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公开(公告)号：WO2016096512A1
公开(公告)日：2016-06-23
申请号：PCT/EP2015/078864
申请日：2015-12-07
Applicant: BASF SE
Inventor： SCHARF, Florian , SCHWIND, Markus , VAN ASTEN, David , JACOBS, Steven Alan
IPC: H01F1/01
CPC classification number: H01F1/012 , C08K5/0016 , C08K5/06 , C08K5/095 , C08K5/101 , C08K5/151 , C09D133/12 , C09D139/08 , F25B21/00 , F25B2321/002 , G02F1/13363 , C08L33/12 , C08L39/08
Abstract: The invention relates to a magnetocaloric cascade containing a sequence of magnetocaloric material layers having different Curie temperatures T c , wherein - the magnetocaloric material layers include a cold-side outer layer, a hot-side outer layer and at least three inner layers between the cold-side outer layer and the hot-side outer layer, - for each pair of next neighboring magnetocaloric material layers of the magnetocaloric cascade there exists a respective crossing temperature, at which an entropy parameter mΔS of both respective neighboring magnetocaloric material layers assumes the same crossing-point value, the entropy parameter mΔS being defined as a product of the mass m of the respective magnetocaloric material layer and an amount of its isothermal magnetic entropy change ΔS in a magnetic phase transition of the respective magnetocaloric material layer, - at least two of the inner layers have masses m differing from each other and - all crossing-point values of the entropy parameter mΔS of all pairs of next neighboring inner layers are equal, either exactly or within a margin of ±15%, to a mean value of all crossing-point values of all pairs of next neighboring inner layers of the magnetocaloric cascade.
Abstract translation: 本发明涉及一种包含具有不同居里温度Tc的磁热材料层序列的磁热级联，其中 - 磁热材料层包括冷侧外层，热侧外层和冷侧外层之间的至少三层内层， 侧面外层和热侧外层， - 对于磁热级联的每对下一个相邻的磁热材料层，存在相应的交叉温度，在该交叉温度下，两个相邻的磁热材料层的熵参数mΔS呈现相同的交叉 - 点值，将熵参数mΔS定义为相应磁热材料层的质量m与其各自磁热材料层的磁相变中的等温磁熵变ΔS的乘积的乘积， - 至少两个 内层具有彼此不同的质量m，以及熵的所有交叉点值 所有下一个相邻内层对的y参数mΔS精确地或相当于磁热级联的所有下一相邻内层对的所有交叉点值的±15％的裕量内。
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公开(公告)号：WO2016042051A1
公开(公告)日：2016-03-24
申请号：PCT/EP2015/071271
申请日：2015-09-17
Applicant: BASF SE
Inventor： HERMES, Wilfried , SCHWIND, Markus , MOORS, Jürgen , WEICKERT, Mathias
Abstract: The invention relates to the use of thermo-compression bonding (TCB) for bonding electrically conductive contacts to thermoelectric material pieces, respective processes and thermoelectric modules which are suitable for fitting in the exhaust system of an internal combustion engine.
Abstract translation: 本发明涉及使用热压接合（TCB）将导电触头接合到热电材料片，各自的工艺和热电模块，这些热工模块和热电模块适于装配在内燃机的排气系统中。
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公开(公告)号：WO2016096509A1
公开(公告)日：2016-06-23
申请号：PCT/EP2015/078848
申请日：2015-12-07
Applicant: BASF SE
Inventor： SCHARF, Florian , SCHWIND, Markus , VAN ASTEN, David , JACOBS, Steven Alan
IPC: H01F1/01
Abstract: The invention relates to a magnetocaloric cascade containing a sequence of magnetocaloric material layers having different Curie temperatures T c , wherein - the magnetocaloric material layers include a cold-side outer layer, a hot-side outer layer and at least three inner layers between the cold-side outer layer and the hot-side outer layer, and each pair of next neighboring magnetocaloric layers of the magnetocaloric cascade has a respective Curie-temperature difference amount ΔΤ c between their respective Curie temperatures, wherein - the hot-side outer layer or the cold-side outer layer or both the hot-side and cold-side outer layer exhibits a larger ratio mΔS max /ΔΤ c in comparison with any of the inner layers, m denoting the mass of the respective magnetocaloric material layer and ΔS max denoting a maximum amount of isothermal magnetic entropy change achievable in a magnetic phase transition of the respective magnetocaloric material layer.
Abstract translation: 本发明涉及包含具有不同居里温度Tc的磁热材料层序列的磁热级联，其中 - 磁热材料层包括冷侧外层，热侧外层和冷侧外层之间的至少三层内层， 侧面外层和热侧外层，并且磁热级联的每对下一相邻磁热层在各自的居里温度之间具有相应的居里温度差ΔTc，其中 - 热侧外层或冷侧外层 与侧壁外层或热侧外侧层和冷侧外层两者相比，与任何内层相比，表示较大的mΔSmax/Δtc比，m表示各磁热材料层的质量，表示最大量的等温磁性的ΔSmax 在相应的磁热材料层的磁相变中可实现的熵变化。
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公开(公告)号：WO2015158768A1
公开(公告)日：2015-10-22
申请号：PCT/EP2015/058158
申请日：2015-04-15
Applicant: BASF SE
Inventor： CHARRAK, Monika , THOMAS, Hans-Josef , YU, Miran , SCHWIND, Markus
CPC classification number: C08K9/08 , C08G59/245 , C08G59/3218 , C08G59/5026 , C08G59/686 , C08J3/24 , C08J5/00 , C08J2363/00 , C08K3/08 , C08K3/32 , C08K3/34 , C08K5/315 , C08L63/00 , F25B21/00 , F25B2321/002 , H01F1/012
Abstract: A shaped body comprising at least one solid material and a cured epoxy resin wherein the cured epoxy resin is prepared from an epoxy resin composition containing at least one epoxy resin having at least one epoxy group per molecule; at least one curing agent selected from cyanoalkylated polyamines of formula (A) A(NH-X-CN) n , wherein A is a group selected from aryl, arylalkyl, alkyl, and cycloalkyl, wherein A does not contain a primary amino group, X is alkylene having 1 to 10 C-atoms, and n ≥ 2; and at least one accelerator selected from tertiary amines, imidazoles, guanidines, urea compounds, and Lewis acids.
Abstract translation: 一种成形体，其包含至少一种固体材料和固化的环氧树脂，其中固化的环氧树脂由每分子含有至少一个具有至少一个环氧基的环氧树脂的环氧树脂组合物制备; 至少一种选自式（A）A（NH-X-CN）n的氰烷基化多胺的固化剂，其中A是选自芳基，芳烷基，烷基和环烷基的基团，其中A不含伯氨基， X是具有1〜10个碳原子的亚烷基，n≥2; 和选自叔胺，咪唑，胍，脲化合物和路易斯酸中的至少一种促进剂。
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公开(公告)号：WO2017162768A1
公开(公告)日：2017-09-28
申请号：PCT/EP2017/056869
申请日：2017-03-22
Applicant: BASF SE
Inventor： SCHARF, Florian , BÖHLING, Ralf , SCHWIND, Markus
IPC: F25B21/00
CPC classification number: F25B21/00 , F25B2321/0022 , Y02B30/66
Abstract: The invention relates to a magnetocaloric device, comprising a field generator, arranged to provide a changing external magnetic field and a magnetocaloric regenerator arrangement. The magnetocaloric regenerator arrangement comprises a magnetocaloric element, wherein the magnetocaloric element comprises magnetocaloric material, and wherein the magnetocaloric regenerator arrangement is arranged to be exposed to the changing external magnetic field of the field generator. Furthermore, the invention is characterized in that the magnetocaloric device further comprises an insulating means wherein the insulating means is arranged such that the magnetocaloric regenerator arrangement is hermetically surrounded by the insulating means.
Abstract translation: 本发明涉及一种磁热装置，其包括场发生器，该场发生器被设置成提供变化的外部磁场和磁热回热器装置。 磁热回热器装置包括磁热元件，其中磁热元件包括磁热材料，并且其中磁热回热器装置布置成暴露于场发生器的变化的外部磁场。 此外，本发明的特征在于，所述磁热装置还包括绝缘装置，其中所述绝缘装置被布置成使得所述磁热回收装置被所述绝缘装置气密地包围。
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Patent Agency Ranking6.发明申请CORROSION INHIBITORS FOR FE2P STRUCTURE MAGNETOCALORIC MATERIALS IN WATER 审中-公开用于FE2P结构的水泥腐蚀材料的腐蚀抑制剂
公开(公告)号：WO2015044263A1
公开(公告)日：2015-04-02
申请号：PCT/EP2014/070479
申请日：2014-09-25
Applicant: BASF SE
Inventor： SCHIERLE-ARNDT, Kerstin , SEELER, Fabian , SCHWIND, Markus , FRANCOIS, Jerome
CPC classification number: H01F1/442 , C23F11/08 , C23F11/149 , C23F11/1676 , C23F11/187 , C23F11/188 , F25B21/00 , F25B2321/002 , H01F1/015 , Y02B30/66
Abstract: Use of a composition (A) having a pH of at least 8 at 25°C containing at least 50 wt.-%xof water or a water containing solvent mixture, at least 0.1 mol/m3 of at least one waterxsoluble silicate, optionally at least one molybdate, optionally at least one phosphonate, optionally at least one azole, optionally at least one additional freezing point depressing salt, optionally at least one phosphate, and optionally at least one nitrate, as heat carrier medium for magnetocaloric materials of formula (I) (A y B 1-y ) 2+u C w D x E z (I) where: A is Mn or Co, B is Fe, Cr or Ni, C is Ge, As or Si, D is different from C and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, E may be same or different from C and D and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb.
Abstract translation: 使用在25℃下pH至少为8的组合物（A），其含有至少50重量％的水或含水溶剂混合物，至少0.1摩尔/立方米的至少一种水溶性硅酸盐，任选地 至少一种钼酸盐，任选的至少一种膦酸盐，任选的至少一种唑，任选至少一种另外的冰点抑制盐，任选的至少一种磷酸盐和任选的至少一种硝酸盐作为式（I ）（AyB1-y）2 + uCwDxEz（I）其中：A为Mn或Co，B为Fe，Cr或Ni，C为Ge，As或Si，D与C不同，选自P，B，Se Ge，Ga，Si，Sn，N，As和Sb中的一个或多个，E可以相同或不同，选自P，B，Se，Ge，Ga，Si，Sn，N，As和Sb。
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7.发明申请
公开(公告)号：WO2017005555A1
公开(公告)日：2017-01-12
申请号：PCT/EP2016/065052
申请日：2016-06-28
Applicant: BASF SE
Inventor： CARROLL, Colman-Patrick , BENDER, Dietmar , SCHWIND, Markus
CPC classification number: B22F3/03 , B30B15/30 , B32B37/24 , B32B2307/208 , F25B2321/0021 , H01F1/01 , H01F41/02
Abstract: The invention relates to a production station for use in producing at least one layered bed, in particular a plurality of layered beds, of a magneto caloric material, the station comprising a frame work and further for arrangement at the frame work the station comprising: - a material receptacle for receiving a particulate magnetocaloric material, - a dosing plate, having at least one intake opening adapted to receive a magneto-caloric material of one layer of the layered bed - at least one reservoir below the at least one intake opening, wherein the reservoir is adapted to receive the one or more layers of the particulate magnetocaloric material, wherein the production station further comprises: - a shutter plate arranged between the reservoir and the dosing plate, wherein the shutter plate is switchable through motion with respect to the dosing plate and wherein the shutterplate is arranged and adapted to at least activate a filling modus, wherein in the filling modus the at least one reservoir is filled with particulate magneto caloric material of the one layer of the layered bed by a switching control of the shutter plate.
Abstract translation: 本发明涉及一种用于生产磁热量材料的至少一层分层床，特别是多层分层床的生产站，该工位包括框架工作，并进一步用于框架工作，该工位包括： - 用于接收颗粒状磁热材料的材料容器， - 配量板，具有至少一个进气口，其适于接纳一层层状床的磁热量材料 - 至少一个在至少一个进气口下方的储存器，其中 所述储存器适于接收所述一个或多个所述颗粒状磁热材料层，其中所述生产站还包括： - 布置在所述储存器和所述计量板之间的挡板，其中所述挡板可相对于所述计量 板，并且其中所述快门板被布置并适于至少激活填充模式，其中在所述填充模式中至少一个 e储层通过快门板的切换控制填充层状床的一层的颗粒状磁热量材料。
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公开(公告)号：EP3049552B1
公开(公告)日：2018-11-14
申请号：EP14777051.5
申请日：2014-09-25
Applicant: BASF SE
Inventor： SCHIERLE-ARNDT, Kerstin , SEELER, Fabian , SCHWIND, Markus , FRANCOIS, Jerome
CPC classification number: H01F1/442 , C23F11/08 , C23F11/149 , C23F11/1676 , C23F11/187 , C23F11/188 , F25B21/00 , F25B2321/002 , H01F1/015 , Y02B30/66
Abstract: Use of a composition (A) having a pH of at least 8 at 25° C. containing at least 50 wt.-% of water or a water containing solvent mixture, at least 0.1 mol/m3 of at least one water soluble silicate, optionally at least one molybdate, optionally at least one phosphonate, optionally at least one azole, optionally at least one additional freezing point depressing salt, optionally at least one phosphate, and optionally at least one nitrate, as heat carrier medium for magnetocaloric materials of formula (I) (AyB1−y)2+uCwDxEz (I) where: A is Mn or Co, B is Fe, Cr or Ni, C is Ge, As or Si, D is different from C and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, E may be same or different from C and D and is selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb.
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公开(公告)号：EP3131959A1
公开(公告)日：2017-02-22
申请号：EP15716788.3
申请日：2015-04-15
Applicant: BASF SE
Inventor： CHARRAK, Monika , THOMAS, Hans-Josef , YU, Miran , SCHWIND, Markus
CPC classification number: C08K9/08 , C08G59/245 , C08G59/3218 , C08G59/5026 , C08G59/686 , C08J3/24 , C08J5/00 , C08J2363/00 , C08K3/08 , C08K3/32 , C08K3/34 , C08K5/315 , C08L63/00 , F25B21/00 , F25B2321/002 , H01F1/012
Abstract: A shaped body comprising at least one solid material and a cured epoxy resin wherein the cured epoxy resin is prepared from an epoxy resin composition containing at least one epoxy resin having at least one epoxy group per molecule; at least one curing agent selected from cyanoalkylated polyamines of formula (A) A(NH—X—CN), wherein A is a group selected from aryl, arylalkyl, alkyl, and cycloalkyl, wherein A does not contain a primary amino group, X is alkylene having 1 to 10 C-atoms, and n≧2; and at least one accelerator selected from tertiary amines, imidazoles, guanidines, urea compounds, and Lewis acids.
Abstract translation: 一种成形体，其包含至少一种固体材料和固化的环氧树脂，其中固化的环氧树脂由含有至少一种每分子具有至少一个环氧基团的环氧树脂的环氧树脂组合物制备; 至少一种选自式（A）A（NH-X-CN）n的氰烷基化聚胺的固化剂，其中A是选自芳基，芳烷基，烷基和环烷基的基团，其中A不含伯氨基， X是具有1至10个C原子的亚烷基，且n≥2; 和至少一种选自叔胺，咪唑，胍，脲化合物和路易斯酸的促进剂。
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公开(公告)号：EP3433548A1
公开(公告)日：2019-01-30
申请号：EP17712981.4
申请日：2017-03-22
Applicant: BASF SE
Inventor： SCHARF, Florian , BÖHLING, Ralf , SCHWIND, Markus
IPC: F25B21/00
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