abstract: Masas de moldeo termoplásticas que contienen una mezcla constituida por (A) un 30 a un 69% en peso, referido a la suma de componentes (A), (B) y (C), de un polímero de metacrilato de metilo, obtenible mediante polimerización de una mezcla constituida por (A1) un 90 a un 100% en peso, referido a (A), de metacrilato de metilo, y (A2) un 0 a un 10% en peso, referido a (A), de un éster de alquilo con 1 a 8 átomos de carbono de ácido acrílico y (B) un 30 a un 69% en peso, referido a la suma de los componentes (A), (B) y (C), de un copolímero obtenible mediante polimerización de una mezcla, constituida por (B1) un 75 a un 88% en peso, referido a (B), de un monómero aromático vinílico, y (B2) un 12 a un 25% en peso, referido a (B), de un cianuro de vinilo, y (C) un 1 a un 40% en peso, referido a la suma de componentes (A), (B) y (C), de un copolímero de injerto, obtenible a partir de (C1) un 60 a un 90% en peso, referido a (C), de un núcleo, obtenible mediante polimerización de una mezcla de monómeros, constituida por (C11) un 65 a un 89,9% en peso, referido a (C1), de un 1,3-dieno, (C12) un 10 a un 34,9% en peso, referido a (C1), de un monómero aromático vinílico, (C13) un 0,1 a un 5% en peso, referido a (C1), de un polímero de aglomeración, y (C2) un 5 a un 20% en peso, referido a (C) de una primera envoltura de injerto, obtenible mediante polimerización de una mezcla de monómeros constituida por (C21) un 30 a un 39% en peso, referido a (C2), de un monómero aromático vinílico, (C22) un 61 a un 70% en peso, referido a (C2), de un éster de alquilo con 1 a 8 átomos de carbono de ácido metacrílico, y (C23) un 0 a un 3% en peso, referido a (C2), de un monómero reticulante, y (C3) un 5 a un 20% en peso, referido a (C), de una segunda envoltura de injerto, obtenible mediante polimerización de una mezcla de monómeros constituida por (C31) un 70 a un 98% en peso, referido a (C3), de un éster de alquilo con 1 a 8 átomos de carbono de ácido metacrílico y (C32) un 2 a un 30% en peso, referido a (C3), de un éster de alquilo con 1 a 8 átomos de carbono de ácido acrílico, y (D) en caso dado aditivos habituales en cantidades de hasta un 20% en peso, referido a la suma de componentes (A), (B) y (C), con la condición de que la proporción ponderal de (C2) y (C3) se sitúe en el intervalo de 2 : 1 a 1 : 2, caracterizadas porque - el núcleo (C1) presenta una distribución de tamaños de partícula monomodal, - el tamaño medio de partícula D 50 del núcleo (C1) (determinado según el método citado en la descripción) se sitúa en el intervalo de 300 a 400 nm, y - la suma de la diferencia de índice de refracción (nD-C) del componente total (C) y el índice de refracción (nD- A-B) de la matriz total de los componentes (A) y (B) se sitúa en el intervalo de 0,003 a 0,008, determinándose los índices de refracción respectivamente según los métodos citados en la descripción.
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公开(公告)号：DE502006002400D1
公开(公告)日：2009-01-29
申请号：DE502006002400
申请日：2006-09-25
Applicant: BASF SE
Inventor： WEBER MARTIN , GOTTSCHALK AXEL , ITTEMANN PETER , HOENL HANS
Abstract: A thermoplastic molding composition comprising a specified mixture containing (a) a methyl methacrylate (co)polymer, (b) a vinyl aromatic-vinyl cyanide copolymer, (c) a graft copolymer and optionally (d) conventional additives is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the (a)/(b) matrix is 0.003-0.008 as measured by a specified method. A thermoplastic molding composition comprising a specified mixture containing (c) a graft copolymer is such that (1) the copolymeric core used for graft copolymer (c) has a monomodal particle size distribution and an average particle size (D 50) as measured by a described method of 300-400 nm; and (2) the difference of the refractive index of the total composition used to produce (c) and that of the matrix based on the other polymers is 0.003-0.008 as measured by a specified method. The specified mixture comprises by weight (A) a methyl methacrylate polymer (30-69%) obtained by polymerization of (i) methyl methacrylate (90-100%) and (ii) a 1-8C alkyl acrylate (0-10%); (B) a copolymer (30-69%) obtained by copolymerization of (iii) a vinyl aromatic monomer (75-88%) and (iv) a vinyl cyanide (12-25%); (C) a graft copolymer (1-40%) comprising a core polymer (60-90%) obtained from (v) a 1,3-diene (65-89.9%), (vi) a vinyl aromatic monomer (10-34.9%) and (vii) an agglomeration polymer together with a first shell (5-20%) obtained by polymerization of (viii) a vinyl aromatic monomer (30-39%), (ix) a 1-8C alkyl methacrylate (61-70%) and (x) a crosslinking monomer (0-3%) and a second shell (5-20%) obtained by polymerization of (xi) a 1-8C alkyl methacrylate (70-98%) and (xii) a 1-8C alkyl acrylate (2-30%), the weight ratio first : second shell being 2 : 1-1 : 2; and optionally (D) conventional additives (up to 20%). An independent claim is also included for production of the mixtures by melt mixing of the components.
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公开(公告)号：BRPI0618534A2
公开(公告)日：2012-05-08
申请号：BRPI0618534
申请日：2006-11-08
Applicant: BASF SE
Inventor： GUNTHERBERG NORBERT , HOFMANN JUERGEN , WABMER KARL-HEINZ , LOTH WOLFGANG , SCHIERHOLZ JEANS-UWE , SCHMAUS PAULUS , MOURS MARIAN , SCHADE CHRISTIAN , ITTEMANN PETER , HEINEN HARTMUT , CZAUDERNA BERNHARD , SAUER MICHAEL , BARDON RAINER , KRUEGER MARCO
Abstract: The invention relates to a tube bundle heat exchanger (R) for removing dissolved substances from a polymer solution (P) by degassing, having a bundle of tubes (R) which are arranged parallel to one another and vertically and are fastened at both ends in each case in one tube plate (B), and having a degassing region below the lower tube plate (B), having an insert (1) in each tube (R), which insert (1) narrows the free throughflow cross section through the tube (R), and wherein the polymer solution (P) is supplied into the tubes (R) in a single-phase liquid state, and having a casing space around the tubes (R) which is traversed by a heat carrier, wherein the degassing takes place by means of a pressure drop between the inlet pressure of the polymer solution (P) in the tube bundle heat exchanger (R) and the degassing region, characterized in that each insert (1) is designed in such a way as to generate a pressure step between the inlet pressure and the pressure in the degassing region, by means of which pressure step a predefined low residual content of dissolved substances is obtained in the degassed polymer, and an additional heat input which is necessary for this purpose takes place via the heat carrier into the single-phase liquid polymer solution (P).
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公开(公告)号：MX2009008817A
公开(公告)日：2009-10-07
申请号：MX2009008817
申请日：2008-02-18
Applicant: BASF SE
Inventor： WEBER MARTIN , ITTEMANN PETER , HAENSEL WERNER , HOENL HANS
Abstract: La invención se refiere a un compuesto termoplástico para moldeado, que contiene los componentes A, B, C y D en las siguientes cantidades: a) 3 a 91.9% en peso de uno o más copolímeros de estireno A, b) de 3 a 91.9% en peso de una o más poliamidas B, c) 5 a 50% en peso de uno o más polímeros injertados C, d) 0.1 a 25% en peso de un terpolímero D que tenga un porcentaje de oligómeros de menos de 3% en peso, y como una opción, como componentes adicionales otro caucho, y anhídrido F al menos monofuncional, fibra o cargas en forma de partícula G y aditivos adicionales H, en donde el compuesto para moldeado presenta anisotropía considerablemente reducida respecto a la resistencia al choque.
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