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公开(公告)号:WO2023274726A1
公开(公告)日:2023-01-05
申请号:PCT/EP2022/066302
申请日:2022-06-15
Applicant: BASF SE
Inventor: LEE, Robert Matthew , RIEWALD, Felix Florian , KURZHALS, Philipp , SOMMER, Heino
IPC: H01M4/525 , C01G53/00 , C01G53/50 , C01P2002/60 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M10/0525 , H01M4/131 , H01M4/621 , H01M4/625
Abstract: Particulate material of the composition LiaMgb)i+x(NicM1dM2e)1-xO2 wherein M1 is selected from Ti, Zr, Nb, Mo, and W, and combinations of at least two of the aforementioned, M2 is selected from Al, Co and Mn and combinations of at least two of the aforementioned, a : b is in the range of from 100:1 to 400:1, and a + b = 1, c : d is in the range of from 40:1 to 250:1, and c : e is in the range of from 12:1 to 50:1, and c + d + e = 1, total molar ratio of (Li + Mg) to (Ni + M1 + M2) is in the range of from 1 :1 to 1.05:1, 0.00
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公开(公告)号:WO2023061826A1
公开(公告)日:2023-04-20
申请号:PCT/EP2022/077697
申请日:2022-10-05
Applicant: BASF SE
Inventor: KURZHALS, Philipp , SOMMER, Heino , RIEWALD, Felix Florian
IPC: C01G53/00
Abstract: Process for making an electrode active material wherein said process comprises the following steps: (a) Providing an (oxy)hydroxide of TM wherein TM is transition metal and includes nickel and, optionally, at least one of cobalt and manganese, wherein the nickel content is at least 80 mol-% referring to TM, (b) mixing said (oxy)hydroxide of TM with 75 to 85 mol-% of a lithium source, referring to TM, and at least one compound of Mg or Al, (c) treating the resultant mixture at a temperature at a temperature in the range of from 400 to 700°C, thereby obtaining a powder, (d) mixing the powder from step (c) with a source of lithium and with at least one compound of Mg or Al and with at least one compound of Nb, Ta, W, Ti or Zr, (e) treating the mixture obtained from step (d) thermally at a temperature in the range of from 550 to 800°C.
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公开(公告)号:WO2022106268A1
公开(公告)日:2022-05-27
申请号:PCT/EP2021/081174
申请日:2021-11-10
Applicant: BASF SE
Inventor: SOMMER, Heino , RIEWALD, Felix Florian , KURZHALS, Philipp
Abstract: The present invention is related to a process for making an electrode active material wherein said process comprises the following steps: (a) Providing a hydroxide TM(OH)2 or at least one oxide TMO or at least one oxyhydroxide of TM or a combination of at least two of the foregoing wherein TM is one or more metals and contains at least 97 mol-% Ni and, optionally, in total up to 3 mol-% of at least one metal selected from Al, Ti, Zr, V, Co, Zn, Ba, and Mn; (b) mixing said hydroxide TM(OH)2 or oxide TMO or oxyhydroxide of TM or combination with a source of lithium and a source of Mg wherein the molar amount of (Li + Mg) cor-responds to 75 to 95 mol-% of TM; (c) treating the mixture obtained from step (b) thermally at a temperature in the range of from 450 to 650°C, thereby obtaining an intermediate; (d) mixing the intermediate from step (c) with a source of Li and with at least one compound of a metal M1 selected from Al, Zr, Co, Mn, Nb, Ta, Mo, and W; (e) treating the mixture obtained from step (d) thermally at a temperature in the range of from 500 to 850°C.
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公开(公告)号:EP4416106A1
公开(公告)日:2024-08-21
申请号:EP22801727.3
申请日:2022-10-05
Applicant: BASF SE
Inventor: KURZHALS, Philipp , SOMMER, Heino , RIEWALD, Felix Florian
IPC: C01G53/00
CPC classification number: C01G53/50 , C01P2006/4020130101 , C01P2004/6020130101 , Y02E60/10
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公开(公告)号:EP4095102A1
公开(公告)日:2022-11-30
申请号:EP21176525.0
申请日:2021-05-28
Applicant: BASF SE
Inventor: LENNARTZ, Michael , SOMMER, Heino , RIEWALD, Felix Florian , SCHEIFF, Frederik , EHRHARDT, Karl Rainer , KIPFER, Tim , BOCK, Moritz
IPC: C01G53/00 , H01M4/131 , H01M4/505 , H01M4/525 , H01M4/1391
Abstract: Process for making a particulate compound according to general formula Li 1+x TM 1-x O 2 with x being in the range of from -0.02 to +0.15 and with TM representing nickel and at least one metal selected from Co and Mn and, optionally, including at least one of Al, Mg, Ti, Zr, Nb, Ta, Mo, and W, wherein said process comprises the steps of:
(a) providing a nanoparticulate oxide or (oxy)hydroxide of each of the metals of TM,
(b) mixing the nanoparticulate oxides or (oxy)hydroxides in the stoichiometry targeted for TM under addition of a source of lithium selected from LiOH and Li 2 CO 3 and Li 2 O 2 and Li 2 O, and
(c) treating the mixture from step (c) at a temperature in the range of from 700 to 950°C.-
公开(公告)号:EP4074660A1
公开(公告)日:2022-10-19
申请号:EP21168417.0
申请日:2021-04-14
Applicant: BASF SE
Inventor: TER MAAT, Johan , KURZHALS, Philipp , RIEWALD, Felix Florian , SOMMER, Heino
Abstract: Process for making an electrode active material wherein said process comprises the following steps:
(a) Providing an (oxy)hydroxide of TM wherein TM is one or more metals wherein at least 90 mol% is Ni, referring to TM,
(b) Contacting said (oxy)hydroxide of TM with an aqueous slurry or colloidal solution of an oxyhydroxide of Zr or Ti, followed by removal of water,
(c) heating said treated (oxy)hydroxide of TM from step (b) at a temperature in the range of from 700 to 1000°C, thereby obtaining a Zr or Ti containing oxide TMO or an oxyhydroxide of TM with a residual moisture content of at most 100 ppm,
(d) mixing said oxide or oxyhydroxide from step (c) with a source of lithium and with at least one compound of Mg or Al and with at least one compound of Nb, Ta, W, or with either a compound of Ti or Zr,
(e) treating the mixture obtained from step (d) thermally at a temperature in the range of from 550 to 850°C.-
公开(公告)号:EP4011834A1
公开(公告)日:2022-06-15
申请号:EP20212953.2
申请日:2020-12-10
Applicant: BASF SE
Inventor: HARTMANN, Pascal , SOMMER, Heino , TOMOTA, Yohko , LEE, Robert Matthew , SÜLING, Carsten , MICHEL, Kathrin , RIEWALD, Felix Florian
Abstract: Process for making an electrode active material comprising the steps of:
(a) providing a target specification containing at least three electrode active material properties selected from elemental composition, primary particle size, crystallite size, average secondary particle diameter (D50), particle diameter distribution, residual lithium content, specific surface (BET), shape of secondary particles, lattice parameters, press density, electrochemical performance, tap density,
(b) providing process parameters selected from calcination temperature, calcination duration, saggar loading, gas composition and gas flow, and composition of mixture to be subjected to calcination,
(c) providing a model of relationship between electrode active material properties in accordance with (a) and process parameters according to (b),
(d) manufacturing an electrode active according to a process with parameters according to step (b) in a manufacturing unit,
(e) obtaining electrode active material sample(s) generated from manufacturing process (d)
(f) performing measurements on said sample(s) to determine the properties as specified in (a),
(g) providing results from step (f) to a processing device,
(h) determining the difference between target specification in accordance with (a) and sample measurements according to (f),
(i) refining the model from step (c),
(j) deriving new process parameters from the refined model from step (i), and
(k) providing an electronic signal based on new process parameters of step (j) to a production control function in the manufacturing unit.-
公开(公告)号:EP4364218A1
公开(公告)日:2024-05-08
申请号:EP22734271.4
申请日:2022-06-15
Applicant: BASF SE
Inventor: LEE, Robert Matthew , RIEWALD, Felix Florian , KURZHALS, Philipp , SOMMER, Heino
CPC classification number: C01G53/50 , C01P2006/4020130101 , C01P2004/6120130101 , C01P2002/6020130101 , C01P2006/1220130101 , H01M4/525 , H01M4/131 , H01M4/625 , H01M4/621 , H01M10/0525 , Y02E60/10
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公开(公告)号:EP4247760A1
公开(公告)日:2023-09-27
申请号:EP21802764.7
申请日:2021-11-10
Applicant: BASF SE
Inventor: SOMMER, Heino , RIEWALD, Felix Florian , KURZHALS, Philipp
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公开(公告)号:EP4056535A1
公开(公告)日:2022-09-14
申请号:EP21162385.5
申请日:2021-03-12
Applicant: BASF SE
Inventor: RIEWALD, Felix Florian , KURZHALS, Philipp , STREMPEL, Verena , SOMMER, Heino
Abstract: Process for making a partially coated electrode active material wherein said process comprises the following steps:
(a) formula Li 1+x TM 1-x O 2 , wherein TM contains at least 90 mol-% Ni, and x is in the range of from - 0.05 to 0.05,
(b) treating said electrode active material with an alkoxide or amide of zirconium,
(c) treating the material obtained in step (b) with moisture,
(d) repeating the sequence of steps (b) and (c) four to twelve times,
(e) performing a post-treatment by heating the material obtained after the last step (d) at a temperature from 250 to 750°C.
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