ADHESION PROMOTER FOR ADHESIVE COMPOSITES COMPOSED OF PLASTIC AND OF A POLYISOCYANATE POLYADDITION PRODUCT
    1.
    发明申请
    ADHESION PROMOTER FOR ADHESIVE COMPOSITES COMPOSED OF PLASTIC AND OF A POLYISOCYANATE POLYADDITION PRODUCT 审中-公开
    粘结粘结性能的塑料复合材料聚异氰酸酯加聚

    公开(公告)号:WO2010072572A2

    公开(公告)日:2010-07-01

    申请号:PCT/EP2009066783

    申请日:2009-12-10

    Abstract: The present invention relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, which can be prepared by polycondensation of an acid component and of one or more low-molecular-weight diols whose molecular weight is less than 500 g/mol, in excess, where the acid component comprises 83 to 97 mol% of adipic acid and 3 to 17 mol% of phthalic acid, isophthalic acid and/or terephthalic acid. The present invention further relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, preparable by polycondensation of an acid component and one or more low-molecular-weight diols having a molecular weight of less than 500 g/mol, in excess, the low-molecular-weight diols containing 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol. The present invention also relates to a process for the production of these composite elements, and to components in the fitting-out of aircraft, of vehicles, or of buildings, and to insulation systems comprising this type of composite element.

    Abstract translation: 本发明涉及包含(i)塑料的复合元件,粘附的(ⅱ)多异氰酸酯Polyadditionsproduktanschließt,其中,通过将(a)异氰酸酯与(b)中的化合物具有异氰酸酯反应性基团得到的多异氰酸酯加聚产物 (c)中的催化剂,(d)任选地,发泡剂和(e)任选的其它添加剂,以形成反应混合物,并进行反应使反应混合物到多异氰酸酯加聚产物,其特征在于,含异氰酸酯 - 反应性基团的化合物(b)含有聚酯多元醇作为其可以通过缩聚来制备粘合剂 的酸组分和具有小于500g / mol的过量,其中所述酸组分包含83-97%(摩尔)己二酸和邻苯二甲酸,间苯二甲酸和/或对苯二甲酸的3〜17摩尔%的分子量的一种或多种低分子量二醇。 此外,本发明的复合元件包括:(i)塑料,粘附的(ⅱ)多异氰酸酯加聚产物其中所获得的多异氰酸酯加聚产物而言,通过混合(A)异氰酸酯与(B)的化合物具有异氰酸酯反应性基团 ,(C)的催化剂,(d)任选地,发泡剂和(e)任选的其他添加剂,以形成反应混合物,并允许反应在反应混合物的聚异氰酸酯加聚产物,其特征在于,含异氰酸酯 - 反应性基团的化合物(b)含有聚酯多元醇作为可制备的粘接剂 酸组分和具有小于500克/ molim过量,的分子量的一种或多种低分子量二醇的缩聚,其中含有5至66摩尔%的1,3-丙二醇的,基于二醇的总量中的低分子量二醇。 另外,本发明提供了用于制备这样的复合元件,并且组件飞机,车辆或不动产膨胀的方法,将含有绝缘涉及这样的复合元件。

    ADHESION PROMOTER FOR ADHESIVE COMPOSITES COMPOSED OF PLASTIC AND OF A POLYISOCYANATE POLYADDITION PRODUCT

    公开(公告)号:CA2746833A1

    公开(公告)日:2010-07-01

    申请号:CA2746833

    申请日:2009-12-10

    Applicant: BASF SE

    Abstract: The present invention relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, which can be prepared by polycondensation of an acid component and of one or more low-molecular-weight diols whose molecular weight is less than 500 g/mol, in excess, where the acid component comprises 83 to 97 mol% of adipic acid and 3 to 17 mol% of phthalic acid, isophthalic acid and/or terephthalic acid. The present invention further relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, preparable by polycondensation of an acid component and one or more low-molecular-weight diols having a molecular weight of less than 500 g/mol, in excess, the low-molecular-weight diols containing 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol. The present invention also relates to a process for the production of these composite elements, and to components in the fitting-out of aircraft, of vehicles, or of buildings, and to insulation systems comprising this type of composite element.

    ADHESION PROMOTER FOR ADHESIVE COMPOSITES COMPOSED OF PLASTIC AND OF A POLYISOCYANATE POLYADDITION PRODUCT

    公开(公告)号:CA2746833C

    公开(公告)日:2017-05-30

    申请号:CA2746833

    申请日:2009-12-10

    Applicant: BASF SE

    Abstract: The present invention relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, which can be prepared by polycondensation of an acid component and of one or more low-molecular-weight diols whose molecular weight is less than 500 g/mol, in excess, where the acid component comprises 83 to 97 mol% of adipic acid and 3 to 17 mol% of phthalic acid, isophthalic acid and/or terephthalic acid. The present invention further relates to composite elements comprising (i) plastic, adhering to which there is (ii) a polyisocyanate polyaddition product, where the polyisocyanate polyaddition product is obtained by mixing (a) isocyanate with (b) compounds having groups reactive toward isocyanates, (c) catalysts, (d) if desired, blowing agent, and (e) if desired, further additives, to give a reaction mixture, and permitting the reaction mixture to complete its reaction to give the polyisocyanate polyaddition product, where the compounds (b) having groups reactive toward isocyanates comprise a polyester polyalcohol as adhesion promoter, preparable by polycondensation of an acid component and one or more low-molecular-weight diols having a molecular weight of less than 500 g/mol, in excess, the low-molecular-weight diols containing 5 to 66 mol% of 1,3-propanediol, based on the total amount of the diol. The present invention also relates to a process for the production of these composite elements, and to components in the fitting-out of aircraft, of vehicles, or of buildings, and to insulation systems comprising this type of composite element.

    Promotor de adhesión para compuestos adhesivos que comprenden un plástico y un producto de poli-adición de poli-isocianato

    公开(公告)号:ES2590211T3

    公开(公告)日:2016-11-18

    申请号:ES14166682

    申请日:2009-12-10

    Applicant: BASF SE

    Abstract: Elementos composite que contienen (i) plástico, al cual se une adhiriéndose (ii) un producto de poli-adición de poli-isocianato, en cuyo caso el producto de poli-adición de poli-isocianato se obtiene mezclando a) isocianato con b) compuestos que tienen grupos reactivos frente a los isocianatos, c) catalizadores, d) opcionalmente propelentes y e) opcionalmente otros aditivos, para formar una mezcla de reacción y dejando reaccionar la mezcla de reacción para obtener el producto de poliadición de poli-isocianato, en cuyo caso los compuestos que tienen grupos reactivos frente a los isocianatos (b) contienen un poliéster-polialcohol en calidad de promotor de adhesión, el cual puede producirse mediante policondensación de un componente de ácido y uno o varios dioles de bajo peso molecular, en exceso, que tienen un peso molecular de menos de 500 g/mol, en cuyo caso los dioles de bajo peso molecular contienen 5 a 66 % molar de 1,3-propandiol, respecto de la cantidad total del diol.

    PROMOTOR DE ADHESION PARA COMPUESTOS ADHESIVOS CONSTITUIDOS DE PLASTICO Y DE UN PRODUCTO DE POLIADICION DE POLIISOCIANATO.

    公开(公告)号:MX2011006199A

    公开(公告)日:2011-07-01

    申请号:MX2011006199

    申请日:2009-12-10

    Applicant: BASF SE

    Abstract: La presente invención se refiere a elementos compuestos que comprenden (i) plástico, al cual se adhiere, (ii) un producto de poliadición de poliisocianato, donde el producto de poliadición de poliisocianato se obtiene a través del mezclado del (a) isocianato con (b) compuestos que tienen grupos reactivos a los isocianatos, (c) catalizadores, (d) si es apropiado, agente de soplado, y (e) si es apropiado, aditivos adicionales, para dar una mezcla de reacción y permitir a la mezcla de reacción completar su reacción para dar el producto de poliadición de poliisocianato, donde los compuestos (b) que tienen grupos reactivos a los isocianatos comprenden un polialcohol de poliéster como promotor de adhesión, apto para producción a través de la policondensación de un componente ácido y de uno o más dioles de peso molecular bajo cuya masa molar es menor de 500 g/moles, en exceso, donde el componente ácido comprende 83 a 97% en mol de ácido adípico y de 3 a 17% en mol de ácido ftálico, ácido isoftálico, y/o ácido tereftálico. La presente invención se refiere además a elementos compuestos que comprenden un (i) plástico, al cual se adhiere (ii) un producto de poliadición de poliisocianato, donde el producto de poliadición de poliisocianato se obtiene a través del mezclado de (a) isocianato con (b) compuestos que tienen grupos reactivos a los isocianatos, (c) catalizadores, (d) si es apropiado, agente de soplado, y (e) si es apropiado, aditivos adicionales para dar una mezcla de reacción y permitir a la mezcla de reacción completar su reacción para dar el producto de poliadición de poliisocianato, donde los compuestos (b) que tienen grupos reactivos a los isocianatos comprenden un polialcohol de poliéster como promotor de adhesión, apto para producción a través de la policondensación de un componente ácido y de uno o más dioles de peso molecular bajo cuya masa molar es menor de 500 g/moles, en exceso, donde los dioles de peso molecular bajo comprenden de 5 a 66% en mol de 1,3-propandiol, en base a la cantidad total del diol. La presente invención también se refiere a un proceso para la producción de estos elementos compuestos, y a componentes en el armado de aeronaves, de vehículos, o de edificios, y al aislamiento que comprende este tipo de elemento compuesto.

Patent Agency Ranking