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公开(公告)号：CA3047026A1
公开(公告)日：2018-06-21
申请号：CA3047026
申请日：2017-12-07
Applicant: BASF SE
Inventor： FUCHS YANNICK , DETERING JUERGEN , MEISE MARKUS , WITTELER HELMUT , SCHMIDT-HANSBERG BENJAMIN , ESPER CLAUDIA , SCHMITT MARCEL , DE MORAGAS MARIA
Abstract: The present invention relates to a method for producing water-soluble films, wherein the water-soluble film comprises at least one layer S1) containing or consisting of a polymer composition P1), obtainable by free-radical polymerization of a monomer composition M1) which contains at least one monomer A) selected from a,ß-ethylenically unsaturated mono-and dicarboxylic acids, salts of a,ß-ethylenically unsaturated mono-and dicarboxylic acids, anhydrides, a,ß--ethylenically unsaturated mono-and dicarboxylic acids, and mixtures thereof, in the presence of at least one polyether component PE), which is selected from polyetherols having a number average molecular weight of at least 200 g/mol, mono-and di-(C1-C6-alkyl) ethers of such polyetherols, polyether groups-containing surfactants and mixtures thereof, wherein the film can have further layers, and wherein the layers are cast on a support material.
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公开(公告)号：CA3045738A1
公开(公告)日：2018-06-21
申请号：CA3045738
申请日：2017-12-15
Applicant: BASF SE
Inventor： FUCHS YANNICK , DETERING JUERGEN , MEISE MARKUS , SCHMIDT-HANSBERG BENJAMIN , ESPER CLAUDIA , NEUMANN JESSICA
Abstract: The present invention relates to a washing and cleaning multi-layer film comprising at least one layer containing a polymer composition or consisting of a polymer composition, obtainable by radical polymerization of a monomer composition which contains at least one a,ß-ethylenically unsaturated carboxylic acid or a salt or an anhydride thereof, wherein the radical polymerization takes place in the presence of at least one polyether component. The invention further relates to a method for producing such a multi-layered film, to the use of such a multi-layered film and to a covering or coating for a washing or cleaning composition portion which comprises such a multi-layered film or consists thereof.
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公开(公告)号：AU2018265476A1
公开(公告)日：2019-11-21
申请号：AU2018265476
申请日：2018-05-11
Applicant: BASF SE
Inventor： KALT MARKUS , RUDE JANINE , WITTELER HELMUT , MEISE MARKUS , KLIPPEL FRANK , SCHROEDER-GRIMONPONT TINA , SEELMANN-EGGEBERT HANS-PETER
IPC: C08G69/04 , C07C231/02 , C07C233/36
Abstract: A polymeric stabilizing agent selected from poly-lysine derivatives obtained by the process comprising the steps of: I. heating an aqueous lysine solution to boiling II. increasing temperature of the aqueous lysine solution to a reaction temperature in the range of about 105°C to about 180°C Ill. keep the reaction temperature in the range of about 105°C to about 180°C until i. melt viscosity of the reaction mixture in the range of about 350 mPa*s to about 6,500 mPa*s when measured at 160°C and ii. an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved IV. optionally, the vacuum applied is released V. add alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol% to 10 mol%, relative to the theoretical amount of poly-lysine comprised in the reaction mixture VI. increase or keep the reaction temperature in the range of about 105°C to about 180°C until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is ≤ 9% by weight, relative to the total weight of the reaction mixture, wherein vacuum is applied either in step (a), (b) and/or (c) and water is removed continuously during the whole process.
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Patent Agency Ranking4.发明专利
公开(公告)号：CA3017788A1
公开(公告)日：2017-09-21
申请号：CA3017788
申请日：2017-03-15
Applicant: BASF SE
Inventor： FUCHS YANNICK , DETERING JUERGEN , MEISE MARKUS , SCHMIDT-HANSBERG BENJAMIN , ESPER CLAUDIA
IPC: C08F220/06 , C08F2/30 , C08F20/06 , C08J5/18 , C11D3/37
Abstract: The present invention relates to a washing- and cleaning-active polymer film which contains a polymer composition P) or is composed of a polymer composition P) which is obtainable by free-radical polymerization of a monomer composition M), wherein the monomer composition M) contains at least one a,ß-ethylenically unsaturated carboxylic acid or a salt thereof and is subjected to a free-radical polymerization in the presence of at least one polyether component. The invention further relates to a process for producing such a washing- and cleaning-active polymer film, to the use of such a polymer film and to a wrapping or coating for a washing or cleaning composition portion which comprises such a polymer film or consists thereof.
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公开(公告)号：AU2018264672A1
公开(公告)日：2019-11-21
申请号：AU2018264672
申请日：2018-04-17
Applicant: BASF SE
Inventor： KALT MARKUS , WITTELER HELMUT , SCHROEDER-GRIMONPONT TINA , MEISE MARKUS , SEELMANN-EGGEBERT HANS-PETER , KLIPPEL FRANK
IPC: C08G69/04 , C07C231/02 , C07C233/36
Abstract: A poly-lysine derivative obtained by a process comprising the steps of (a) heating an aqueous lysine solution to boiling (b) increasing temperature of the aqueous lysine solution to a reaction temperature in the range of about 105°C to about 180°C (c) keep the reaction temperature in the range of about 105°C to about 180°C until i. melt viscosity of the reaction mixture in the range of about 350 m Pa*s to about 6,500 m Pa*s when measured at 160°C and ii. an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved (d) optionally, the vacuum applied is released (e) add alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol% to 10 mol%, relative to the theoretical amount of poly-lysine comprised in the reaction mixture (f) increase or keep the reaction temperature in the range of about 105°C to about 180°C until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is ≤ 9% by weight, relative to the total weight of the reaction mixture. wherein vacuum is applied either in step (a), (b) and/or (c) and water is removed continu- ously during the whole process.
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公开(公告)号：CA3061276A1
公开(公告)日：2018-11-15
申请号：CA3061276
申请日：2018-05-11
Applicant: BASF SE
Inventor： KALT MARKUS , RUDE JANINE , WITTELER HELMUT , MEISE MARKUS , KLIPPEL FRANK , SCHROEDER-GRIMONPONT TINA , SEELMANN-EGGEBERT HANS-PETER
IPC: C08G69/04 , C07C231/02 , C07C233/36
Abstract: A polymeric stabilizing agent selected from poly-lysine derivatives obtained by the process comprising the steps of: I. heating an aqueous lysine solution to boiling II. increasing temperature of the aqueous lysine solution to a reaction temperature in the range of about 105°C to about 180°C Ill. keep the reaction temperature in the range of about 105°C to about 180°C until i. melt viscosity of the reaction mixture in the range of about 350 mPa*s to about 6,500 mPa*s when measured at 160°C and ii. an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved IV. optionally, the vacuum applied is released V. add alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol% to 10 mol%, relative to the theoretical amount of poly-lysine comprised in the reaction mixture VI. increase or keep the reaction temperature in the range of about 105°C to about 180°C until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is = 9% by weight, relative to the total weight of the reaction mixture, wherein vacuum is applied either in step (a), (b) and/or (c) and water is removed continuously during the whole process.
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公开(公告)号：CA3061199A1
公开(公告)日：2018-11-15
申请号：CA3061199
申请日：2018-04-17
Applicant: BASF SE
Inventor： KALT MARKUS , WITTELER HELMUT , SCHROEDER-GRIMONPONT TINA , MEISE MARKUS , SEELMANN-EGGEBERT HANS-PETER , KLIPPEL FRANK
IPC: C08G69/04 , C07C231/02 , C07C233/36
Abstract: A poly-lysine derivative obtained by a process comprising the steps of (a) heating an aqueous lysine solution to boiling (b) increasing temperature of the aqueous lysine solution to a reaction temperature in the range of about 105°C to about 180°C (c) keep the reaction temperature in the range of about 105°C to about 180°C until i. melt viscosity of the reaction mixture in the range of about 350 m Pa*s to about 6,500 m Pa*s when measured at 160°C and ii. an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved (d) optionally, the vacuum applied is released (e) add alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol% to 10 mol%, relative to the theoretical amount of poly-lysine comprised in the reaction mixture (f) increase or keep the reaction temperature in the range of about 105°C to about 180°C until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is = 9% by weight, relative to the total weight of the reaction mixture. wherein vacuum is applied either in step (a), (b) and/or (c) and water is removed continu- ously during the whole process.
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公开(公告)号：CA3047197A1
公开(公告)日：2018-06-21
申请号：CA3047197
申请日：2017-12-15
Applicant: BASF SE
Inventor： MEISE MARKUS , FUCHS YANNICK , WITTELER HELMUT , GARCIA MARCOS ALEJANDRA , DETERING JUERGEN , SCHMIDT-HANSBERG BENJAMIN
Abstract: The present invention relates to a multi-layered film comprising at least one layer having a polymer composition or consisting of a polymer composition, obtainable by radical polymerization of a monomer composition, which contains at least one monomer A), which is selected using a,ß-ethylenically unsaturated mono and dicarboxylic acids, salts of an a,ß-ethylenically unsaturated mono and dicarboxylic acid, anhydrides of a,ß-ethylenically unsaturated mono and dicarboxylic acids and mixtures thereof, wherein the radical polymerization takes place in the presence of at least one polyether component. The invention further relates to a method for producing such a multi-layered film, different uses of said type of multi-layered film and specifically to a covering or coating for a washing, cleaning or dishwasher agent portion which comprises such a multi-layered film or consists thereof. The invention also relates to washing, cleaning or dishwasher agents which have such a multi-layered film.
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