公开(公告)号：WO2008116799A1

公开(公告)日：2008-10-02

申请号：PCT/EP2008/053248

申请日：2008-03-18

Applicant: BASF SE ,  CHALLAND, Nina ,  SAVA, Xavier ,  RÖPER, Michael

Inventor： CHALLAND, Nina ,  SAVA, Xavier ,  RÖPER, Michael

IPC: C07C51/00 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

CPC classification number: C07C51/00 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0271 ,  B01J31/2404 ,  B01J2231/625 ,  B01J2531/821 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

Abstract: Die Erfindung betrifft ein Verfahren zur Herstellung von Ameisensäure, bei dem man durch katalytische Hydrierung von Kohlendioxid mit Wasserstoff an einem Katalysator, der ein Metall der Gruppen 8 bis 10 des Periodensystems enthält, in Gegenwart eines primären, sekundären und/oder tertiären Amins das entsprechende Ammoniumformiat erzeugt und das Ammoniumformiat durch Erhitzen in Ameisensäure und das Amin spaltet, dadurch gekennzeichnet, dass das primäre, sekundäre oder tertiäre Amin ausgewählt ist aus den Aminen der Formel I oder deren Gemischen, wobei R 1 bis R 3 gleich oder verschieden sind und Wasserstoff, lineare oder verzweigte Alkylreste mit 1 bis 18 Kohlenstoffatomen, cycloaliphatische Reste mit 5 bis 7 Kohlenstoffatomen, Arylreste und/oder Arylalkylreste bedeuten und mindestens einer der Reste R 1 bis R 3 eine Hydroxylgruppe trägt, und man die Hydrierung in einem Lösungsmittel, das bei Normaldruck einen Siedepunkt ≥105 0C aufweist, durchführt, und man die Ameisensäure in dem das hoch siedende Lösungsmittel enthaltenden Reaktionsgemisch der Hydrierung durch thermische Spaltung des Ammoniumformiats und Abdestillieren der Ameisensäure gewinnt.

Abstract translation: 本发明涉及一种用于生产甲酸的方法，其中二氧化碳的催化氢化与氢气在含有8族的金属的周期表第10的催化剂，在一个伯，仲和/或叔胺的存在下，相应的甲酸铵的方法 产生并通过在甲酸和胺加热的甲酸铵切割，其特征在于，所述伯，仲或叔胺，从式胺I或它们的混合物，其中R _{1 至R 3 是相同的或不同的并且是氢，直链或支链烷基具有1至18个碳原子，具有5至7个碳原子，芳基脂环族基团和/或芳烷基是指与基团中的至少一个R 1 至R 3 携带羟基，氢化在溶剂的沸点下进行= 105 0C aufwe在大气压力 被执行，并且在其中高沸点溶剂包含氢化反应混合物中获得由甲酸铵和蒸馏甲酸的热裂解的甲酸。}

公开(公告)号：EP1527103B1

公开(公告)日：2011-01-05

申请号：EP03766179.0

申请日：2003-07-16

Applicant: BASF SE

Inventor： CHOWDHRY, Mubarik, Mahmood ,  SCHMID, Markus ,  PREISHUBER-PFLÜGL, Peter ,  SAVA, Xavier ,  WEISS, Horst ,  MECKING, Stefan ,  BAUERS, Florian, M.

IPC: C08F2/24 ,  C08F2/22 ,  C08F10/00

CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/26 ,  C08F2/24 ,  C08F4/80 ,  C08F2500/02 ,  C08F2500/03 ,  C08F210/14 ,  C08F212/08 ,  C08F210/06 ,  C08F210/08

Abstract: A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups,and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3' and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z,wherein the variables are defined as follows: M is a transition metal of groups 7 - 10 in the periodic system of the elements;L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0 - 3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.

公开(公告)号：EP2139837A1

公开(公告)日：2010-01-06

申请号：EP08717979.2

申请日：2008-03-18

Applicant: BASF SE

Inventor： CHALLAND, Nina ,  SAVA, Xavier ,  RÖPER, Michael

IPC: C07C51/00 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

CPC classification number: C07C51/00 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0271 ,  B01J31/2404 ,  B01J2231/625 ,  B01J2531/821 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

Abstract: The invention relates to a method for producing formic acid by generating the corresponding ammonium formate by means of catalytic hydrogenation of carbon dioxide with hydrogen on a catalyst comprising a metal of groups 8 through 10 of the periodic system, in the presence of a primary, secondary, and/or tertiary amine, and by cleaving the ammonium formate by heating it in formic acid and the amine, characterized in that the primary, secondary, or tertiary amine is selected from the amines of formula I or the mixtures thereof, R1 through R3 being identical or different and being hydrogen, linear or branched alkyl radicals having 1 to 18 carbon atoms, cycloaliphatic radicals having 5 to 7 carbon atoms, aryl radicals and/or aryl alkyl radicals, at least one of the radicals R1 to R3 carrying a hydroxyl group, and that said hydrogenation is performed in a solvent having a boiling point of ≥105°C at normal pressure, and that the formic acid is obtained in the hydrogenation reaction mixture comprising the high-boiling solvent by thermal cleavage of the ammonium formate and distillation of the formic acid.

Abstract translation: 本发明涉及一种生产甲酸的方法，该方法通过在含有周期系统第8-10族金属的催化剂上，用二氧化碳用氢催化氢化，在伯，仲 ，和/或叔胺，并且通过在甲酸和胺中将甲酸铵加热裂解甲酸铵，其特征在于伯胺，仲胺或叔胺选自式I的胺或其混合物，R1至R3 相同或不同并且是氢，具有1至18个碳原子的直链或支链烷基，具有5至7个碳原子的环脂族基团，芳基和/或芳基烷基，至少一个基团R 1至R 3携带羟基 并且所述氢化在常压下在沸点≥105℃的溶剂中进行，并且甲酸在氢化反应混合物中获得 e通过甲酸铵的热裂解和甲酸的蒸馏包含高沸点溶剂。

公开(公告)号：EP1626998B1

公开(公告)日：2010-09-01

申请号：EP04731348.1

申请日：2004-05-06

Applicant: BASF SE

Inventor： SCHMID, Markus ,  CHOWDHRY, Mubarik, Mahmood ,  PREISHUBER-PFLÜGL, Peter ,  SAVA, Xavier ,  LINDNER, Ekkehard ,  SUNJUK, Mahmoud ,  WEGNER, Peter

IPC: C08F10/00 ,  C08F4/70 ,  C08F2/18

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F2/18 ,  C08F4/7016

Abstract: The invention relates to a method for producing an aqueous polymer dispersion by polymerisation of at least one unsaturated compound in an aqueous medium in the presence of at least one dispersant and one solid polymerisation catalyst.

公开(公告)号：EP1539666B1

公开(公告)日：2009-01-07

申请号：EP03748014.2

申请日：2003-09-12

Applicant: BASF SE

Inventor： VOLLAND, Martin ,  AHLERS, Wolfgang ,  EBEL, Klaus ,  PACIELLO, Rocco ,  RÖPER, Michael ,  MACKEWITZ, Thomas ,  BÖHM, Volker ,  SAVA, Xavier ,  LÖBER, Oliver ,  BEY, Oliver ,  STEPHAN, Jürgen ,  HAESE, Frank

IPC: C07C45/50 ,  C07C47/21 ,  C07C47/12 ,  C07F9/6558

CPC classification number: C07F9/6596 ,  C07C45/50 ,  C07F9/5721 ,  C07F9/5728 ,  C07F9/65522 ,  C07F9/65586 ,  C07F9/65842 ,  C07F9/65848 ,  C07C47/12 ,  C07C47/21

Abstract: The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.