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    METHOD FOR HYDROGENATING AROMATIC COMPOUNDS
    2.
    发明申请
    METHOD FOR HYDROGENATING AROMATIC COMPOUNDS 审中-公开
    氢化芳族化合物的方法

    公开(公告)号：US20160304436A1

    公开(公告)日：2016-10-20

    申请号：US15103652

    申请日：2014-12-10

    Applicant: BASF SE

    Inventor： Bernd Bastian SCHAACK ,  Martin BOCK ,  Kirsten DAHMEN

    IPC: C07C209/72

    CPC classification number: C07C209/72 ,  C07C2601/14 ,  C07C211/36

    Abstract: The present invention relates to a method for hydrogenating aromatic compounds with hydrogen in the presence of a catalyst, in which the catalyst comprises ruthenium on a zirconium oxide support material, and also the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating aromatic compounds.

    Abstract translation: 本发明涉及一种在催化剂存在下用氢气氢化芳族化合物的方法，其中催化剂在氧化锆载体材料上包含钌，以及在氧化锆载体材料上使用包含钌的催化剂进行氢化 芳香族化合物。

    METHOD FOR PRODUCING HEXAMETHYLENEDIAMINE
    4.
    发明申请
    METHOD FOR PRODUCING HEXAMETHYLENEDIAMINE 审中-公开
    生产十六烷二胺的方法

    公开(公告)号：US20160326092A1

    公开(公告)日：2016-11-10

    申请号：US15102947

    申请日：2014-12-12

    Applicant: BASF SE

    Inventor： Christoph MÜLLER ,  Martin BOCK ,  Marion DA SILVA ,  Rolf-Hartmuth FISCHER ,  Benoit BLANK ,  Alois KINDLER ,  Johann-Peter MELDER ,  Bernhard OTTO ,  Mathias SCHELWIES ,  Andreas HENNINGER

    IPC: C07C209/16 ,  B01J27/19 ,  B01J25/02 ,  C07C29/17 ,  C07C209/86

    CPC classification number: C07C209/16 ,  B01J25/02 ,  B01J27/19 ,  C07C29/177 ,  C07C209/86 ,  C07C31/20 ,  C07C211/12

    Abstract: The invention relates to a method for producing hexamethylenediamine, wherein a) a muconic acid starting material is provided, which is selected from among muconic acid, esters of muconic acid, lactones of muconic acid, and mixtures thereof, b) the muconic acid starting material is subjected to a reaction with hydrogen in the presence of at least one hydrogenation catalyst in order to form 1,6-hexanediol, and c) the 1,6-hexanediol obtained in step b) is subjected to amination in the presence of an amination catalyst in order to obtain hexamethylenediamine. The invention further relates to hexamethylenediamine which can be produced by means of said method.

    Abstract translation: 本发明涉及一种生产六亚甲基二胺的方法，其中a）提供了一种粘康酸起始物质，其选自粘康酸，粘康酸的酯，粘康酸的内酯及其混合物，b）粘康酸起始物质 在至少一种氢化催化剂的存在下与氢反应以形成1,6-己二醇，和c）将步骤b）中获得的1,6-己二醇在胺化反应中进行胺化 催化剂以获得六亚甲基二胺。 本发明还涉及可以通过所述方法制备的六亚甲基二胺。

    METHOD OF SEPARATING ACIDS FROM CHEMICAL REACTION MIXTURES BY MEANS OF APOLAR AMINES
    6.
    发明申请
    METHOD OF SEPARATING ACIDS FROM CHEMICAL REACTION MIXTURES BY MEANS OF APOLAR AMINES 有权
    通过APOLAR AMINES分离化学反应混合物中的酸的方法

    公开(公告)号：US20160251384A1

    公开(公告)日：2016-09-01

    申请号：US15148430

    申请日：2016-05-06

    Applicant: BASF SE

    Inventor： OLIVER HUTTENLOCH ,  Patrick DECK ,  Holger GANZ ,  Michael MAUSS ,  Wolfgang KÖRNIG ,  Martin BOCK

    IPC: C07F9/22

    CPC classification number: C07F9/224 ,  C07B63/00

    Abstract: A process for the removal of acids from reaction mixtures, comprising at least one product of value which is sparingly soluble in water, by at least one unpolar amine as an auxiliary base, which includes: a) reacting the auxiliary base with the acid with formation of a salt; b) reacting the salt formed in step a) with a further base which accepts the acid with liberation of the auxiliary base and combines with the acid to be accepted from the auxiliary base to form a salt which is very readily soluble in water; c) extraction of the mixture obtained in step b) with water or an aqueous medium, wherein the salt of the further base dissolves in the aqueous phase and the product of value, or the solution of the product of value, in a suitable solvent and the auxiliary base form at least one separate nonaqueous phase; and d) removal by distillation of at least part of any solvent present from the at least one nonaqueous phase obtained in step c), to form two nonmiscible liquid phases.

    Abstract translation: 通过至少一种非极性胺作为辅助碱从反应混合物中除去酸的方法，该方法包括至少一种值得微溶于水的产物，其包括：a）使辅助碱与酸形成反应 的盐 b）使步骤a）中形成的盐与另外的碱反应，其另外的碱可以通过辅助碱的释放与酸接触，并与待辅助的酸结合，形成非常容易溶于水的盐; c）用水或水性介质萃取步骤b）中得到的混合物，其中另外碱的盐溶解在水相中，并且将有价值的产物或产品的溶液在合适的溶剂中溶解， 辅助碱形成至少一个单独的非水相; 和d）通过蒸馏除去存在于步骤c）中获得的至少一种非水相中的任何溶剂的至少一部分，以形成两个不可混溶的液相。

    METHOD FOR PREPARING PHENYLCYCLOHEXANE
    7.
    发明申请
    METHOD FOR PREPARING PHENYLCYCLOHEXANE 审中-公开
    制备苯甲醇的方法

    公开(公告)号：US20140100400A1

    公开(公告)日：2014-04-10

    申请号：US14041380

    申请日：2013-09-30

    Applicant: BASF SE

    Inventor： Martin BOCK

    IPC: C07C5/11

    CPC classification number: C07C5/11 ,  C07C2601/14 ,  C07C13/28

    Abstract: A method for preparing a phenylcyclohexane of formula I by hydrogenation of a biphenyl of formula II with hydrogen in the presence of Raney nickel, where R1 and R2 both have the same meaning in formulas I and II and independently of one another are hydrogen atoms, C1- to C10-alkyl groups or phenyl groups, wherein the hydrogenation takes place in the presence of 0 to 20 parts by weight of water to 100 parts by weight of Raney nickel.

    Abstract translation: 通过在阮内镍的存在下氢与式Ⅱ联苯制备式I的苯基环己烷的方法，其中R 1和R 2在式I和II中都具有相同的含义并且彼此独立地是氢原子，C1 - 至C10烷基或苯基，其中在0至20重量份的水存在下进行氢化至100重量份的阮内镍。

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