公开(公告)号：WO2013098772A1

公开(公告)日：2013-07-04

申请号：PCT/IB2012/057750

申请日：2012-12-27

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： LIMBACH, Michael ,  LINDNER, Ronald ,  LEJKOWSKI, Michael Ludwik ,  KAGEYAMA, Takeharu ,  BODIZS, Gabriella Eva ,  SCHUNK, Stephan ,  FUTTER, Cornelia ,  ROTHER, Jörg

IPC: C07C51/15 ,  C07C51/41 ,  C07B41/08 ,  C07B41/10

CPC classification number: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

Abstract: In a process for preparing an alkalimetalor alkaline earth metal salt of an α,β -ethylenically unsaturated carboxylic acid, a)a transition metal-alkene complex is reacted with CO 2 to give a metallalactone, b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the α,β -ethylenically unsaturated carboxylic acid with the transition metal complex, and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the α,β -ethylenically unsaturated carboxylic acid and regenerate the transition metal-alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is, for example, ethene. The transition metal complex comprises, for example, nickel and a bidentate P,P, P,N, P,O or P,carbene ligand, such as 1,2-bis(di- tert -butylphosphino)ethane.

Abstract translation: 在制备α，β-烯属不饱和羧酸的碱金属碱土金属盐的方法中，a）过渡金属 - 烯烃络合物与CO 2反应得到金属内酯，b）金属内酯与碱反应，得到 α，β-烯键式不饱和羧酸的碱金属或碱土金属盐与过渡金属络合物的加合物，和c）加合物与烯烃反应以释放α，β-烯属的碱金属盐碱金属盐 不饱和羧酸并再生过渡金属 - 烯烃络合物。 碱选自碱金属或碱土金属氢氧化物和碱金属或碱土金属超碱物。烯烃是例如乙烯。 过渡金属络合物包括例如镍和二齿P，P，P，N，P，O或P，卡宾配体，例如1,2-双（二叔丁基膦基）乙烷。

公开(公告)号：WO2015173276A1

公开(公告)日：2015-11-19

申请号：PCT/EP2015/060535

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  JEVTOVIKJ, Ivana ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  STIEBER, Sabine Chantal Eileen ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  LEJKOWSKI, Michael ,  KAGEYAMA, Takeharu ,  SCHUNK, Stephan A.

IPC: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

CPC classification number: C07C51/15 ,  B01J31/2409 ,  B01J31/2433 ,  B01J31/2452 ,  B01J31/2476 ,  B01J2231/32 ,  B01J2531/824 ,  B01J2531/847 ,  C07C57/04

Abstract: Catalytic process for preparing an α, β -ethylenically unsaturated carboxylic acid salt, comprising reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α, β -ethylenically unsaturated carboxylic acid salt with a base, the carboxylation catalyst being a transition metal complex, which comprises a structurally constrained bidentate P,X ligand, wherein X is selected from the group consisting of P, N, O, and carbene, the P and X atom are separated by 2 to 4 bridging atoms, and wherein the bridging atoms are part of at least one 5- to 7-membered cyclic substructure. A further catalytic processes for preparing α, β -ethylenically unsaturated carboxylic acid derivatives from CO 2 and an alkene is provided.

Abstract translation: 用于制备α，β-烯键式不饱和羧酸盐的催化方法，包括在羧化催化剂存在下使烯烃和二氧化碳反应，并用碱释放α，β-烯属不饱和羧酸盐，羧化催化剂为 过渡金属络合物，其包含结构受限的二齿P，X配体，其中X选自P，N，O和卡宾，P和X原子被2至4个桥连原子分开，并且其中 桥连原子是至少一个5-至7-元环结构的一部分。 提供了从CO 2和烯烃制备α，β-烯键式不饱和羧酸衍生物的另外的催化方法。

公开(公告)号：EP3142992B1

公开(公告)日：2018-09-26

申请号：EP15722197.9

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  JEVTOVIKJ, Ivana ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  STIEBER, Sabine Chantal Eileen ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  LEJKOWSKI, Michael ,  KAGEYAMA, Takeharu ,  SCHUNK, Stephan A.

IPC: B01J31/24 ,  C07C51/15

CPC classification number: C07C51/15 ,  B01J31/2409 ,  B01J31/2433 ,  B01J31/2452 ,  B01J31/2476 ,  B01J2231/32 ,  B01J2531/824 ,  B01J2531/847 ,  C07C57/04

Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α,β-ethylenically unsaturated carboxylic acid salt with a base, the carboxylation catalyst being a transition metal complex, which comprises a structurally constrained bidentate P,X ligand, wherein X is selected from the group consisting of P, N, O, and carbene, the P and X atom are separated by 2 to 4 bridging atoms, and wherein the bridging atoms are part of at least one 5- to 7-membered cyclic substructure. A further catalytic processes for preparing α,βethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene is provided.

公开(公告)号：EP3142992A1

公开(公告)日：2017-03-22

申请号：EP15722197.9

申请日：2015-05-13

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  JEVTOVIKJ, Ivana ,  HUGUET SUBIELA, Nuria ,  GORDILLO, Alvaro ,  STIEBER, Sabine Chantal Eileen ,  LINDNER, Ronald ,  BRU ROIG, Miriam ,  LEJKOWSKI, Michael ,  KAGEYAMA, Takeharu ,  SCHUNK, Stephan A.

IPC: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

CPC classification number: C07C51/15 ,  B01J31/2409 ,  B01J31/2433 ,  B01J31/2452 ,  B01J31/2476 ,  B01J2231/32 ,  B01J2531/824 ,  B01J2531/847 ,  C07C57/04

Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α,β-ethylenically unsaturated carboxylic acid salt with a base, the carboxylation catalyst being a transition metal complex, which comprises a structurally constrained bidentate P,X ligand, wherein X is selected from the group consisting of P, N, O, and carbene, the P and X atom are separated by 2 to 4 bridging atoms, and wherein the bridging atoms are part of at least one 5- to 7-membered cyclic substructure. A further catalytic processes for preparing α-βethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene is provided.

Abstract translation: 用于制备α，β-烯键式不饱和羧酸盐的催化方法，包括在羧化催化剂存在下使烯烃和二氧化碳反应并与碱释放α，β-烯属不饱和羧酸盐，羧化催化剂为 过渡金属络合物，其包含结构受限的二齿P，X配体，其中X选自P，N，O和卡宾，P和X原子被2至4个桥连原子分开，并且其中 桥连原子是至少一个5-至7-元环结构的一部分。 提供了从CO 2和烯烃制备α，β-烯键式不饱和羧酸衍生物的另外的催化方法。

公开(公告)号：EP2797869A1

公开(公告)日：2014-11-05

申请号：EP12861287.6

申请日：2012-12-27

Applicant: BASF SE

Inventor： LIMBACH, Michael ,  LINDNER, Ronald ,  LEJKOWSKI, Michael Ludwik ,  KAGEYAMA, Takeharu ,  BODIZS, Gabriella Eva ,  SCHUNK, Stephan ,  FUTTER, Cornelia ,  ROTHER, Jörg

IPC: C07C51/15 ,  C07C51/41 ,  C07B41/08 ,  C07B41/10

CPC classification number: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

Abstract: In a process for preparing an alkalimetalor alkaline earth metal salt of an
α,β -ethylenically unsaturated carboxylic acid, a)a transition metal-alkene complex is reacted with CO
2 to give a metallalactone, b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the
α,β -ethylenically unsaturated carboxylic acid with the transition metal complex, and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the
α,β -ethylenically unsaturated carboxylic acid and regenerate the transition metal-alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is, for example, ethene. The transition metal complex comprises, for example, nickel and a bidentate P,P, P,N, P,O or P,carbene ligand, such as 1,2-bis(di-
tert -butylphosphino)ethane.