公开(公告)号：WO2010043624A3

公开(公告)日：2010-12-09

申请号：PCT/EP2009063358

申请日：2009-10-13

Applicant: BASF SE ,  GEHRINGER LIONEL ,  KAMPF GUNNAR ,  TISCHER GERLINDE

Inventor： GEHRINGER LIONEL ,  KAMPF GUNNAR ,  TISCHER GERLINDE

IPC: C08G18/42 ,  C08G18/40 ,  C08G63/48 ,  C08J9/00

CPC classification number: C08G18/4219 ,  C08G18/4018 ,  C08G18/4288 ,  C08G63/127 ,  C08G63/48 ,  C08G2101/0025

Abstract: Polyester polyol containing the esterification product of a) 10 to 70 mol-% of a dicarboxylic acid composition containing a1) from 50 to 100 mol-% of a terephthalic acid-based material selected from terephthalic acid, dimethyl terephthalate and polyalkylene terephthalate and mixtures thereof, a2) 0 to 50 mol-% of phthalic acid, phthalic acid anhydride or isophthalic acid, a3) 0 to 50 mol-% of one or more dicarboxylic acids, b) 2 to 30 mol-% of one or more fatty acids and/or fatty acid derivatives and/or benzoic acid, c) 10 to 70 mol-% of one or more aliphatic or cycloaliphatic diols with 2 to 18 C atoms or alkoxylates thereof, d) 2 to 50 mol-% of a highly functional polyol selected from the group consisting of glycerin, alkoxylated glycerin, trimethylol propane, alkoxylated trimethylol propane, pentaerythritol and alkoxylated pentaerythritol, wherein at least 200 mmol, preferably at least 500 mmol and especially preferred at least 800 mmol of polyols d) with an OH functionality of = 2.9 are converted per kg of polyester polyol.

Abstract translation: 聚酯多元醇，其包括的酯化产物）10〜70摩尔％，其包括A1从50〜100摩尔％的材料的基于来自对苯二甲酸，对苯二甲酸二甲酯，和聚亚烷基对苯二甲酸酯以及它们的混合物，A2）0〜50摩尔选定对苯二甲酸的二羧酸成分）的 - 邻苯二甲酸，邻苯二甲酸酐，或间苯二甲酸，a3）的0〜50摩尔％的一种或多种二羧酸，b）2〜30摩尔％的一种或多种脂肪酸和/或脂肪酸衍生物和/或苯甲酸的％c）10至70摩尔 的一种或多种脂族或碳原子数为2至18或烷氧基化物或其脂环族二醇，D）2〜50摩尔％选自甘油的组中的官能高级多元醇，烷氧基化甘油，三羟甲基丙烷，烷氧基化三羟甲基丙烷，季戊四醇和烷氧基化的％ 季戊四醇，其特征在于，每千克聚酯多元醇至少为200毫摩尔，优选至少500毫摩尔，特别青睐 至少800上的多元醇ð毫摩尔GT）与的= 2.9Hz羟基官能反应。

公开(公告)号：WO2010072572A2

公开(公告)日：2010-07-01

申请号：PCT/EP2009066783

申请日：2009-12-10

Applicant: BASF SE ,  RENNER CHRISTIAN ,  TISCHER GERLINDE ,  ILLGUTH ROLF ,  GEHRING MARGIT ,  REDL FRANZ XAVER

Inventor： RENNER CHRISTIAN ,  TISCHER GERLINDE ,  ILLGUTH ROLF ,  GEHRING MARGIT ,  REDL FRANZ XAVER

IPC: C08J7/04 ,  C09D7/46 ,  C08J7/16 ,  C08J9/34

CPC classification number: B32B27/40 ,  B32B5/18 ,  B32B7/12 ,  B32B27/065 ,  B32B27/08 ,  B32B27/18 ,  B32B37/14 ,  B32B2266/0278 ,  B32B2307/206 ,  B32B2307/7265 ,  B32B2307/734 ,  B32B2419/00 ,  B32B2605/08 ,  B32B2605/18 ,  C08G18/4018 ,  C08G18/4216 ,  C08G2101/0058 ,  C08G2101/0083 ,  Y10T428/249953

Abstract: The present invention relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, which can be prepared by polycondensation of an acid component and of one or more low-molecular-weight diols whose molecular weight is less than 500 g/mol, in excess, where the acid component comprises 83 to 97 mol% of adipic acid and 3 to 17 mol% of phthalic acid, isophthalic acid and/or terephthalic acid. The present invention further relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, preparable by polycondensation of an acid component and one or more low-molecular-weight diols having a molecular weight of less than 500 g/mol, in excess, the low-molecular-weight diols containing 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol. The present invention also relates to a process for the production of these composite elements, and to components in the fitting-out of aircraft, of vehicles, or of buildings, and to insulation systems comprising this type of composite element.

Abstract translation: 本发明涉及包含（i）塑料的复合元件，粘附的（ⅱ）多异氰酸酯Polyadditionsproduktanschließt，其中，通过将（a）异氰酸酯与（b）中的化合物具有异氰酸酯反应性基团得到的多异氰酸酯加聚产物 （c）中的催化剂，（d）任选地，发泡剂和（e）任选的其它添加剂，以形成反应混合物，并进行反应使反应混合物到多异氰酸酯加聚产物，其特征在于，含异氰酸酯 - 反应性基团的化合物（b）含有聚酯多元醇作为其可以通过缩聚来制备粘合剂 的酸组分和具有小于500g / mol的过量，其中所述酸组分包含83-97％（摩尔）己二酸和邻苯二甲酸，间苯二甲酸和/或对苯二甲酸的3〜17摩尔％的分子量的一种或多种低分子量二醇。 此外，本发明的复合元件包括：（i）塑料，粘附的（ⅱ）多异氰酸酯加聚产物其中所获得的多异氰酸酯加聚产物而言，通过混合（A）异氰酸酯与（B）的化合物具有异氰酸酯反应性基团 ，（C）的催化剂，（d）任选地，发泡剂和（e）任选的其他添加剂，以形成反应混合物，并允许反应在反应混合物的聚异氰酸酯加聚产物，其特征在于，含异氰酸酯 - 反应性基团的化合物（b）含有聚酯多元醇作为可制备的粘接剂 酸组分和具有小于500克/ molim过量，的分子量的一种或多种低分子量二醇的缩聚，其中含有5至66摩尔％的1,3-丙二醇的，基于二醇的总量中的低分子量二醇。 另外，本发明提供了用于制备这样的复合元件，并且组件飞机，车辆或不动产膨胀的方法，将含有绝缘涉及这样的复合元件。

公开(公告)号：CA2936765C

公开(公告)日：2018-09-25

申请号：CA2936765

申请日：2009-12-10

Applicant: BASF SE

Inventor： RENNER CHRISTIAN ,  TISCHER GERLINDE ,  ILLGUTH ROLF ,  GEHRING MARGIT ,  REDL FRANZ XAVER

IPC: C08J7/04 ,  C09D7/46 ,  C08J7/16

Abstract: The present invention concerns a process for the production of composite elements comprising plastic, adhering to which there is a polyisocyanate polyaddition product, where isocyanate is mixed with compounds having groups reactive toward isocyanates, catalysts, if appropriate, blowing agent, and if appropriate, further additives to give a reaction mixture and the reaction mixture is permitted to complete its reaction to give the polyisocyanate polyaddition product, where the compounds having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, capable of production via polycondensation of an acid component and of one or more low-molecular-weight diols whose molar mass is less than 500 g/mol, in excess, where the low-molecular-weight diols comprise at least 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol.

公开(公告)号：HUE030631T2

公开(公告)日：2017-05-29

申请号：HUE14166682

申请日：2009-12-10

Applicant: BASF SE

Inventor： RENNER CHRISTIAN ,  TISCHER GERLINDE ,  ILLGUTH ROLF ,  GEHRING MARGIT ,  REDL FRANZ XAVER

IPC: C08J7/04 ,  C09D7/46 ,  C08J7/16 ,  C08J9/34

公开(公告)号：CA2746833C

公开(公告)日：2017-05-30

申请号：CA2746833

申请日：2009-12-10

Applicant: BASF SE

Inventor： RENNER CHRISTIAN ,  TISCHER GERLINDE ,  ILLGUTH ROLF ,  GEHRING MARGIT ,  REDL FRANZ XAVER

IPC: C08J7/04 ,  C09D7/46 ,  C08J7/16

Abstract: The present invention relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, which can be prepared by polycondensation of an acid component and of one or more low-molecular-weight diols whose molecular weight is less than 500 g/mol, in excess, where the acid component comprises 83 to 97 mol% of adipic acid and 3 to 17 mol% of phthalic acid, isophthalic acid and/or terephthalic acid. The present invention further relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, preparable by polycondensation of an acid component and one or more low-molecular-weight diols having a molecular weight of less than 500 g/mol, in excess, the low-molecular-weight diols containing 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol. The present invention also relates to a process for the production of these composite elements, and to components in the fitting-out of aircraft, of vehicles, or of buildings, and to insulation systems comprising this type of composite element.

公开(公告)号：ES2346271T3

公开(公告)日：2010-10-13

申请号：ES08156969

申请日：2008-05-27

Applicant: BASF SE

Inventor： KAMPF GUNNAR ,  TOMOVIC ZELJKO ,  TISCHER GERLINDE ,  WANG YAYUN

IPC: C08G18/42 ,  C08G18/36

Abstract: Procedimiento para la obtención de espumas duras de poliuretano mediante reacción de a) poliisocianatos con b) compuestos con al menos dos átomos de hidrógeno reactivos con grupos isocianato en presencia de c) agentes propulsores, caracterizado porque el componente b) presenta al menos un alcohol de poliéster bi) con una funcionalidad de 1,5 a 4,5 y un índice de hidroxilo en el intervalo entre 200 y 800 mg KOH/g, para cuya obtención se empleó al menos un ácido carboxílico alifático, al menos difuncional, al menos un alcohol alifático, al menos difuncional, así como al menos un aceite vegetal, y/o al menos un ácido graso.

公开(公告)号：DE502008000788D1

公开(公告)日：2010-07-29

申请号：DE502008000788

申请日：2008-05-27

Applicant: BASF SE

Inventor： KAMPF GUNNAR ,  TOMOVIC ZELJKO ,  TISCHER GERLINDE ,  WANG YAYUN

IPC: C08G18/42 ,  C08G18/36

公开(公告)号：BRPI0920168A2

公开(公告)日：2015-12-29

申请号：BRPI0920168

申请日：2009-10-13

Applicant: BASF SE

Inventor： TISCHER GERLINDE ,  KAMPF GUNNAR ,  GEHRINGER LIONEL

IPC: C08G63/48 ,  C08G18/40 ,  C08G18/42 ,  C08J9/00

公开(公告)号：PL2340269T3

公开(公告)日：2013-02-28

申请号：PL09783986

申请日：2009-10-13

Applicant: BASF SE

Inventor： GEHRINGER LIONEL ,  KAMPF GUNNAR ,  TISCHER GERLINDE

IPC: C08G18/42 ,  C08G18/40 ,  C08G63/48 ,  C08J9/00

公开(公告)号：MX2011003903A

公开(公告)日：2011-04-28

申请号：MX2011003903

申请日：2009-10-13

Applicant: BASF SE

Inventor： TISCHER GERLINDE ,  GEHRINGER LIONEL ,  KAMPF GUNNAR

IPC: C08G18/42 ,  C08G18/40 ,  C08G63/48 ,  C08J9/00

Abstract: El poliol de poliéster que contiene el producto de esterificación de a) 10 a 70% mol de una composición de ácido dicarboxílico que contiene a1) desde 50 hasta 100% mol de un material basado en ácido tereftálico seleccionado de ácido tereftálico, dimetil tereftalato y polialquilentereftalato y mezclas de los mismos, a2) 0 a 50% mol de ácido ftálico, anhídrido del ácido ftálico o ácido isoftálico, a3) 0 a 50% mol de uno o más ácidos dicarboxílicos, b) 2 a 30% mol de uno o más ácidos grasos y/o derivados de ácidos grasos y/o ácido benzoico, c) 10 a 70% mol de uno o más dioles alifáticos o cicloalifáticos con 2 a 18 átomos de C o alcoxilatos de los mismos, d) 2 a 50% mol de un poliol altamente funcional seleccionado del grupo que consiste de glicerina, glicerina alcoxilada, trimetilol propano, trimetilol propano alcoxilado, pentaeritritol y pentaeritritol alcoxilado, en donde al menos 200 mmol, preferiblemente al menos 500 mmol y especialmente preferido al menos 800 mmol de los polioles d) con una funcionalidad de OH de = 2.9 se convierten por kg de poliol de poliéster.