公开(公告)号：WO2010072723A3

公开(公告)日：2010-09-10

申请号：PCT/EP2009067661

申请日：2009-12-21

Applicant: BASF SE ,  DOBNER CORNELIA KATHARINA ,  ALTWASSER STEFAN ,  WILMER HAGEN ,  ROSOWSKI FRANK

Inventor： DOBNER CORNELIA KATHARINA ,  ALTWASSER STEFAN ,  WILMER HAGEN ,  ROSOWSKI FRANK

IPC: B01J27/198 ,  B01J35/02 ,  B01J35/10 ,  C07C51/215

CPC classification number: B01J35/023 ,  B01J27/198 ,  B01J35/002 ,  B01J35/02 ,  B01J35/026 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0018 ,  C07C51/215 ,  Y10T428/2975 ,  C07C57/145

Abstract: The invention relates to a catalyst molded body for producing maleic anhydride by gas-phase oxidation of a hydrocarbon having at least four carbon atoms, comprising a catalytically active mass, which contains vanadium, phosphorus, and oxygen. The catalyst molded body comprises a substantially cylindrical body having at least two, preferably four, inner through-bores substantially parallel to the cylinder axis of the body. The catalyst molded body has a large outer surface area, a lower pressure loss, and sufficient mechanical stability.

Abstract translation: 用于通过气相氧化具有至少四个碳原子的烃来生产马来酸酐的成型催化剂体包含含有钒，磷和氧的催化活性材料。 该催化剂成型体具有基本上圆柱形的本体，该本体具有至少两个，优选四个与本体的圆柱轴线基本上平行的连续的内孔。 催化剂成型体具有较大的外表面，较低的压降和足够的机械稳定性。

公开(公告)号：WO2014013397A3

公开(公告)日：2014-03-06

申请号：PCT/IB2013055729

申请日：2013-07-12

Applicant: BASF SE ,  BASF SCHWEIZ AG ,  BASF CHINA CO LTD

Inventor： KRAEMER MICHAEL ,  ZUEHLKE JUERGEN ,  ALTWASSER STEFAN ,  FISCHER NICO FREDERIK ,  ROSOWSKI FRANK ,  ALLMANN HANS-MARTIN

IPC: B01J23/16 ,  C07C51/265

CPC classification number: B01J23/22 ,  B01J35/0046 ,  B01J35/006 ,  B01J35/1014 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0244 ,  B01J37/04 ,  C07D307/89

Abstract: Provided is a catalyst for preparing carboxylic acids and/or carboxylic anhydrides, which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonite having a maximum content of crystalline valentinite of 5% by weight. The present invention further provides a process for gas-phase oxidation in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonite having a maximum content of crystalline valentinite of 5 % by weight.

Abstract translation: 本发明涉及用于生产羧酸和/或具有多个连续布置的催化剂层的羧酸酐的催化剂，在制备锑酸钒用的5重量％结晶Valentinit的最大含量使用。 此外，本发明涉及一种用于气相氧化的方法，其中，引导气体流，其含有至少一种烃和分子氧由包括多个连续布置的催化剂层的催化剂，以及它们的生产，钒锑酸盐与结晶Valentinit的最大含量 5，使用重量％。

公开(公告)号：WO2013124771A3

公开(公告)日：2016-09-01

申请号：PCT/IB2013051243

申请日：2013-02-15

Applicant: BASF SE ,  BASF (CHINA) COMPANY LTD

Inventor： KARPOV ANDREY ,  DOBNER CORNELIA KATHARINA ,  ROSOWSKI FRANK ,  EICHELBAUM MAIK ,  TRUNSCHKE ANNETTE ,  SCHLOEGL ROBERT

IPC: B01J27/198 ,  B01J35/02 ,  C07C37/00 ,  C07C51/215

CPC classification number: B01J19/0093 ,  B01J2219/00792 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00876 ,  B01J2219/00916 ,  B01J2219/00941 ,  G01N22/00 ,  G01N31/10

Abstract: A catalyst for the gas phase oxidation of organic hydrocarbons comprises a multielement oxide which comprises at least one transition meal such as vanadium, wherein the catalyst has a charge transport activation energy Ec at a temperature of 375 to 425°C of less than 0 kJ/mol. The catalyst serves for preparation of maleic anhydride.

Abstract translation: 用于气相氧化有机烃的催化剂包括多元素氧化物，其包含至少一种过渡膳食，例如钒，其中催化剂在375至425℃的温度下具有小于0kJ / 摩尔。 催化剂用于制备马来酸酐。

公开(公告)号：WO2007135104A8

公开(公告)日：2008-06-12

申请号：PCT/EP2007054841

申请日：2007-05-18

Applicant: BASF SE ,  MACKEWITZ THOMAS ,  ROSOWSKI FRANK ,  TENTEN ANDREAS

Inventor： MACKEWITZ THOMAS ,  ROSOWSKI FRANK ,  TENTEN ANDREAS

IPC: C07D307/89

CPC classification number: C07D307/89 ,  C07C51/265 ,  C07C63/16

Abstract: The invention relates to a method for producing phthalic anhydride by catalytic gas phase oxidation of o-xylol. According to said method, a gaseous mixture of o-xylol and an oxygen-containing gas is guided through at least two reaction zones in a main reactor, the temperature of said reaction zones being adjustable independently of each other, and is reacted to give a gaseous intermediate reaction product which contains unreacted o-xylol, phthalic anhydride reaction products with a lower oxidation state and phthalic anhydride, and the intermediate reaction product is introduced into a secondary reactor. The temperature in the reaction zones in the primary reactor is controlled in such a manner that the concentration of the unreacted o-xylol in the intermediate reaction product is at least 0.5% by weight. The method according to the invention allows an increase in total yield of phthalic anhydride without any or without substantial decrease in product quality.

Abstract translation: 用于通过邻二甲苯，其中其将通过至少两个反应区，其是独立温度可控地转发所描述的，含有氧的气体邻二甲苯的气体混合物，并在主反应器的催化气相氧化制备邻苯二甲酸酐，于气态中间反应产物的方法 反应含有未反应的邻二甲苯，邻苯二甲酸酐欠氧化产品和邻苯二甲酸酐，以及将所述中间反应产物分离成二级反应器，其特征在于，它调节在主反应器中的反应区的温度，即未转化的邻二甲苯中的中间反应产物中的浓度为至少0 ，5重量％（重量）。 该方法允许增加邻苯二甲酸酐的总产没有或没有在产品质量上显著恶化。

公开(公告)号：WO2012049246A3

公开(公告)日：2012-06-14

申请号：PCT/EP2011067887

申请日：2011-10-13

Applicant: BASF SE ,  MACHT JOSEF ,  MUELLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK

Inventor： MACHT JOSEF ,  MUELLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK

IPC: C07C47/22 ,  C07C45/35

CPC classification number: C07C45/35 ,  C07C47/22

Abstract: Disclosed is a method for long-term operation of a heterogeneously catalyzed partial gas phase oxidation of propene to obtain acrolein, in which the propene contained in the fed reaction gas mixture is partially oxidized when said gas mixture penetrates the fixed catalyst bed that is accommodated in two spatially successive temperature zones A, B, and in order to prevent the quality of the fixed catalyst bed from deteriorating during long-term operation, the temperature in at least one of the two temperature zones is raised in such a way that the difference TB- TA becomes greater and greater, where TB is the temperature in temperature zone B and TA is the temperature in temperature zone A.

Abstract translation: 一种用于丙烯的非均相催化部分气相氧化成丙烯醛，其中部分氧化的通过固定催化剂床，其被容纳在两个空间上连续的温度区A，B传递时该气体混合物中，并且，在长期运转中所含的反应气体输入混合物的丙烯的长期操作方法，作为针对一个测量 减少在固定催化剂床的质量，两个温度区中的至少一个的温度提高，以使差TB TA变得越来越大，TB温度区B的温度，和TA是温度区中的温度。

公开(公告)号：WO2010136551A2

公开(公告)日：2010-12-02

申请号：PCT/EP2010057375

申请日：2010-05-28

Applicant: BASF SE ,  KARPOV ANDREY ,  HIBST HARTMUT ,  DEISSLER CHRISTINE ,  DOBNER CORNELIA KATHARINA ,  ROSOWSKI FRANK ,  BREM NADINE ,  SCHUNK STEPHAN

Inventor： KARPOV ANDREY ,  HIBST HARTMUT ,  DEISSLER CHRISTINE ,  DOBNER CORNELIA KATHARINA ,  ROSOWSKI FRANK ,  BREM NADINE ,  SCHUNK STEPHAN

IPC: C07C51/265

CPC classification number: B01J23/686 ,  B01J23/002 ,  B01J23/687 ,  B01J23/8993 ,  B01J27/199 ,  B01J37/0045 ,  B01J2523/00 ,  C07C51/265 ,  C07C63/16 ,  C07C63/26 ,  B01J2523/18 ,  B01J2523/305 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/51 ,  B01J2523/3712 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/17 ,  B01J2523/69 ,  B01J2523/15 ,  B01J2523/56 ,  B01J2523/842

Abstract: The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe * f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, AI, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d = 4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 Å (± 0.04 Å).

Abstract translation: 一种用于烃的气相部分氧化催化剂包括通式（I）的多金属氧化物，AgaMObVcMdOe * F H 2 O（I）其中M是其中锂，钠，钾，铷，铯，铍，镁，钙的至少一个， 锶，钡，硼，铝，镓，铟，硅，锡，铅，磷，锑，铋，Y，钛，锆，铪，钒，铌，钽，铬，钨，锰，RE，铁，钌， 锇，钴，铑，铱，镍，钯，铂，铜，金，锌，镉，镧，铈，镨，钕，钐，铕，钆，铽，镝，钬，铒，铥，镱，路， U被选择的元素，一个具有0.5至1.5的值; b为0.5〜1.5的值，c具有从0.5至1.5，A + b + C的值 是3，D具有小于1的值，例如确定由其中，F为0至20的值，式（I）中氧以外的元素的化合价和频率定义的一个数，在 的晶体结构存在，其粉末X至少为5，在D的特征在于衍射峰= 4.53，3.38，3.32，3.23，2.88，2.57，2.39，2.26，1， 83，1.77埃（±0.04 A）中的晶面间距。

公开(公告)号：WO2010072721A3

公开(公告)日：2010-10-28

申请号：PCT/EP2009067657

申请日：2009-12-21

Applicant: BASF SE ,  DOBNER CORNELIA KATHARINA ,  ALTWASSER STEFAN ,  WILMER HAGEN ,  ROSOWSKI FRANK

Inventor： DOBNER CORNELIA KATHARINA ,  ALTWASSER STEFAN ,  WILMER HAGEN ,  ROSOWSKI FRANK

IPC: B01J27/198 ,  B01J35/02 ,  B01J35/10 ,  C07C51/215

CPC classification number: B01J27/198 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0018 ,  C07C51/215 ,  C07C57/145

Abstract: The catalytically active mass of a catalyst molded body comprises a multi-element oxide containing vanadium and phosphorus. The specific pore volume PV (in ml/g) of the catalyst molded body, the bulk density p of the catalyst molded body (in kg/l), the geometric surface area Ageo (in mm2), and the geometric volume Vgeo (in mm3) of the catalyst molded body satisfy the condition: 0.275 geo/Vgeo. In a method for producing maleic acid anhydride by heterogeneously catalytic gas phase oxidation of a hydrocarbon, the catalyst molded body allows a lower pressure loss and a high yield.

Abstract translation: 成形催化剂体的催化活性组合物包含含钒和含磷的多元素氧化物。 比孔体积PV（以ml / g）的催化剂成型的，该催化剂成型体的催化剂成型体的体积密度ρ（单位为kg /升），则几何表面积地理（以mm 2）和所述几何体积VGEo（以mm 3）满足条件：0.275地理 / VGEo。 在通过催化剂成型体的烃的非均相催化气相氧化制备马来酸酐的方法允许较低的压力损失和较高的产率。

公开(公告)号：EP2558453A4

公开(公告)日：2013-10-23

申请号：EP11768534

申请日：2011-04-06

Applicant: BASF SE

Inventor： ALTWASSER STEFAN ,  ZUEHLKE JUERGEN ,  CHEN HAO ,  DOBNER CORNELIA KATHARINA ,  ROSOWSKI FRANK

IPC: C07D307/89 ,  C07C51/21 ,  C07C51/255

CPC classification number: C07D307/89 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16

公开(公告)号：EP2558198A4

公开(公告)日：2013-11-06

申请号：EP11768541

申请日：2011-04-12

Applicant: BASF SE

Inventor： KRAEMER MICHAEL ,  SCHUBERT MARKUS ,  LAUTENSACK THOMAS ,  HILL THOMAS ,  KOERNER REINHARD ,  ROSOWSKI FRANK ,  ZUEHLKE JUERGEN

IPC: B01J23/22

CPC classification number: B01J21/08 ,  B01J23/22 ,  B01J27/053 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1052 ,  B01J37/0018 ,  C01B17/79

公开(公告)号：EP2558197A4

公开(公告)日：2014-03-26

申请号：EP11768535

申请日：2011-04-12

Applicant: BASF SE

Inventor： KRAEMER MICHAEL ,  SCHUBERT MARKUS ,  LAUTENSACK THOMAS ,  HILL THOMAS ,  KOERNER REINHARD ,  ROSOWSKI FRANK ,  ZUEHLKE JUERGEN

IPC: B01J23/22

CPC classification number: B01J21/08 ,  B01D53/8609 ,  B01D2251/102 ,  B01D2255/202 ,  B01D2255/2022 ,  B01D2255/30 ,  B01D2255/9205 ,  B01D2257/302 ,  B01J23/22 ,  B01J29/06 ,  B01J37/20