PYRIDINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS III
    1.
    发明申请
    PYRIDINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS III 审中-公开
    用于控制无节幼虫的吡啶化合物III

    公开(公告)号:WO2012034959A3

    公开(公告)日:2012-08-16

    申请号:PCT/EP2011065708

    申请日:2011-09-12

    CPC classification number: A01N43/40 A01N43/54 A01N43/58 A01N43/60 A01N25/00

    Abstract: The present invention relates to a method for controlling invertebrate pests, in particular arthropod pests and nematodes, by using pyridine compounds of formulae (I) or (II) and the salts thereof, the tautomers thereof, the N-oxides thereof and the salts of the tautomers or N-oxides thereof, where the radical A is of the formula (A), wherein # denotes the point of attachment to the remainder of formulae (I) or (II), and wherein A1 is N or C-RA1, A2 is N or C-RA2, A3 is N or C-RA3, A4 is N or C-RA4 and A5 is N or C-RA5, provided that one or two of the variables A1, A2, A3, A4 or A5 is N; RA1, RA5, if present, are H, halogen, CN, NO2, C1-C6-alkyl, C1-C6-haloalkyl and the like; RA2, RA4, if present, are H, halogen, CN, NO2, C1-C10-alkyl, C1-C10-haloalkyl and the like; RA3, if present, is H, halogen, CN, NO2, C1-C10-alkyl, C1-C10-haloalkyl and the like; R1 is H, CN, C1-C10- alkyl, C1-C10-haloalkyl and the like; R2 is H, halogen, methyl, C1-haloalkyl and the like; R3 is H, halogen, C1-C4-alkyl, C1-C3-haloalkyl and the like; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl and the like; X2 is OR2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2, R2a is C1-C4-alkyl, C1-C4-haloalkyl and the like, R2b and R2c are H, C1-C4-alkyl, C1-C4- haloalkyl and the like, or R2b and R2c together with the nitrogen atom to which they are bound form a heterocycle, and R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl and the like. The present invention further relates to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound of formulae (I) or (II), their salts or N-oxides, and to an agricultural composition containing at least one compound of formulae (I) or (II), their salts or N-oxides.

    Abstract translation: 本发明涉及通过使用式(I)或(II)的吡啶化合物及其盐,其互变异构体,其N-氧化物和以下物质的盐来控制无脊椎害虫,特别是节肢动物害虫和线虫的方法: 其中基团A具有式(A)的互变异构体或N-氧化物,其中#表示与式(I)或(II)的其余部分的连接点,并且其中A1是N或C-RA1, 条件是变量A1,A2,A3,A4或A5中的一个或两个是N或C-RA2,A3是N或C-RA3,A4是N或C-RA4并且A5是N或C-RA5。 N; RA1,RA5(如果存在)为H,卤素,CN,NO2,C1-C6-烷基,C1-C6-卤代烷基等; 如果存在,RA 2,RA 4是H,卤素,CN,NO 2,C 1 -C 10烷基,C 1 -C 10卤代烷基等; 如果存在,RA3为H,卤素,CN,NO2,C1-C10-烷基,C1-C10-卤代烷基等; R 1是H,CN,C 1 -C 10烷基,C 1 -C 10卤代烷基等; R2是H,卤素,甲基,C1-卤代烷基等; R3是H,卤素,C1-C4-烷基,C1-C3-卤代烷基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X2是OR2a,NR2bR2c或S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4-卤代烷基等,R2b和R2c是H,C1-C4-烷基, C1-C4-卤代烷基等,或者R2b和R2c与它们所连接的氮原子一起形成杂环,R2d为C1-C4-烷基,C1-C4-卤代烷基,C3-C6-环烷基等 。 本发明进一步涉及保护植物繁殖材料和/或从其生长的植物到植物繁殖材料的方法,所述植物繁殖材料包含至少一种式(I)或(II)的化合物,其盐或N-氧化物,和 涉及含有至少一种式(I)或(II)化合物,其盐或N-氧化物的农业组合物。

    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    2.
    发明申请
    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS 审中-公开
    用于控制反相胶束的吡咯化合物

    公开(公告)号:WO2010034738A3

    公开(公告)日:2010-10-07

    申请号:PCT/EP2009062318

    申请日:2009-09-23

    CPC classification number: A01N43/90 C07D471/04 C07D487/04 C07D498/04

    Abstract: The present invention relates to a method for controlling invertebrate pests which method comprises treating the pests, their food supply, their habitat or their breeding ground or a plant, seed, soil, area, material or environment in which the pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from pest attack or infestation with a pesticidally effective amount of a pyrazole compound of formulae I or II or a salt or an N-oxide thereof, wherein A is a pyrazole radical of the formulae A1 or A2, wherein # denotes the binding; D is a 5- or 6-membered heterocyclic radical fused to the pyrazole moiety; Rp1, Rp2 and Rpx are H, halogen, CN, NO2, C1-C10-alkyl, C2-C10- alkenyl, C2-C10-alkynyl, etc.; n is 0 to 4; or two radicals Rpx bound to the same ring- member may form an oxo substituent, or two radicals Rpx bound to adjacent ring- members may form a 3- to 7-membered fused cyclic radical; B is N or CR4, wherein R4 is H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl, etc.; X2 is O2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2; R2a is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R1 is H, CN, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, etc.; R2, R3 and R5 are H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound of formulae I or II, to a method for treating or protecting an animal from infestation or infection by parasites, to novel pyrazole compounds of formulae I or Il and agricultural composition containing those compounds.

    Abstract translation: 本发明涉及一种控制无脊椎害虫的方法,该方法包括处理害虫,其食物供应,栖息地或其繁殖地,或害虫生长或可能生长的植物,种子,土壤,面积,物质或环境 ,或用农药有效量的式I或II的吡唑化合物或其盐或N-氧化物防止害虫侵袭或侵染的材料,植物,种子,土壤,表面或空间,其中A为 式A1或A2的吡唑基,其中#表示结合; D是与吡唑部分稠合的5或6元杂环基; Rp1,Rp2和Rpx是H,卤素,CN,NO2,C1-C10-烷基,C2-C10-烯基,C2-C10-炔基等; n为0〜4; 或者与相同环成员结合的两个基团R px可以形成氧代取代基,或者与相邻环 - 成员键合的两个基团R px可以形成3-至7-元稠合的环状基团; B是N或CR 4,其中R 4是H,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X 2是O 2 a,NR 2 b R 2c或S(O)m R 2d,其中m是0,1或2; R 2a是C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R2b,R2c为H,C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R1是H,CN,C1-C10-烷基,C1-C10-卤代烷基,C3-C10-环烷基等; R2,R3和R5是H,卤素,CN,NO2,C1-C4-烷基,C1-C4-卤代烷基,C1-C4-烷氧基等; 涉及一种用于保护植物繁殖材料和/或从其生长的植物的方法,将包含至少一种式I或II化合物的植物繁殖材料用于治疗或保护动物免受寄生虫感染或感染的方法,用于新颖的 式I或II的吡唑化合物和含有这些化合物的农业组合物。

    PESTICIDAL MIXTURE COMPRISING A PYRAZOLE COMPOUND, AN INSECTICIDE AND A FUNGICIDE
    3.
    发明申请
    PESTICIDAL MIXTURE COMPRISING A PYRAZOLE COMPOUND, AN INSECTICIDE AND A FUNGICIDE 审中-公开
    包含吡唑化合物,杀虫剂和杀真菌剂的杀菌混合物

    公开(公告)号:WO2016128261A3

    公开(公告)日:2016-10-27

    申请号:PCT/EP2016052218

    申请日:2016-02-03

    Applicant: BASF SE

    Abstract: The present invention relates to the use of a pesticidal mixture PM comprising at least one compound of formula I as defined in the specification, an insecticide II and a fungicide III for protecting plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato, the plant propagation material thereof, or soil or water, in which the plants are growing, against the attack or infestation by invertebrate pests and/or phytopathogenic harmful fungi. Furthermore, the present invention relates to a seed treatment composition comprising the pesticidal mixture PM and to seeds comprising the pesticidal mixture PM or the seed treatment composition thereof. Moreover, the present invention relates to a method for controlling invertebrate pests and/or phytopathogenic harmful fungi on plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato comprising contacting the plant or the plant propagation material; the pest or its food supply, habitat or breeding ground; and/or the fungi or their habitat, with an effective amount of the pesticidal mixture PM or the seed treatment composition thereof. In a further aspect, the present invention relates to binary mixtures of a compound of formula I and tioxazafen, tetraniliprole, broflanilide, cyhalodiamide, fluazaindolizine, and fluxametamide, resp.

    Abstract translation: 本发明涉及包含至少一种本说明书中定义的式I化合物的杀虫混合物PM的用途,杀虫剂II和杀真菌剂III用于保护选自小麦,玉米,大麦,燕麦,黑麦,稻米, 大豆,棉花,甜菜,油菜籽和马铃薯,植物繁殖材料,植物生长的土壤或水,抵抗无脊椎动物害虫和/或植物病原性有害真菌的侵袭或侵袭。 此外,本发明涉及包含杀虫混合物PM和包含杀虫混合物PM或其种子处理组合物的种子的种子处理组合物。 此外,本发明涉及一种在选自小麦,玉米,大麦,燕麦,黑麦,稻,大豆,棉花,甜菜,油菜籽和马铃薯的植物中控制无脊椎害虫和/或植物病原性有害真菌的方法,包括使植物或 植物繁殖材料; 害虫或其食物供应,栖息地或繁殖地; 和/或真菌或其栖息地,有效量的杀虫混合物PM或其种子处理组合物。 在另一方面,本发明涉及式I化合物和噻唑烷酮,四硝基吡咯,broflanilide,cyhalodiamide,fluazaindolizine和fluxametamide的二元混合物,

    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    4.
    发明申请
    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS 审中-公开
    用于控制反相胶束的吡咯化合物

    公开(公告)号:WO2012076704A3

    公开(公告)日:2012-08-02

    申请号:PCT/EP2011072363

    申请日:2011-12-09

    Abstract: The present invention relates to a method for controlling invertebrate pests, in particular arthropod pests and nematodes, by using pyrazole compounds of formula (I) and the salts thereof, the tautomers thereof, the N-oxides thereof and the salts of the tautomers or N-oxides thereof, (I) wherein X is N or CH, Y is N or CH, Z is N or CH, provided that either only one of X, Y and Z is N or only two adjacent groups of X, Y and Z are N; and wherein Q is a bivalent 5- or 6-membered carbocyclic radical or a 5- or 6-membered heterocyclic radical having one heteroatom moiety which is selected from the group consisting of O, S, N or N-RQN as ring member and 0, 1 or 2 further heteroatom moieties N as ring members, wherein 0, 1, 2 or 3 of the ring members that are carbon atoms may carry a radical RQ, provided that the pyrazole radical and the 6-membered heteroaromatic radical are bound in ortho- or meta-position of Q with respect to each other, if Q is a 6-membered radical; and wherein RA, if present, is C1-C3-alkyl, C1-C3-haloalkyl or the like; n is 0, 1 or 2; RN is C1-C3-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy-C1-C2-alkyl or the like; Rt and Ru are independently of each other selected from hydrogen, methyl and the like; RQN is hydrogen, C1-C4-alkyl or the like; RQ is hydrogen, halogen, C1-C4-alkyl or the like. The present invention further relates to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound of formula (I), their salts or N-oxides, and to pyrazole compounds of formula (I).

    Abstract translation: 本发明涉及通过使用式(I)的吡唑化合物及其盐,其互变异构体,其N-氧化物和互变异构体或N的盐来控制无脊椎害虫,特别是节肢动物害虫和线虫的方法 (I)其中X是N或CH,Y是N或CH,Z是N或CH,条件是X,Y和Z中只有一个是N或只有X,Y和Z的两个相邻基团 是N; 并且其中Q是二价5-或6-元碳环基团或具有一个杂原子部分的5-或6-元杂环基团,其选自O,S,N或N-RQN作为环成员,0 ,1个或2个另外的杂原子部分N作为环成员,其中作为碳原子的环成员的0,1,2或3可以携带自由基RQ,条件是吡唑基和6元杂芳族基团以邻位 - 或相对于Q的间位,如果Q是6元基团; 并且其中RA如果存在,是C 1 -C 3 - 烷基,C 1 -C 3 - 卤代烷基等; n为0,1或2; RN是C 1 -C 3烷基,C 1 -C 2卤代烷基,C 1 -C 2烷氧基-C 1 -C 2烷基等; Rt和Ru彼此独立地选自氢,甲基等; RQN是氢,C1-C4烷基等; RQ是氢,卤素,C1-C4烷基等。 本发明还涉及一种用于保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种式(I)化合物,其盐或N-氧化物的植物繁殖材料,以及吡唑化合物 式(I)。

    PYRIDINE DERIVATIVES FOR CONTROLLING INVERTEBRATE PESTS
    6.
    发明申请
    PYRIDINE DERIVATIVES FOR CONTROLLING INVERTEBRATE PESTS 审中-公开
    用于控制反相胶束的吡啶衍生物

    公开(公告)号:WO2011009804A3

    公开(公告)日:2011-06-03

    申请号:PCT/EP2010060243

    申请日:2010-07-15

    Abstract: The present invention relates to methods and uses of compounds of formulae (I) or (II) and the salts and N-oxides thereof, wherein A is a substituted or unsubstituted 5-membered heterocyclic radical; X1 is S, O or NR1a, wherein R1a is selected from H, C1-C10-alkyl and the like; X2 is OR2a, NR2bR2c, S(O)mR2d;; X2 is OR2a, NR2bR2c, S(O)mR2d, wherein m is 0, 1 or 2, R2a is C1-C4- alkyl, C1-C4-haloalkyl and the like, R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl and the like; X3 is a lone pair or oxygen; R1, R2 and R3 are, inter alia, hydrogen, and R1 is H, C1- C10-alkyl and the like. The present invention further relates to a method for controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites and to an agricultural composition containing at least one compound according to the present invention.

    Abstract translation: 本发明涉及式(I)或(II)化合物及其盐和N-氧化物的方法和用途,其中A是取代或未取代的5元杂环基; X1是S,O或NR1a,其中R1a选自H,C1-C10-烷基等; X2是OR2a,NR2bR2c,S(O)mR2d ;; X2是OR2a,NR2bR2c,S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4卤代烷基等,R2b,R2c是H,C1-C4-烷基, C1-C4卤代烷基等; X3是孤对或氧气; R1,R2和R3尤其是氢,R1是H,C1-10烷基等。 本发明还涉及一种控制无脊椎害虫的方法,一种用于保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种根据本发明的化合物的植物繁殖材料的方法, 治疗或保护动物不受寄生虫侵袭或感染,以及含有至少一种本发明化合物的农药组合物。

    КРИСТАЛІЧНА ФОРМА В 1-(1,2-ДИМЕТИЛПРОПІЛ)-N-ЕТИЛ-5-МЕТИЛ-N-ПІРИДАЗИН-4-ІЛ-ПІРАЗОЛ-4-КАРБОКСАМІДУ

    公开(公告)号:UA129323C2

    公开(公告)日:2025-03-19

    申请号:UAA202104305

    申请日:2020-01-10

    Applicant: BASF SE

    Abstract: Данийвинахідналежитьдоновоїкристалічноїформи 1-(1,2-диметилпропіл)-N-етил-5-метил-N-піридазин-4-іл-піразол-4-карбоксаміду, якомунещодавнонаданозагальнуназвудимпропіридаз. Винахідтакожналежитьдозастосуваннякристалічноїформи B дляборотьбиз безхребетнимишкідникамиі доскладівдлязахистурослин, якімістятькристалічнуформу B 1-(1,2-диметилпропіл)-N-етил-5-метил-N-піридазин-4-іл-піразол-4-карбоксаміду. Кристалічнаформа B відповіднододаноговинаходуможебутиідентифікованазадопомогоюпорошковоїрентгенівськоїдифрактометріїнаосновіїїдіаграмипорошковоїрентгенівськоїдифракції, надалітакожназиваютьпорошковоїрентгенівськоїдифракційноюкартиноюабоПРДкартиною, поліморфноїформи B, записаноїз використаннямвипромінення Cu-Kα (1.54178 Å) при 25 (C відображує 3 наступнихвідбиття, зазначенихякзначення 2θ: 20,69,0,101, 24,15,0,101 і 30,52 0,101. Надодатокдоцихтрьохвідбиттівполіморф B відповіднододаноговинаходуможевідбиватив такійПРДкартиніоднеабодекілька, зокрема, щонайменше 2, частощонайменше 4, зокрема, щонайменше 6 абощонайменше 8 відбиттіві особливовсіз відбиттів, зазначенихнижчеякзначення 2θ: 7,99,0,101, 10,07,0,101, 12,38,0,101, 15,31,0,101, 15,97,0,101, 16,50,0,101, 18,03,0,101, 19,29,0,101, 20,22,0,101, 20,96,0,101, 23,40,0,101, 23,70,0,101, 26,09,0,101, 27,26,0,101 і 32,91 0,101.

    Crystalline forms of 1-(1,2-dimethylpropyl)-N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide

    公开(公告)号:AU2020206519A1

    公开(公告)日:2021-07-15

    申请号:AU2020206519

    申请日:2020-01-10

    Applicant: BASF SE

    Abstract: The present invention relates to a novel crystalline form of 1-(1,2-dimethylpropyl)- N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide recently assigned the common name dimpropyridaz. The invention also relates to the use of the crystalline form B for combating invertebrate pests and to formulations for plant protection which contain the crystalline form B of 1-(1,2-dimethylpropyl)-N-ethyl-5-methyl-N-pyridazin-4- yl-pyrazole-4-carboxamide. The crystalline form B according to the present invention can be identified by powder X-ray diffractometry on the basis of its powder X-ray diffraction diagram, hereinafter also termed powder X-ray diffraction pattern or PXRD pattern,of the polymorph form B recorded using Cu-Kα radiation (1.54178 Å) at 25°C displays the 3 following reflections, quoted as 2θ values: 20.69±0.10°, 24.15±0.10°and 30.52± 0.10°.In addition to these 3 reflections, the polymorph B of the present invention may display in such a PXRD pattern one or more, in particular at least 2, often at least 4, in particular at least 6 or at least 8 reflections and especially all of the reflections quoted hereinafter as 2θ values:7.99±0.10°, 10.07±0.10°, 12.38±0.10°,15.31±0.10°, 15.97±0.10°, 16.50±0.10°, 18.03±0.10°,19.29±0.10°, 20.22±.0.10°, 20.96± 0.10°, 23.40±0.10°, 23.70±0.10°,26.09±0.10°, 27.26±0.10°and 32.91±0.10°.

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